Perovskite nickelates as electric-field sensors in salt water.

Designing materials to function in harsh environments, such as conductive aqueous media, is a problem of broad interest to a range of technologies, including energy, ocean monitoring and biological applications. The main challenge is to retain the stability and morphology of the material as it interacts dynamically with the surrounding environment. Materials that respond to mild stimuli through collective phase transitions and amplify signals could open up new avenues for sensing. Here we present the discovery of an electric-field-driven, water-mediated reversible phase change in a perovskite-structured nickelate, SmNiO3. This prototypical strongly correlated quantum material is stable in salt water, does not corrode, and allows exchange of protons with the surrounding water at ambient temperature, with the concurrent modification in electrical resistance and optical properties being capable of multi-modal readout. Besides operating both as thermistors and pH sensors, devices made of this material can detect sub-volt electric potentials in salt water. We postulate that such devices could be used in oceanic environments for monitoring electrical signals from various maritime vessels and sea creatures.

The evolution of red color vision is linked to coordinated rhodopsin tuning in lycaenid butterflies.

Color vision has evolved multiple times in both vertebrates and invertebrates and is largely determined by the number and variation in spectral sensitivities of distinct opsin subclasses. However, because of the difficulty of expressing long-wavelength (LW) invertebrate opsins in vitro, our understanding of the molecular basis of functional shifts in opsin spectral sensitivities has been biased toward research primarily in vertebrates. This has restricted our ability to address whether invertebrate Gq protein-coupled opsins function in a novel or convergent way compared to vertebrate Gt opsins. Here we develop a robust heterologous expression system to purify invertebrate rhodopsins, identify specific amino acid changes responsible for adaptive spectral tuning, and pinpoint how molecular variation in invertebrate opsins underlie wavelength sensitivity shifts that enhance visual perception. By combining functional and optophysiological approaches, we disentangle the relative contributions of lateral filtering pigments from red-shifted LW and blue short-wavelength opsins expressed in distinct photoreceptor cells of individual ommatidia. We use in situ hybridization to visualize six ommatidial classes in the compound eye of a lycaenid butterfly with a four-opsin visual system. We show experimentally that certain key tuning residues underlying green spectral shifts in blue opsin paralogs have evolved repeatedly among short-wavelength opsin lineages. Taken together, our results demonstrate the interplay between regulatory and adaptive evolution at multiple Gq opsin loci, as well as how coordinated spectral shifts in LW and blue opsins can act together to enhance insect spectral sensitivity at blue and red wavelengths for visual performance adaptation.

A hypothesis for robust polarization vision: an example from the Australian imperial blue butterfly, Jalmenus evagoras.

The Australian lycaenid butterfly Jalmenus evagoras has iridescent wings that are sexually dimorphic, spectrally and in their degree of polarization, suggesting that these properties are likely to be important in mate recognition. We first describe the results of a field experiment showing that free-flying individuals of J. evagoras discriminate between visual stimuli that vary in polarization content in blue wavelengths but not in others. We then present detailed reflectance spectrophotometry measurements of the polarization content of male and female wings, showing that female wings exhibit blue-shifted reflectance, with a lower degree of polarization relative to male wings. Finally, we describe a novel method for measuring alignment of ommatidial arrays: by measuring variation of depolarized eyeshine intensity from patches of ommatidia as a function of eye rotation, we show that (a) individual rhabdoms contain mutually perpendicular microvilli; (b) many rhabdoms in the array have their microvilli misaligned with respect to neighboring rhabdoms by as much as 45 deg; and (c) the misaligned ommatidia are useful for robust polarization detection. By mapping the distribution of the ommatidial misalignments in eye patches of J. evagoras, we show that males and females exhibit differences in the extent to which ommatidia are aligned. Both the number of misaligned ommatidia suitable for robust polarization detection and the number of aligned ommatidia suitable for edge detection vary with respect to both sex and eye patch elevation. Thus, J. evagoras exhibits finely tuned ommatidial arrays suitable for perception of polarized signals, likely to match sex-specific life history differences in the utility of polarized signals.

Designing Mesoporous Photonic Structures for High-Performance Passive Daytime Radiative Cooling.

