Chemical and mechanical properties of dual-polymerizing core build-up materials.

OBJECTIVES: To investigate the chemical (degree of conversion (DC)) and mechanical properties (Martens hardness (HM), elastic indentation modulus (EIT), and biaxial flexural strength (BFS)) of four dual-polymerizing resin composite core build-up materials after light- and self-polymerization. MATERIALS AND METHODS: Round specimens with a diameter of 12 mm and a thickness of 1.5 mm were manufactured from CLEARFIL DC CORE PLUS (CLE; Kuraray), core·X flow (COR; Dentsply Sirona), MultiCore Flow (MUL; Ivoclar Vivadent), and Rebilda DC (REB; VOCO) (N = 96, n = 24/material). Half of the specimens were light-polymerized (Elipar DeepCure-S, 3 M), while the other half cured by self-polymerization (n = 12/group). Immediately after fabrication, the DC, HM, EIT, and BFS were determined. Data was analyzed using Kolmogorov-Smirnov, Mann-Whitney U, and Kruskal-Wallis tests, Spearman's correlation, and Weibull statistics (p < 0.05). RESULTS: Light-polymerization either led to similar EIT (MUL; p = 0.119) and BFS (MUL and REB; p = 0.094-0.326) values or higher DC, HM, EIT, and BFS results (all other groups; p < 0.001-0.009). When compared with the other materials, COR showed a high DC (p < 0.001) and HM (p < 0.001) after self-polymerization and the highest BFS (p = 0.020) and Weibull modulus after light-polymerization. Positive correlations between all four tested parameters (R = 0.527-0.963, p < 0.001) were found. CONCLUSIONS: For the tested resin composite core build-up materials, light-polymerization led to similar or superior values for the degree of conversion, Martens hardness, elastic indentation modulus, and biaxial flexural strength than observed after self-polymerization. Among the tested materials, COR should represent the resin composite core build-up material of choice due to its high chemical (degree of conversion) and mechanical (Martens hardness, elastic indentation modulus, and biaxial flexural strength) properties and its high reliability after light-polymerization. The examined chemical and mechanical properties showed a positive correlation. CLINICAL RELEVANCE: The chemical and mechanical performance of dual-polymerizing resin composite core build-up materials is significantly affected by the chosen polymerization mode.

Time-dependent degree of conversion, Martens parameters, and flexural strength of different dual-polymerizing resin composite luting materials.

OBJECTIVE: To investigate the degree of conversion (DC), Martens hardness (HM), elastic indentation modulus (EIT), and biaxial flexural strength (BFS) of six dual-polymerizing resin composite luting materials initially and after 2 and 7 days of aging. MATERIALS AND METHODS: Specimens fabricated from Bifix QM (BIF; VOCO), Calibra Ceram (CAL; Dentsply Sirona), DuoCem (DUO; Coltène/Whaledent), G-CEM LinkForce (GCE; GC Europe), PANAVIA V5 (PAN; Kuraray Europe), and Variolink Esthetic DC (VAR; Ivoclar Vivadent) (n = 12 per material) were light-polymerized through 1 mm thick discs (Celtra Duo, Dentsply Sirona). DC, HM, and EIT were recorded directly after fabrication, and after 2 and 7 days of aging. As a final test, BFS was measured. Univariate ANOVAs, Kruskal-Wallis, Mann-Whitney U, Friedman, and Wilcoxon tests, and Weibull modulus were computed (p < 0.05). RESULTS: While CAL presented low DC, HM, EIT, and BFS values, DUO and BIF showed high results. Highest Weibull moduli were observed for VAR and DUO. DC and Martens parameters increased between the initial measurement and 2 days of aging, while aging for 7 days provided no further improvement. CONCLUSIONS: The choice of dual-polymerizing resin composite luting material plays an important role regarding chemical and mechanical properties, especially with patients sensitive to toxicological issues. DUO may be recommended for bonding fixed dental prostheses, as it demonstrated significantly highest and reliable results regarding DC, HM, and BFS. As DC and HM showed an increase in the first 48 h, it may be assumed that the polymerization reaction is not completed directly after initial polymerization, which is of practical importance to dentists and patients. CLINICAL RELEVANCE: The chemical and mechanical properties of dual-polymerizing resin composite luting materials influence the overall stability and long-term performance of the restoration.

Water-induced Effects on the Hardness and Modulus of Contemporary Sealants Derived from Instrumented Indentation Testing (IIT).

