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1.
J Environ Manage ; 326(Pt A): 116662, 2023 Jan 15.
Artigo em Inglês | MEDLINE | ID: mdl-36347216

RESUMO

To determine factors affecting compost maturity and gaseous emissions during the rapid composting of kitchen waste, an orthogonal test was conducted with three factors: moisture content (MC) (55%, 60%, 65%), aeration rate (AR) (0.3,0.6 and 0.9 L·kg-1DM·min-1) and C/N ratio (21, 24, 27). The results showed that the importance of factors affecting compost maturity was: C/N > AR > MC, optimal conditions were: C/N of 24, AR of 0.3 L·kg-1DM·min-1and MC of 65%. For gaseous emissions, the sequence of essential factors affecting NH3 emissions was: C/N > MC > AR, and the optimal parameters for NH3 reduction were: C/N of 27, MC of 65%, and AR of L·kg-1DM·min-1. The important factors affecting N2O and H2S emissions are both: MC > C/N > AR, while their best parameters were different. The optimal parameters for N2O emission reduction were MC of 60%, AR of 0.3 L·kg-1DM·min-1 and C/N of 24, while these for H2S were MC of 55%, AR of 0.3 L·kg-1DM·min-1 and C/N of 21. The C/N mainly affected the compost maturity and AR further affected the maturity and pollutant gas emissions by influencing the temperature and O2 content. Considering comprehensively the maturity and gaseous reduction, the optimal control parameters were: MC of 60%-65%, AR of L·kg-1DM·min-1, and C/N of 24-27.


Assuntos
Compostagem , Compostagem/métodos , Gases , Solo , Temperatura
2.
Environ Monit Assess ; 195(6): 683, 2023 May 17.
Artigo em Inglês | MEDLINE | ID: mdl-37193921

RESUMO

The objective of this study was to provide an appropriate evaluation of ambient air quality in industrial localities and the surrounding residential areas in its vicinity. Therefore, an assessment of gaseous emissions from industrial sectors was performed. For this purpose, concentrations were measured for SO2, H2S, NO2, O3, CO, PM2.5, and PM10 in five spatially diverse monitoring stations (AQMS) over different temporal intervals (daily, monthly, and annual) for the years 2015-2020. The impact on the environment and public health was evaluated through comparison with the corresponding regional and international standards. In the case study region, a substantial spatiotemporal variation was observed in the gaseous contaminants, due to the predominance of characterized meteorological parameters interfering with contributions from existing chemical facilities and anthropogenic activities. The exceedances for the investigated emissions were routinely violated the standard concentrations. According to AQI classifications, these violations were assigned to be within the acceptable limits for the gaseous emissions, moderately polluted for PM2.5, and unhealthy for sensitive groups for PM10. The proper distribution of the AQMSs within the industrial locality provides enough spatial and temporal observatory data, such that the exceedances were reduced with the subsequent years, hence appropriate evaluation of the relevant measurements revealed effective qualitative policies taken into action by authorities to maintain less accumulation of the gaseous emissions into ambient air beyond the harmful limits for public health and environment.


Assuntos
Poluentes Atmosféricos , Poluição do Ar , Poluentes Atmosféricos/análise , Monitoramento Ambiental , Poluição do Ar/análise , Cidades , Gases , Material Particulado/análise
3.
J Environ Manage ; 317: 115290, 2022 Sep 01.
Artigo em Inglês | MEDLINE | ID: mdl-35640405

