Spreading of pollutants from alkaline mine drainage. Rodalquilar mining district (SE Spain).

In the Rodalquilar mining district of SE Spain, a total of 46 soil samples that were between 0 and 20 cm in depth were taken from the tailings dump, stream sediments, and surfaces that were presumably were unaffected by mining. In each soil sample, organic carbon content, pH, particle size distribution and total and soluble trace element content were analysed. Pollutants were scattered by runoff from two source areas: tailings from Au mining (Sn, Sb, As and Se) and wastes from Pb mining (Pb, Cu and Zn). Sn, Pb, and Sb were spread mostly in the solid phase of the runoff, while Cu, Zn, As and Se were spread in both the solid and soluble phases of the runoff. The pollutants with the highest soluble concentrations were As and Se, which were scattered at greater distances from the source. Some evidence suggests that tailings from Au mining could also be scattered by wind, but no farther than 1500 m from the source.

Impact of unconfined sulphur-mine waste on a semi-arid environment (Almería, SE Spain).

Thirty-five soil samples were taken from unconfined mine waste, stream sediments, and surfaces unoccupied by mining and presumably unaffected by it, in a sulphur-mining zone surrounded by carbonate material and characterized by a semi-arid climate with short torrential storms. These samples were analysed and the results compared to estimate the spread of pollution in the landscape and to assess potential environmental risk. The mean concentrations of S, Zn, Cd, Pb, and As in mine waste were between 3.5-fold (As) and 50-fold (S) greater than unaffected soils. Oxidation of S led to a sharp drop in pH, strong weathering of minerals, and solubilisation of the constituent elements, forming a toxic acidic mine drainage with highly concentrated pollutants that were discharged into the drainage channels. Successive acid mine drainage into the soil on the valley floor spreads acidification and pollution downstream. The high carbonate content in surrounding soils played an important role in the increase of the pH and precipitation of S, Pb, and Al of the affected soils. Meanwhile, high mobility of Zn, Cd and As under basic conditions and a low Fe concentration explain the broad spread of these elements, as high concentrations were detected in soil more than 2000 m from the source. Only the soil solutions from near the waste dump (first 500 m) were highly phytotoxic, and moderately phytotoxic from 500 to 1500 m away. The concentration of pollutants in the leachates was clearly higher than in soil solutions, even in the soils located over 2000 m from the source, implying that the size of the polluted area will increase with time.

Use of liming in the remediation of soils polluted by sulphide oxidation: a leaching-column study.

Pure CaCO(3) in ascending quantities was added to a soil to study the effect of liming after contamination by an acidic solution from the oxidation of pyrite tailings. The samples were placed in percolation columns, and soils and leachates were monitored. In the soil samples, the mineralogy, pH, CaCO(3), iron, and total content in Cu, Zn, As, Cd, and Pb were determined. The presence of CaCO(3) in the soils considerably limited their acidification, favouring the precipitation of Cu, Zn, and Cd, and promoting precipitation of iron and SO(4)(2-) ions in the form of iron hydroxysulphates and gypsum. The iron hydroxysulphates tended to retain the less mobile elements (As, and Pb) near the top of the soil. The more mobile elements (Zn, Cd and Cu) precipitated in deeper layers, directly related mainly to the CaCO(3) added and to pH. The CaCO(3) clearly did not reduce Zn and Cd toxicity effectively enough, given that the concentrations of both elements were above the toxic level in all leachates. The amounts of liming needs to be properly controlled, as excessively high pH limits As fixing, at the same time as the effectiveness of CaCO(3) is limited by coating precipitation, reducing its capacity to react with the acidic solution.