Passive daytime radiative cooling (PDRC) has drawn significant attention recently for electricity-free cooling. Porous polymers are attractive for PDRC since they have excellent performance and scalability. A fundamental question remaining is how PDRC performance depends on pore properties (e.g., radius, porosity), which is critical to guiding future structure designs. In this work, optical simulations are carried out to answer this question, and effects of pore size, porosity, and thickness are studied. We find that mixed nanopores (e.g., radii of 100 and 200 nm) have a much higher solar reflectance R̅solar (0.951) than the single-sized pores (0.811) at a thickness of 300 µm. With an Al substrate underneath, R̅solar, thermal emittance ε̅LWIR, and net cooling power Pcool reach 0.980, 0.984, and 72 W/m2, respectively, under a semihumid atmospheric condition. These simulation results provide a guide for designing high-performance porous coating for PDRC applications.

Chiral Quasi-Bound States in the Continuum.

Quasi-bound states in the continuum (QBICs) are Fano resonant states with long optical lifetimes controlled by symmetry-breaking perturbations. While conventional Fano responses are limited to linear polarizations and do not support tailored phase control, here we introduce QBICs born of chiral perturbations that encode arbitrary elliptical polarization states and enable geometric phase engineering. We thereby design metasurfaces with ultrasharp spectral features that shape the impinging wave front with near-unity efficiency. Our findings extend Fano resonances beyond their conventional limits, opening opportunities for nanophotonics, classical and quantum optics, and acoustics.

Planar nonlinear metasurface optics and their applications.

Metasurfaces are artificial two-dimensional (2D) planar surfaces that consist of subwavelength 'meta-atoms' (i.e. metallic or dielectric nanostructures). They are known for their capability to achieve better and more efficient light control in comparison to their traditional optical counterparts. Abrupt and sharp changes in the electromagnetic properties can be induced by the metasurfaces rather than the conventional gradual accumulation that requires greater propagation distances. Based on this feature, planar optical components like mirrors, lenses, waveplates, isolators and even holograms with ultrasmall thicknesses have been developed. Most of the current metasurface studies have focused on tailoring the linear optical effects for applications such as cloaking, lens imaging and 3D holography. Recently, the use of metasurfaces to enhance nonlinear optical effects has attracted significant attention from the research community. Benefiting from the resulting efficient nonlinear optical processes, the fabrication of integrated all-optical nano-devices with peculiar functionalities including broadband frequency conversions and ultrafast optical switching will become achievable. Plasmonic excitation is one of the most effective approaches to increase nonlinear optical responses due to its induced strong local electromagnetic field enhancement. For instance, continuous phase control on the effective nonlinear polarizability of plasmonic metasurfaces has been demonstrated through spin-rotation light coupling. The phase of the nonlinear polarization can be continuously tuned by spatially changing the meta-atoms' orientations during second and third harmonic generation processes, while the nonlinear metasurfaces also exhibit homogeneous linear properties. In addition, an ultrahigh second-order nonlinear susceptibility of up to 104 pm V-1 has recently been reported by coupling the plasmonic modes of patterned metallic arrays with intersubband transition of multi-quantum-well layered substrate. In order to develop ultra-planar nonlinear plasmonic metasurfaces, 2D materials such as graphene and transition metal dichalcogenides (TMDCs) have been extensively studied based on their unique nonlinear optical properties. The third-order nonlinear coefficient of graphene is five times that of gold substrate, while TMDC materials also exhibit a strong second-order magnetic susceptibility. In this review, we first focus on the main principles of planar nonlinear plasmonics based on metasurfaces and 2D nonlinear materials. The advantages and challenges of incorporating 2D nonlinear materials into metasurfaces are discussed, followed by their potential applications including orbital angular momentum manipulating and quantum optics.

Multifunctional Nonlocal Metasurfaces.

Diffractive photonic devices manipulate light via local and nonlocal optical modes. Local devices, such as metasurfaces, can shape a wave front at multiple selected wavelengths, but inevitably modify light across the spectrum; nonlocal devices, such as grating filters, offer great frequency selectivity but limited spatial control. Here, we introduce a rational design paradigm using quasibound states in the continuum to realize multifunctional nonlocal devices: metasurfaces that produce narrow band spatially tailored wave fronts at multiple selected wavelengths and yet are otherwise transparent.

A review of metasurfaces: physics and applications.