RESUMO

As a by-product of wastewater treatment, biosolids are a source of volatile emissions which can lead to community complaints due to odours and other pollution risks. Sampling methods play a significant role in collecting gas emissions from biosolids-related sources (i.e., pure biosolids, landfilling, land application and composting of biosolids). Though a range of different sampling techniques (flux hood, wind tunnel, static chamber, headspace devices) have been explored in many published papers, the management and best practice for sampling emissions from biosolids is unclear. This paper presents a comprehensive review of sampling methods for collecting gaseous emissions from biosolids. To account for the inconsistent terminologies used to describe sampling devices, a standard nomenclature by grouping sampling devices into five categories was proposed. Literature investigating emission sampling from biosolids-related sources was reviewed. Subsequently a critical analysis of sampling methods in terms of design, advantages, and disadvantages were compiled based on literature findings and assumed mechanistic understanding of operation. Key operational factors such as the presence of fans, purge gas flow rates, insertion depth, and incubation conditions were identified and their level of influence on the measurement of emissions were evaluated. From the review, there are still knowledge gaps regarding sampling methods used to collect gases from biosolids-related sources. Therefore, a framework for the management of emission sampling methodologies based on common sampling purposes was proposed. This critical review is expected to improve the understanding of sampling methodologies used in biosolids-related sources, by demonstrating the potential implications and impacts due to different choices in sampling methods.


Assuntos
Odorantes , Eliminação de Resíduos Líquidos , Biossólidos , Gases/análise , Odorantes/análise , Eliminação de Resíduos Líquidos/métodos
4.
J Clean Prod ; 336: 130449, 2022 Feb 15.
Artigo em Inglês | MEDLINE | ID: mdl-35177880

RESUMO

A farm-to-landscape scale modelling framework combining regulating services and life cycle assessment mid-point impacts for air and water was used to explore the co-benefits and trade-offs of alternative management futures for grazing livestock farms. Two intervention scenarios were compared: one using on-farm interventions typically recommended following visual farm audits (visually-based) and the other using mechanistical understanding of nutrient and sediment losses to water (mechanistically-based). At farm scale, reductions in business-as-usual emissions to water of total phosphorus (TP) and sediment, using both the visually-based and mechanistically-based scenarios, were <5%. These limited impacts highlighted the important role of land drains and the lack of relevant on-farm measures in current recommended advisory lists for the soil types in question. The predicted impacts of both scenarios on free draining soils were significantly higher; TP reductions of ∼9% (visually-based) and ∼20% (mechanistically-based) compared with corresponding respective estimates of >20% and >35% for sediment. Key co-benefits at farm scale included reductions in nitrous oxide emissions and improvements in physical soil quality, whereas an increase in ammonia emissions was the principal trade-off. At landscape scale, simulated reductions in business-as-usual losses were <3% for both pollutants for both scenarios. The visually-based and mechanistically-based scenarios narrowed the gaps between current and modern background sediment loads by 6% and 11%, respectively. The latter scenario also improved the reduction of GWP100 relative to business-as-usual by 4%, in comparison to 1% for the former. However, with the predicted increase of ammonia emissions, both eutrophication potential and acidification potential increased (e.g., by 7% and 14% for the mechanistically-based scenario). The discrepancy of on-farm intervention efficacy across spatial scales generated by non-agricultural water pollutant sources is a key challenge for addressing water quality problems at landscape scale.

