One-step preparation of carboxyl-functionalized porous organic polymer as sorbent for enrichment of phenols in bottled water, juice and honey samples.

Herein, a novel carboxyl-functionalized porous organic polymer (COOH-POP) was prepared as sorbent. Due to multiple hydrogen bonds and π-π interactions between COOH-POP and phenols, COOH-POP shows good enrichment ability and very fast adsorption rate for phenols. Then, an analytical method was developed for determination of five phenols (2-chlorophenol, bisphenol A, 2,6-dichlorophenol, 2,4-dichlorophenol and p-tert-butylphenol) in bottled water, lemon juice, peach juice and honey samples using COOH-POP as solid phase extraction sorbent in combination with high performance liquid chromatography. Under optimal conditions, the COOH-POP based method gave the detection limits (S/N = 3) of 0.02-0.10 ng mL-1 for bottled water, 0.03-0.12 ng mL-1 for lemon juice, 0.03-0.25 ng mL-1 for peach juice and 0.7-1.5 ng g-1 for honey samples. The recoveries for spiked samples ranged from 84.0 % to 119.0 % with relative standard deviation less than 7.6 %. This study provides a new yet effective method for enrichment of phenols by designing carboxyl-functionalized porous organic polymer as sorbent.