Metamaterials are composed of periodic subwavelength metal/dielectric structures that resonantly couple to the electric and/or magnetic components of the incident electromagnetic fields, exhibiting properties that are not found in nature. This class of micro- and nano-structured artificial media have attracted great interest during the past 15 years and yielded ground-breaking electromagnetic and photonic phenomena. However, the high losses and strong dispersion associated with the resonant responses and the use of metallic structures, as well as the difficulty in fabricating the micro- and nanoscale 3D structures, have hindered practical applications of metamaterials. Planar metamaterials with subwavelength thickness, or metasurfaces, consisting of single-layer or few-layer stacks of planar structures, can be readily fabricated using lithography and nanoprinting methods, and the ultrathin thickness in the wave propagation direction can greatly suppress the undesirable losses. Metasurfaces enable a spatially varying optical response (e.g. scattering amplitude, phase, and polarization), mold optical wavefronts into shapes that can be designed at will, and facilitate the integration of functional materials to accomplish active control and greatly enhanced nonlinear response. This paper reviews recent progress in the physics of metasurfaces operating at wavelengths ranging from microwave to visible. We provide an overview of key metasurface concepts such as anomalous reflection and refraction, and introduce metasurfaces based on the Pancharatnam-Berry phase and Huygens' metasurfaces, as well as their use in wavefront shaping and beam forming applications, followed by a discussion of polarization conversion in few-layer metasurfaces and their related properties. An overview of dielectric metasurfaces reveals their ability to realize unique functionalities coupled with Mie resonances and their low ohmic losses. We also describe metasurfaces for wave guidance and radiation control, as well as active and nonlinear metasurfaces. Finally, we conclude by providing our opinions of opportunities and challenges in this rapidly developing research field.

High efficiency near diffraction-limited mid-infrared flat lenses based on metasurface reflectarrays.

We report the first demonstration of a mid-IR reflection-based flat lens with high efficiency and near diffraction-limited focusing. Focusing efficiency as high as 80%, in good agreement with simulations (83%), has been achieved at 45° incidence angle at λ = 4.6 µm. The off-axis geometry considerably simplifies the optical arrangement compared to the common geometry of normal incidence in reflection mode which requires beam splitters. Simulations show that the effects of incidence angle are small compared to parabolic mirrors with the same NA. The use of single-step photolithography allows large scale fabrication. Such a device is important in the development of compact telescopes, microscopes, and spectroscopic designs.

Flat optics with designer metasurfaces.

Conventional optical components such as lenses, waveplates and holograms rely on light propagation over distances much larger than the wavelength to shape wavefronts. In this way substantial changes of the amplitude, phase or polarization of light waves are gradually accumulated along the optical path. This Review focuses on recent developments on flat, ultrathin optical components dubbed 'metasurfaces' that produce abrupt changes over the scale of the free-space wavelength in the phase, amplitude and/or polarization of a light beam. Metasurfaces are generally created by assembling arrays of miniature, anisotropic light scatterers (that is, resonators such as optical antennas). The spacing between antennas and their dimensions are much smaller than the wavelength. As a result the metasurfaces, on account of Huygens principle, are able to mould optical wavefronts into arbitrary shapes with subwavelength resolution by introducing spatial variations in the optical response of the light scatterers. Such gradient metasurfaces go beyond the well-established technology of frequency selective surfaces made of periodic structures and are extending to new spectral regions the functionalities of conventional microwave and millimetre-wave transmit-arrays and reflect-arrays. Metasurfaces can also be created by using ultrathin films of materials with large optical losses. By using the controllable abrupt phase shifts associated with reflection or transmission of light waves at the interface between lossy materials, such metasurfaces operate like optically thin cavities that strongly modify the light spectrum. Technology opportunities in various spectral regions and their potential advantages in replacing existing optical components are discussed.

Broad electrical tuning of graphene-loaded plasmonic antennas.

Plasmonic antennas enable the conversion of light from free space into subwavelength volumes and vice versa, which facilitates the manipulation of light at the nanoscale. Dynamic control of the properties of antennas is desirable for many applications, including biochemical sensors, reconfigurable meta-surfaces and compact optoelectronic devices. The combination of metallic structures and graphene, which has gate-voltage dependent optical properties, is emerging as a possible platform for electrically controlled plasmonic devices. In this paper, we demonstrate in situ control of antennas using graphene as an electrically tunable load in the nanoscale antenna gap. In our experiments, we demonstrate electrical tuning of graphene-loaded antennas over a broad wavelength range of 650 nm (∼140 cm(-1), ∼10% of the resonance frequency) in the mid-infrared (MIR) region. We propose an equivalent circuit model to quantitatively analyze the tuning behavior of graphene-loaded antenna pairs and derive an analytical expression for the tuning range of resonant wavelength. In a separate experiment, we used doubly resonant antenna arrays to achieve MIR optical intensity modulation with maximum modulation depth of more than 30% and bandwidth of 600 nm (∼100 cm(-1), 8% of the resonance frequency). This study shows that combining graphene with metallic nanostructures provides a route to electrically tunable optical and optoelectronic devices.