5.
J Environ Manage ; 271: 110960, 2020 Oct 01.
Artigo em Inglês | MEDLINE | ID: mdl-32579521

RESUMO

Production of compost from cattle manure results in ammonia (NH3) and greenhouse gas emissions, causing the loss of valuable nitrogen (N) and having negative environmental impacts. Lignite addition to cattle pens has been reported to reduce NH3 emissions from manure by approximately 60%. However, the effect of lignite additions during the manure composting process, in terms of gaseous emissions of NH3, nitrous oxide (N2O), carbon dioxide (CO2), and methane (CH4) is not clear. This composting study was conducted at a commercial cattle feedlot in Victoria, Australia. Prior to cattle entering the feedlot, we applied 4.5 kg m-2 of dry lignite to a treatment pen, and no lignite to a control pen. After 90 days of occupancy, the cattle were removed and the accumulated manure from each pen was used to form two separate compost windrows (control and treatment). During composting we collected manure samples regularly and quantified gaseous emissions of NH3, N2O, CO2, and CH4 from both windrows with an inverse-dispersion technique using open-path Fourier transform infrared spectroscopy (OP-FTIR). Over the 87-day measurement period, the cumulative gas fluxes of NH3, N2O, CO2, and CH4 were 3.4 (± 0.6, standard error), 0.4 (± 0.1), 932 (± 99), and 1.2 (± 0.3) g kg-1 (initial dry matter (DM)), respectively for the lignite amended windrow, and 7.2 (± 1.3), 0.1 (± 0.03), 579 (± 50) and -0.5 (± 0.1) g kg-1 DM, respectively for the non-lignite windrow. The addition of lignite reduced NH3 emissions by 54% during composting, but increased total greenhouse gas (GHG) emissions by 2.6 times. Total N losses as NH3-N and N2O-N were approximately 11 and 25% of initial N for the lignite and non-lignite windrows, respectively. The effectiveness of retaining N was obvious in the first three weeks after windrow formation. A cost-benefit analysis indicated that the benefit of lignite addition to cattle pens by reduced NH3 emission could justify the trade-off of increased GHG emissions.


Assuntos
Compostagem , Amônia/análise , Animais , Dióxido de Carbono/análise , Bovinos , Carvão Mineral , Esterco , Metano , Óxido Nitroso/análise , Vitória
6.
J Environ Manage ; 267: 110649, 2020 Aug 01.
Artigo em Inglês | MEDLINE | ID: mdl-32364133

RESUMO

This study used a laboratory-scale system to investigate the effects of calcium magnesium phosphate fertilizer (CaMgP), biochar, and spent mushroom substrate (SMS) on compost maturity and gasous emissions during pig manure composting. The results showed that the addition of CaMgP, Biochar or SMS had no negative effect on the quality and maturity of compost, and all three additives could reduce the emissions of ammonia (NH3), hydrogen sulfide (H2S), dimethyl sulfide (Me2S) and dimethyl disulfide (Me2SS). Among them, the effect of adding CaMgP on NH3 emission reduction was the most obvious, reduced 42.90%. The emission reduction of CaMgP to H2S was similar to that of SMS, which decreased by 34.91% and 32.88% respectively. The emission reduction effects of the three additives on Me2S and Me2SS were obvious, all of which were over 50%. However, only adding SMS reduced the N2O emission by 37.08%.


Assuntos
Agaricales , Compostagem , Animais , Carvão Vegetal , Fertilizantes , Gases , Esterco , Nitrogênio , Fosfatos , Solo , Suínos
7.
J Environ Manage ; 200: 416-422, 2017 Sep 15.
Artigo em Inglês | MEDLINE | ID: mdl-28609732

RESUMO

The aim of the study was to evaluate the impact of slurry treatment by additives (EU200® (EU200), Bio-buster® (BB), JASS® and sulphuric acid (H2SO4)) and mechanical separation on the physical-chemical characteristics, gaseous emissions (NH3, CH4, CO2 and N2O) during anaerobic storage at ∼20 °C (experiment 1) and NH3 losses after field application (experiment 2). The treatments studied in experiment 1 were: whole slurry (WS), WS+H2SO4 to a pH of 6.0, WS+EU200 and WS+BB. Treatments for experiment 2 were: WS, slurry liquid fraction (LF), composted solid fraction (CSF), LFs treated with BB (LFB), JASS® (LFJ), H2SO4 to a pH of 5.5 (LFA) and soil only (control). The results showed an inhibition of the degradation of organic materials (cellulose, hemicellulose, dry matter organic matter and total carbon) in the WS+H2SO4 relative to the WS. When compared to the WS, the WS+H2SO4 increased electrical conductivity, ammonium (NH4+) and sulphur (S) concentrations whilst reducing slurry pH after storage. The WS+H2SO4 reduced NH3 volatilization by 69% relative to the WS but had no effect on emissions of CH4, CO2 and N2O during storage. Biological additive treatments (WS+EU200 and WS+BB) had no impact on slurry characteristics and gaseous emissions relative to the WS during storage. After field application, the cumulative NH3 lost in the LF was almost 50% lower than the WS. The losses in the LFA were reduced by 92% relative to the LF. The LFB and LFJ had no impact on NH3 losses relative to the LF. A significant effect of treatment on NH4+ concentration was found at the top soil layer (0-5 cm) after NH3 measurements with higher concentrations in the LF treatments relative to the WS. Overall, the use of the above biological additives to decrease pollutant gases and to modify slurry characteristics are questionable. Reducing slurry dry matter through mechanical separation can mitigate NH3 losses after field application. Slurry acidification can increase the fertilizer value (NH4+ and S) of slurry whilst mitigating the environmental impacts through a decrease in NH3 losses during storage and after application.


