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1.
Entropy (Basel) ; 22(2)2020 Feb 22.
Artigo em Inglês | MEDLINE | ID: mdl-33286025

RESUMO

Self-assembly is a spontaneous process through which macroscopic structures are formed from basic microscopic constituents (e.g., molecules or colloids). By contrast, the formation of large biological molecules inside the cell (such as proteins or nucleic acids) is a process more akin to self-organization than to self-assembly, as it requires a constant supply of external energy. Recent studies have tried to merge self-assembly with self-organization by analyzing the assembly of self-propelled (or active) colloid-like particles whose motion is driven by a permanent source of energy. Here we present evidence that points to the fact that self-propulsion considerably enhances the assembly of polymers: self-propelled molecules are found to assemble faster into polymer-like structures than non self-propelled ones. The average polymer length increases towards a maximum as the self-propulsion force increases. Beyond this maximum, the average polymer length decreases due to the competition between bonding energy and disruptive forces that result from collisions. The assembly of active molecules might have promoted the formation of large pre-biotic polymers that could be the precursors of the informational polymers we observe nowadays.

2.
Sci Rep ; 8(1): 15872, 2018 10 26.
Artigo em Inglês | MEDLINE | ID: mdl-30367121

RESUMO

Since the pioneering work by Vicsek and his collaborators on the motion of self-propelled particles, most of the subsequent studies have focused on the onset of ordered states through a phase transition driven by particle density and noise. Usually, the particles in these systems are placed within periodic boundary conditions and interact via short-range velocity alignment forces. However, when the periodic boundaries are eliminated, letting the particles move in open space, the system is not able to organize into a coherently moving group since even small amounts of noise cause the flock to break apart. While the phase transition has been thoroughly studied, the conditions to keep the flock cohesive in open space are still poorly understood. Here we extend the Vicsek model of collective motion by introducing long-range alignment interactions between the particles. We show that just a small number of these interactions is enough for the system to build up long lasting ordered states of collective motion in open space and in the presence of noise. This finding was verified for other models in addition to the Vicsek one, suggesting its generality and revealing the importance that long-range interactions can have for the cohesion of the flock.

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