Flat­Knit, Flexible, Textile Metasurfaces.

Lightweight, low-cost metasurfaces and reflectarrays that are easy to stow and deploy are desirable for many terrestrial and space-based communications and sensing applications. This work demonstrates a lightweight, flexible metasurface platform based on flat-knit textiles operating in the cm-wave spectral range. By using a colorwork knitting approach called float-jacquard knitting to directly integrate an array of resonant metallic antennas into a textile, two textile reflectarray devices, a metasurface lens (metalens), and a vortex-beam generator are realized. Operating as a receiving antenna, the metalens focuses a collimated normal-incidence beam to a diffraction-limited, off-broadside focal spot. Operating as a transmitting antenna, the metalens converts the divergent emission from a horn antenna into a collimated beam with peak measured directivity, gain, and efficiency of 21.30, 15.30, and -6.00 dB (25.12%), respectively. The vortex-beam generating metasurface produces a focused vortex beam with a topological charge of m = 1 over a wide frequency range of 4.1-5.8 GHz. Strong specular reflection is observed for the textile reflectarrays, caused by wavy yarn floats on the backside of the float-jacquard textiles. This work demonstrates a novel approach for the scalable production of flexible metasurfaces by leveraging commercially available yarns and well-established knitting machinery and techniques.

TRPA5 encodes a thermosensitive ankyrin ion channel receptor in a triatomine insect.

As ectotherms, insects need heat-sensitive receptors to monitor environmental temperatures and facilitate thermoregulation. We show that TRPA5, a class of ankyrin transient receptor potential (TRP) channels absent in dipteran genomes, may function as insect heat receptors. In the triatomine bug Rhodnius prolixus (order: Hemiptera), a vector of Chagas disease, the channel RpTRPA5B displays a uniquely high thermosensitivity, with biophysical determinants including a large channel activation enthalpy change (72 kcal/mol), a high temperature coefficient (Q10 = 25), and in vitro temperature-induced currents from 53°C to 68°C (T0.5 = 58.6°C), similar to noxious TRPV receptors in mammals. Monomeric and tetrameric ion channel structure predictions show reliable parallels with fruit fly dTRPA1, with structural uniqueness in ankyrin repeat domains, the channel selectivity filter, and potential TRP functional modulator regions. Overall, the finding of a member of TRPA5 as a temperature-activated receptor illustrates the diversity of insect molecular heat detectors.

Roadmap for Optical Metasurfaces.

Metasurfaces have recently risen to prominence in optical research, providing unique functionalities that can be used for imaging, beam forming, holography, polarimetry, and many more, while keeping device dimensions small. Despite the fact that a vast range of basic metasurface designs has already been thoroughly studied in the literature, the number of metasurface-related papers is still growing at a rapid pace, as metasurface research is now spreading to adjacent fields, including computational imaging, augmented and virtual reality, automotive, display, biosensing, nonlinear, quantum and topological optics, optical computing, and more. At the same time, the ability of metasurfaces to perform optical functions in much more compact optical systems has triggered strong and constantly growing interest from various industries that greatly benefit from the availability of miniaturized, highly functional, and efficient optical components that can be integrated in optoelectronic systems at low cost. This creates a truly unique opportunity for the field of metasurfaces to make both a scientific and an industrial impact. The goal of this Roadmap is to mark this "golden age" of metasurface research and define future directions to encourage scientists and engineers to drive research and development in the field of metasurfaces toward both scientific excellence and broad industrial adoption.

Coaxial silicon nanowires as solar cells and nanoelectronic power sources.

Solar cells are attractive candidates for clean and renewable power; with miniaturization, they might also serve as integrated power sources for nanoelectronic systems. The use of nanostructures or nanostructured materials represents a general approach to reduce both cost and size and to improve efficiency in photovoltaics. Nanoparticles, nanorods and nanowires have been used to improve charge collection efficiency in polymer-blend and dye-sensitized solar cells, to demonstrate carrier multiplication, and to enable low-temperature processing of photovoltaic devices. Moreover, recent theoretical studies have indicated that coaxial nanowire structures could improve carrier collection and overall efficiency with respect to single-crystal bulk semiconductors of the same materials. However, solar cells based on hybrid nanoarchitectures suffer from relatively low efficiencies and poor stabilities. In addition, previous studies have not yet addressed their use as photovoltaic power elements in nanoelectronics. Here we report the realization of p-type/intrinsic/n-type (p-i-n) coaxial silicon nanowire solar cells. Under one solar equivalent (1-sun) illumination, the p-i-n silicon nanowire elements yield a maximum power output of up to 200 pW per nanowire device and an apparent energy conversion efficiency of up to 3.4 per cent, with stable and improved efficiencies achievable at high-flux illuminations. Furthermore, we show that individual and interconnected silicon nanowire photovoltaic elements can serve as robust power sources to drive functional nanoelectronic sensors and logic gates. These coaxial silicon nanowire photovoltaic elements provide a new nanoscale test bed for studies of photoinduced energy/charge transport and artificial photosynthesis, and might find general usage as elements for powering ultralow-power electronics and diverse nanosystems.