Assuntos
Fertilizantes , Gases , Esterco , Amônia , Meio Ambiente , Solo
8.
J Environ Manage ; 149: 46-56, 2015 Feb 01.
Artigo em Inglês | MEDLINE | ID: mdl-25463570

RESUMO

Ammonia emissions are a major problem associated with animal slurry management, and solutions to overcome this problem are required worldwide by farmers and stakeholders. An obvious way to minimize ammonia emissions from slurry is to decrease slurry pH by addition of acids or other substances. This solution has been used commonly since 2010 in countries such as Denmark, and its efficiency with regard to the minimization of NH3 emissions has been documented in many studies. Nevertheless, the impact of such treatment on other gaseous emissions during storage is not clear, since the studies performed so far have provided different scenarios. Similarly, the impact of the soil application of acidified slurry on plant production and diffuse pollution has been considered in several studies. Also, the impact of acidification upon combination with other slurry treatment technologies (e.g. mechanical separation, anaerobic digestion …) is important to consider. Here, a compilation and critical review of all these studies has been performed in order to fully understand the global impact of slurry acidification and assess the applicability of this treatment for slurry management.


Assuntos
Ácidos/química , Agricultura/métodos , Amônia/química , Poluição Ambiental/prevenção & controle , Esterco/análise , Solo/química , Amônia/análise , Animais , Dinamarca , Concentração de Íons de Hidrogênio
9.
Front Microbiol ; 15: 1359670, 2024.
Artigo em Inglês | MEDLINE | ID: mdl-38946909

RESUMO

The microbial population in the pig's gastrointestinal tract can be influenced by incorporating fibrous by-products into the diets. This study investigated the impact of including two types of dried olive cake (OC) in pigs' diets on fecal bacterial composition. The correlation between fecal microbiota and growth performance, nutrient digestibility, gut fermentation pattern and slurry gas emissions was also evaluated. Thirty male Pietrain x (Landrace x Large white) pigs (47.9 ± 4.21 kg) were assigned to three groups: a control group (C), a group fed a diet with 20% partially defatted OC (20PDOC), and a group fed a diet with 20% cyclone OC (20COC) for 21 days. Fecal samples collected before and after providing the experimental diets were analyzed for the V3-V4 region of the 16S rRNA gene. Pigs were weighed, and feed intake was recorded throughout the study. Potential ammonia and methane emissions from slurry were measured. No significant differences in alpha diversity indexes were found. The taxonomic analysis revealed that Firmicutes and Bacteroidota phyla were dominant at the phylum level across all groups. Differential abundance analysis using ALDEx showed significant differences among groups for various bacteria at the phylum, genus, and species levels at the end of the experiment. Pigs from 20PDOC and 20COC groups exhibited increased abundances of health-promoting bacteria, such as Plactomycetota at the phylum level and Allisonella and an unidentified genus from the Eggerthellaceae family at the genus level. These changes influenced short-chain fatty acids' (SCFA) concentration in slurries, leading to greater acetic, butyric, caproic and heptanoic acids in OC-fed groups, especially 20COC pigs. A volatility analysis revealed significant positive correlations (p < 0.05) between Uncultured_Bacteroidales and Unculured_Selenomonadaceae and energy digestibility. Monoglobus and Desulfovibrio showed a positive significant (p < 0.05) correlation with total SCFA, indicating a high impact on gut fermentation. However, growth performance parameters and potential gas emission displayed no significant correlations with a specific bacterial genus. In conclusion, our results suggest that OC inclusion into pig diets could positively modulate and contribute to the gut microbiota's favorable composition and functionality. Also, nutrient digestibility and gut fermentation patterns can be associated with specific microbial populations.

