RESUMO
1D nanomaterials have attracted great attention due to their outstanding anisotropic and linear structures. A facile method is developed to fabricate 1D copper metal-organic framework nanowires (Cu-MOF-NW) through steam-assisted conversion from Cu-MOF precursors. During the steam-assisted conversion, Cu-MOF precursor gradually dissolves in methanol steam, and then recrystallized into Cu-MOF-NW, which shows high aspect ratio of about 600 and identical crystal structure of MOF-74. As-prepared Cu-MOF-NW with multiscale porous structure can effectively remove cationic dyes even in dye mixture. Moreover, Cu-MOF-NW, as an ideal template, is calcined to form Cu nanoparticle-doped carbon nanofiber with maintaining its 1D morphology, which shows excellent electrocatalytic activity for the non-enzymatic sensing of glucose.
RESUMO
Due to the strong oxidizability of H2O2, rapid, accurate, sensitive, and stable sensors of hydrogen peroxide (H2O2) have attracted wide attention in the chemical industry, food, medicine, household detergents, and environmental monitoring fields. Here, a high-performance H2O2 electrochemical sensing platform is proposed based on an Au nanoparticles@UiO-66 film coated on a carbon cloth (CC) electrode (Au NPs@UiO-66/CC electrode). The Au NPs@UiO-66/CC electrode was prepared through solvothermal growth of a UiO-66 film on a functionalized three-dimensional CC electrode, followed by in situ deposition of Au NPs into the UiO-66 film under a periodic galvanostatic pulse current. The in situ preparation strategy greatly improves the electrical interaction between Au NPs@UiO-66 and the CC substrate without sacrificing the electrochemical activity of the Au NPs@UiO-66/CC electrode. Meanwhile, thanks to the high specific surface area of the three-dimensional Au NPs@UiO-66/CC electrode, the optimized Au NPs@UiO-66/CC electrode illustrates excellent electrochemical detection capability for H2O2 with an extensive linear range (0.1-21 mM), high sensitivity (1048.01 µA mM-1 cm-2), and lower limit of detection [0.033 µM (S/N = 3)] and limit of quantification [0.109 µM (S/N = 3)]. At the same time, the encapsulated structure of Au NPs in the UiO-66 film also endows the composite electrode with specific sensing performance owing to the regular opening channels of the UiO-66 films that prevent large-size interferents from reacting to the electrochemically active Au NPs. Together with all these advantages, the proposed sensing platform would exhibit great potential for electrochemical sensors and bioelectronics.
RESUMO
A new method to construct hierarchical architectures has been developed by programmed transformation of metal-organic frameworks (MOFs). A MOF precursor was fabricated by reaction of Cu(OAC)2 and 2,5-dihydroxyterephthalic acid (H4DOBDC), which could perform transformation in pure methanol solvent and the sodium dodecyl benzene sulfonate (SDBS) solution of methanol, respectively. Interestingly, two kinds of immersion solutions could induce the transformation of the MOF precursor into MOF-74, which resulted in different morphologies: nanoneedles for the methanol and nanosheets for the SDBS. Herein, nanosheets-mesorods-microcuboid hierarchical quaternary architectures of MOF have been successfully achieved by sequential immersion of the precursor in two kinds of transformation solutions, which demonstrates well-defined hierarchy from the nanoscale to mesoscale to microscale. A unique hierarchical architecture could be recognized as quaternary structures, taking the MOF unit cell as the primary structure, the nanosheets as the secondary structure, the mesorods as the tertiary structure, and the microcuboid as the quaternary structure. Our study indicated the potential of programmed transformation between MOFs in the construction of hierarchical architectures, offering a new approach to sophisticated materials.