Whispering-gallery mode resonators for highly unidirectional laser action.

Optical microcavities can be designed to take advantage of total internal reflection, which results in resonators supporting whispering-gallery modes (WGMs) with a high-quality factor (Q factor). One of the crucial problems of these devices for practical applications such as designing microcavity lasers, however, is that their emission is nondirectional due to their radial symmetry, in addition to their inefficient power output coupling. Here we report the design of elliptical resonators with a wavelength-size notch at the boundary, which support in-plane highly unidirectional laser emission from WGMs. The notch acts as a small scatterer such that the Q factor of the WGMs is still very high. Using midinfrared (λ ∼ 10 µm) injection quantum cascade lasers as a model system, an in-plane beam divergence as small as 6 deg with a peak optical power of ∼5 mW at room temperature has been demonstrated. The beam divergence is insensitive to the pumping current and to the notch geometry, demonstrating the robustness of this resonator design. The latter is scalable to the visible and the near infrared, thus opening the door to very low-threshold, highly unidirectional microcavity diode lasers.

Out-of-plane reflection and refraction of light by anisotropic optical antenna metasurfaces with phase discontinuities.

Experiments on ultrathin anisotropic arrays of subwavelength optical antennas display out-of-plane refraction. A powerful three-dimensional (3D) extension of the recently demonstrated generalized laws of refraction and reflection shows that the interface imparts a tangential wavevector to the incident light leading to anomalous beams, which in general are noncoplanar with the incident beam. The refracted beam direction can be controlled by varying the angle between the plane of incidence and the antenna array.

A broadband, background-free quarter-wave plate based on plasmonic metasurfaces.

We demonstrate optically thin quarter-wave plates built with metasurfaces that generate high-quality circularly polarized light over a broad wavelength range for arbitrary orientation of the incident linear polarization. The metasurface consists of an array of plasmonic antennas with spatially varying phase and polarization responses. Experimentally demonstrated quarter-wave plates generate light with a high degree of circular polarization (>0.97) from λ = 5 to 12 µm, representing a major advance in performance compared to previously reported plasmonics-based wave plates.

Aberration-free ultrathin flat lenses and axicons at telecom wavelengths based on plasmonic metasurfaces.

The concept of optical phase discontinuities is applied to the design and demonstration of aberration-free planar lenses and axicons, comprising a phased array of ultrathin subwavelength-spaced optical antennas. The lenses and axicons consist of V-shaped nanoantennas that introduce a radial distribution of phase discontinuities, thereby generating respectively spherical wavefronts and nondiffracting Bessel beams at telecom wavelengths. Simulations are also presented to show that our aberration-free designs are applicable to high-numerical aperture lenses such as flat microscope objectives.

Leaky-wave metasurfaces for integrated photonics.

Metasurfaces have been rapidly advancing our command over the many degrees of freedom of light; however, so far, they have been mostly limited to manipulating light in free space. Metasurfaces integrated on top of guided-wave photonic systems have been explored to control the scattering of light off-chip with enhanced functionalities-namely, the point-by-point manipulation of amplitude, phase or polarization. However, these efforts have so far been limited to controlling one or two optical degrees of freedom at best, as well as device configurations much more complex compared with conventional grating couplers. Here we introduce leaky-wave metasurfaces, which are based on symmetry-broken photonic crystal slabs that support quasi-bound states in the continuum. This platform has a compact form factor equivalent to the one of grating couplers, but it provides full command over the amplitude, phase and polarization (four optical degrees of freedom) across large apertures. We present devices for phase and amplitude control at a fixed polarization state, and devices controlling all the four optical degrees of freedom for operation at a wavelength of 1.55 µm. Merging the fields of guided and free-space optics through the hybrid nature of quasi-bound states in the continuum, our leaky-wave metasurfaces may find applications in imaging, communications, augmented reality, quantum optics, LIDAR and integrated photonic systems.