10.
Waste Manag ; 178: 231-238, 2024 Apr 15.
Artigo em Inglês | MEDLINE | ID: mdl-38412755

RESUMO

Composting has demonstrated to be an effective and sustainable technology to valorise organic waste in the framework of circular economy, especially for biowaste. Composting can be performed in various technological options, from full-scale plants to community or even individual composters. However, there is scarce scientific information about the potential impact of community composting referred to gaseous emissions. This work examines the emissions of methane and nitrous oxide as main GHG, ammonia, VOC and odours from different active community composting sites placed in Spain, treating kitchen, leftovers and household biowaste. Expectedly, the gaseous emissions have an evident relation with the composting progress, represented mainly by its decrease as temperature or biological activity decreases. GHG and odour emission rates ranged from 5.3 to 815.2 mg CO2eq d-1 kg-1VS and from 69.8 to 1088.5 ou d-1 kg-1VS, respectively, generally being lower than those find in open-air full-scale composting. VOC characterization from the community composting gaseous emissions showed a higher VOC families' distribution in the emissions from initial composting phases, even though terpenes such as limonene, α-pinene and ß-pinene were the most abundant VOC along the composting process occurring in the different sites studied. The results presented in this study can be the basis to evaluate systematically and scientifically the numerous current projects for a worldwide community composting implementation in decentralised biowaste management schemes.


Assuntos
Compostagem , Compostos Orgânicos Voláteis , Humanos , Gases , Odorantes , Amônia/análise , Solo
11.
Bioresour Technol ; 399: 130575, 2024 May.
Artigo em Inglês | MEDLINE | ID: mdl-38479629

RESUMO

Aerobic kitchen waste composting can contribute to greenhouse gas (GHGs) emissions and global warming. This study investigated the effects of biochar and zeolite on GHGs emissions during composting. The findings demonstrated that biochar could reduce N2O and CH4 cumulative releases by 47.7 %and 47.9 %, respectively, and zeolite could reduce the cumulative release of CO2 by 28.4 %. Meanwhile, the biochar and zeolite addition could reduce the abundance of potential core microorganisms associated with GHGs emissions. In addition, biochar and zeolite reduced N2O emissions by regulating the abundance of nitrogen conversion functional genes. Biochar and zeolite were shown to reduce the impact of bacterial communities on GHGs emissions. In summary, this study revealed that biochar and zeolite can effectively reduce GHG emissions during composting by altering the compost microenvironment and regulating microbial community structure. Such findings are valuable for facilitating high-quality resource recovery of organic solid waste.


Assuntos
Compostagem , Gases de Efeito Estufa , Zeolitas , Gases de Efeito Estufa/análise , Zeolitas/química , Solo/química , Metano/análise , Carvão Vegetal , Nitrogênio/análise , Óxido Nitroso/análise
12.
Bioresour Technol ; 407: 131132, 2024 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-39043282

RESUMO

Pyrolysis and combustion experiments were carried out on a single wood pellet in a drop tube furnace, under a heating rate of 5 °C/min. Kinetic modeling was done using the Extended Independent Parallel Reaction model. Three reactions were considered in the pyrolysis case and only one in the combustion case. In the pyrolysis case, a thermal model was proposed which is coupled with the kinetic model to correct the temperature inside the pellet. In the combustion case, the mass rate curve was compared to that of the main gaseous emissions. The mass and mass rate curves between the combustions of a pellet in the drop tube furnace and of pellet sawdust in a thermobalance under the same heating rate were compared.


Assuntos
Temperatura Alta , Madeira , Madeira/química , Cinética , Calefação/métodos , Pirólise , Modelos Químicos , Modelos Teóricos
13.
Sci Total Environ ; 927: 172304, 2024 Jun 01.
Artigo em Inglês | MEDLINE | ID: mdl-38604357

RESUMO

Hyperthermophilic composting, characterized by temperatures equal to or exceeding 75 °C, offers superior compost maturity and performance. Inoculation with thermophilic bacteria presents a viable approach to achieving hyperthermophilic composting. This study investigates the effects of inoculating thermophilic bacteria, isolated at different temperatures (50 °C, 60 °C, and 70 °C) into compost on maturity, gaseous emissions, and microbial community dynamics during co-composting. Results indicate that the thermophilic bacteria inoculation treatments exhibited peak temperature on Day 3, with the maximum temperature of 75 °C reached two days earlier than the control treatment. Furthermore, these treatments demonstrated increased bacterial richness and diversity, along with elevated relative abundances of Firmicutes and Proteobacteria. They also fostered mutualistic correlations among microbial species, enhancing network connectivity and complexity, thereby facilitating lignocellulose degradation. Specifically, inoculation with thermophilic bacteria at 60 °C increased the relative abundance of Thermobifida and unclassified-f-Thermomonosporaceae (Actinobacteriota), whereas Bacillus, a thermophilic bacterium, was enriched in the 70 °C inoculation treatment. Consequently, the thermophilic bacteria at 60 °C and 70 °C enhanced maturity by 36 %-50 % and reduced NH3 emissions by 1.08 %-27.50 % through the proliferation of thermophilic heterotrophic ammonia-oxidizing bacteria (Corynebacterium). Moreover, all inoculation treatments decreased CH4 emissions by 6 %-27 % through the enrichment of methanotrophic bacteria (Methylococcaceae) and reduced H2S, Me2S, and Me2SS emissions by 1 %-25 %, 47 %-63 %, and 15 %-53 %, respectively. However, the inoculation treatments led to increased N2O emissions through enhanced denitrification, as evidenced by the enrichment of Truepera and Pusillimonas. Overall, thermophilic bacteria inoculation promoted bacteria associated with compost maturity while attenuating the relationship between core bacteria and gaseous emissions during composting.


Assuntos
Bactérias , Compostagem , Microbiota , Microbiologia do Solo , Compostagem/métodos , Microbiota/fisiologia , Temperatura Alta , Poluentes Atmosféricos/análise
14.
Chemosphere ; 352: 141484, 2024 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-38368962

RESUMO

The production of biofuels to be used as bioenergy under combustion processes generates some gaseous emissions (CO, CO2, NOx, SOx, and other pollutants), affecting living organisms and requiring careful assessments. However, obtaining such information experimentally for data evaluation is costly and time-consuming and its in situ obtaining for regional biomasses (e.g., those from Northeast Brazil (NEB) is still a major challenge. This paper reports on the application of artificial neural networks (ANNs) for the prediction of the main air pollutants (CO, CO2, NO, and SO2) produced during the direct biomass combustion (N2/O2:80/20%) with the use of ultimate analysis (carbon, hydrogen, nitrogen, sulfur, and oxygen). 116 worldwide biomasses were used as input data, which is a relevant alternative to overcome the lack of experimental resources in NEB and obtain such information. Cross-validation was conducted with k-fold to optimize the ANNs and performance was analyzed with the use of statistical errors for accuracy assessments. The results showed an acceptable statistical performance for all architectures of ANNs, with 0.001-12.41% MAPE, 0.001-5.82 mg Nm-3 MAE, and 0.03-52.30 mg Nm-3 RMSE, highlighting the high precision of the emissions studied. On average, the differences between predicted and real values for CO, CO2, NO, and SO2 emissions from NEB biomasses were approximately 0.01%, 10-6%, 0.14%, and 0.05%, respectively. Pearson coefficient provided consistent results of concentration of the ultimate analysis in relation to the emissions studied and effectiveness of the test set in the developed models.


Assuntos
Poluentes Atmosféricos , Poluentes Atmosféricos/análise , Biomassa , Dióxido de Carbono/análise , Gases/análise , Redes Neurais de Computação
15.
Chemosphere ; 352: 141457, 2024 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-38378050

RESUMO

This study assessed the impact of different plant-derived biochar (cornstalk, rice husk, and sawdust) on bacterial community and functions for compost maturity and gaseous emissions during the composting of food waste. Results showed that all biochar strengthened organic biotransformation and caused a higher germination index on day 12 (over 100%), especially for rice husk biochar to enhance the growth of Thermobifida related to aerobic chemoheterotrophy. Rice husk biochar also achieved a relatively higher reduction efficiency of methane (85.8%) and ammonia (82.7%) emissions since its greater porous structure. Besides, the growth of Pseudomonas, Pusillimonas, and Desulfitibacter was restricted to constrict nitrate reduction, nitrite respiration, and sulfate respiration by optimized temperature and air permeability, thus reducing nitrous oxide and hydrogen sulfide emissions by 48.0-57.3% by biochar addition. Therefore, rice husk biochar experienced the optimal potential for maturity increment and gaseous emissions mitigation.


Assuntos
Compostagem , Eliminação de Resíduos , Gases , Perda e Desperdício de Alimentos , Nitrogênio/análise , Alimentos , Solo/química , Carvão Vegetal , Esterco
16.
Chemosphere ; 317: 137881, 2023 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-36657582

RESUMO

Recycling nutrients is of paramount importance. For this reason, struvite and nitrogen enriched zeolite fertilizers produced from wastewater treatments are receiving growing attention in European markets. However, their effects on agricultural soils are far from certain, especially struvite, which only recently was implemented in EU Fertilizing Product Regulations. In this paper, we investigate the effects of these materials in acid sandy arable soil, particularly focusing on N dynamics, evaluating potential losses, transformation pathways, and the effects of struvite and zeolitic tuffs on main soil biogeochemical parameters, in comparison to traditional fertilization with digestate. Liming effect (pH alkalinization) was observed in all treatments with varying intensities, affecting most of the soil processes. The struvite was quickly solubilized due to soil acidity, and the release of nutrients stimulated nitrifying and denitrifying microorganisms. Zeolitic tuff amendments decreased the NOx gas emissions, which are precursors to the powerful climate altering N2O gas, and the N enriched chabazite tuff also recorded smaller NH3 emissions compared to the digestate. However, a high dosage of zeolites in soil increased NH3 emissions after fertilization, due to pronounced pH shifts. Contrasting effects were observed between the two zeolitic tuffs when applied as soil amendments; while the chabazite tuff had a strong positive effect - increasing up to ∼90% the soil microbial N immobilization - the employed clinoptilolite tuff had immediate negative effects on the microbial biomass, likely due to the large quantities of sulphur released. However, when applied at lower dosages, the N enriched clinoptilolite also contributed to the increase of microbial N. From these outcomes, we confirm the potential of struvite and zeolites to mitigate the outfluxes of nutrients from agricultural systems. To gain the best results and significantly lower environmental impacts, extension practitioners could give recommendations based on the soils that are planned for zeolite application.


Assuntos
Zeolitas , Zeolitas/química , Nitrogênio/química , Estruvita , Agricultura , Solo/química , Fertilizantes , Óxido Nitroso/análise
17.
Sci Total Environ ; 889: 164239, 2023 Sep 01.
Artigo em Inglês | MEDLINE | ID: mdl-37196963

RESUMO

This study assessed the impact of aeration intensity on food waste digestate composting to simultaneously govern organic humification and gaseous emissions. Results show that an augment in the aeration intensity from 0.1 to 0.4 L·kg-1 DM·min-1 provided more oxygen to facilitate organic consumption and thus temperature increase, but slightly restrained organic humification (e.g. less humus content and higher E4/E6 ratio) and substrate maturity (i.e. lower germination index). Furthermore, increasing aeration intensity inhibited the proliferation of the genera Tepidimicrobium and Caldicoprobacter to alleviate methane emission and enriched the genus Atopobium to boost hydrogen sulphide production. More importantly, increasing aeration intensity limited the growth of the genus Acinetobacter for nitrite/nitrogen respiration, but strengthened aerodynamics to blow out nitrous oxide and ammonia produced inside piles. Principal component analysis comprehensively indicated that a low aeration intensity of 0.1 L·kg-1DM·min-1 facilitated precursors synthesis toward humus and simultaneously mitigated gaseous emissions to improve food waste digestate composting.


Assuntos
Compostagem , Eliminação de Resíduos , Gases , Alimentos , Solo
18.
Bioresour Technol ; 382: 129199, 2023 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-37201868

RESUMO

The purpose of current study was to probe the effect of various length of branch on gaseous emissions and vital enzymatic activity. Four lengths (< 2 cm, 2 cm, 5 cm, and > 5 cm) of clipped branch were mingled with collected pig manure for 100 days aerobic fermentation. The consequence demonstrated that the amendment of 2 cm of branch showed conducive to decline the greenhouse gas emissions, which the CH4 emissions decreased by 1.62-40.10%, and the N2O emissions decreased by 21.91-34.04% contrasted with other treatments. Furthermore, the peak degree of enzymatic activities was also observed in 2 cm of branch treatment by the optimizing living condition for microbes. In view of microbiological indicators, the most abundant and complex bacterial community could be monitor in 2 cm of branch composting pile, which verified the microbial facilitation. Summing up, the strategy of 2 cm branch amendment would be recommended.


Assuntos
Compostagem , Gases de Efeito Estufa , Suínos , Animais , Gases , Esterco , Tamanho da Partícula , Solo
19.
Heliyon ; 9(3): e13982, 2023 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-36895387

RESUMO

The presented scientific study deals with the environmental and energetic aspects concerning application of the experimental fuels in high-powerful engines. This study analyses the most important results from the experimental tests realised on the motorbike engine in the case of two testing regimes: at first using a standardly produced combustion engine and then with the adjusted engine configuration designed in order to improve efficiency of the combustion process. There were tested and compared each other three different engine fuels in framework of the presented research work. The first fuel was the top experimental fuel 4-SGP, which is world-widely applied in the motorbike competitions. The second fuel was the experimental and sustainable fuel, which is called superethanol E-85. This fuel was developed in order to reach the highest power output and the lowest engine gaseous emissions. The third was a standard fuel, which is normally at disposal. Besides that, there were created also the experimental fuel mixtures. Their power output and emissions were tested, too.

20.
J Hazard Mater ; 453: 131365, 2023 07 05.
Artigo em Inglês | MEDLINE | ID: mdl-37080030

RESUMO

Large variabilities in ammonia (NH3) released from animal manure and emitted from different livestock buildings were frequently reported, but the factors influencing the emissions were not sufficiently investigated. In this paper, continuously monitored data of NH3 emissions and other relevant environmental variables under controlled conditions in a 12-room experimental swine building for a 155-d complete wean-to-finish cycle were studied. Measurement data mining was conducted at both spatial and temporal dimensions using panel data analysis with heterogeneous time trends. The pig diet, total pig weight, and the pit air temperature were identified as the major influencing factors for the variabilities by using multivariate linear regression. Two unidentified factors that imposed substantial influences on the NH3 emission variabilities were predicted. They were most possibly related to variations in microenvironment and microbial activity inside the manure in the pit. The results suggest necessary future research to identify physical properties of the new NH3 emissions factors in microbiological and biochemical processes.


Assuntos
Amônia , Esterco , Suínos , Animais , Amônia/análise , Esterco/análise , Dieta
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