AIM: To compare the mechanical properties of four different types of contemporary fissure sealants before and after water storage employing a modern instrumented indentation testing (IIT) method. MATERIALS AND METHODS: Four different types of materials used in everyday practice were deliberately selected. Fissurit (FIS) is a highly filled resin, Embrace (EMB) is a bisphenol A (BPA)-free unfilled resin, Helioseal (HEL) is an unfilled resin, and Riva Protect (RIV) is a glass-ionomer material. Six cylindrical specimens from each material were prepared (h: 3 mm, Ø: 15 mm), and Martens hardness (HM), elastic modulus (EIT), elastic index (ηIT), and Vickers hardness (HV) were determined employing an IIT machine according to International Organization for Standardization (ISO) 14577:2015. Then, the samples were stored in water at 37°C for 48 hours and measured again at the same surface. The mechanical properties tested (HM, EIT, ηIT, and HV) were statistically analyzed by two-way repeated measurements analysis of variance (ANOVA) employing materials and conditions as discriminating variables. Statistically significant differences were identified by Tukey's post hoc multiple comparison test. In all cases, a 95% level of significance was set (p = 0.05). RESULTS: Statistically significant differences in selected mechanical properties were allocated among materials tested. The artificial aging had a detrimental effect on HM, EIT, and HV apart from ηIT for FIS, EMB, and HEL. In contrast, no significant differences were identified for RIV before and after water storage for all aforementioned properties apart from ηIT. CONCLUSION: Significant differences were identified in mechanical properties among materials tested and thus differences in their clinical behavior are anticipated. CLINICAL SIGNIFICANCE: This study contributes to the understanding of the mechanical properties of different dental sealants with respect to water contact, which may influence the choice by the therapist.

Mechanical and physical properties of splint materials for oral appliances produced by additive, subtractive and conventional manufacturing.

OBJECTIVES: To investigate the flexural strength (FS), elastic modulus (E), Martens hardness (HM), water sorption (wsp), water solubility (wsl) and degree of conversion (DC) of 3D-printed, milled and injection molded splint materials. METHODS: Specimens (N = 1140) were fabricated from five 3D-printed (GR-22 flex, GR-10 guide, ProArt Print Splint clear, V-Print Splint, V-Print Splint comfort), five milled (BioniCut, EldyPlus, ProArt CAD Splint clear, Temp Premium Flexible, Thermeo) and two injection molded (PalaXPress clear, Pro Base Cold) materials. FS, E, HM, wsp, wsl and DC were tested initially (24 h, 37 °C, H2O), after water storage (90 d, 37 °C, H2O) as well as after thermal cycling (5000 thermal cycles, 5/55 °C). Data were analyzed with Kolmogorov-Smirnov, Kruskal- Wallis, Mann-Whitney U test and Spearman's correlation (p < 0.05). RESULTS: Initially, the mean flexural strength values ranged from 1.9 to 90.7 MPa for printed, 3.8 to 107 MPa for milled and 99.7 to 102 MPa for injection molded materials. The initial mean elastic modulus values were 0.0 to 2.4 GPa for printed, 0.1 to 2.7 GPa for milled and 2.8 GPa for injection molded materials. The initial mean Martens hardness values were 14.5 to 126 N/mm2 for printed, 50.2 to 171 N/mm2 for milled and 143 to 151 N/mm2 for injection molded materials. Initially, the mean water sorption values ranged from 23.1 to 41.2 µg/mm3 for printed, 4.5 to 23.5 µg/mm3 for milled and from 22.5 to 23.3 µg/ mm3 for injection molded materials. The initial mean water solubility values ranged from 2.2 to 7.1 µg/mm3 for printed, 0.0 to 0.5 µg/mm3 for milled and 0.1 to 0.3 µg/mm3 for injection molded materials. After water storage and thermal cycling most of the values decreased and some increased. The mean DC values ranged initially from 72.3 to 94.5 %, after water storage from 74.2 to 96.8 % and after thermal cycling from 75.6 to 95.4 % for the printed materials. SIGNIFICANCE: The mechanical and physical properties of printed, milled and injection molded materials for occlusal devices vary and are influenced by aging processes. For clinical applications, materials need to be chosen according to the specific indications.

Effects of printing orientation and artificial ageing on martens hardness and indentation modulus of 3D printed restorative resin materials.

BACKGROUND: Three-dimensional (3D) printing is increasingly used to fabricate dental restorations due to its enhanced precision, consistency and time and cost-saving advantages. The properties of 3D-printed resin materials can be influenced by the chosen printing orientation which can impact the mechanical characteristics of the final products. PURPOSE: The objective of this study was to evaluate the influence of printing orientation and artificial ageing on the Martens hardness (HM) and indentation modulus (EIT) of 3D-printed definitive and temporary dental restorative resins. METHODS: Disk specimens (20 mm diameter × 2 mm height) were additively manufactured in three printing orientations (0°, 45°, 90°) using five 3D-printable resins: VarseoSmile Crownplus (VCP), Crowntec (CT), Nextdent C&B MFH (ND), Dima C&B temp (DT), and GC temp print (GC). The specimens were printed using a DLP 3D-printer (ASIGA MAX UV), while LavaTM Ultimate (LU) and Telio CAD (TC) served as milled control materials. Martens hardness (HM) and indentation modulus (EIT) were tested both before and after storage in distilled water and artificial saliva for 1, 30, and 90 days at 37 °C. RESULTS: 90° printed specimens exhibited higher HM than the other orientations at certain time points, but no significant differences were observed in HM and EIT between orientations for all 3D-printed materials after 90 days of ageing in both aging media. LU milled control material exhibited the highest HM and EIT among the tested materials, while TC, the other milled control, showed similar values to the 3D printed resins. CT and VCP (definitive resins) and ND displayed higher Martens parameters compared to DT and GC (temporary resins). The hardness of the 3D-printed materials was significantly impacted by artificial ageing compared to the controls, with ND having the least hardness reduction percentage amongst all 3D-printed materials. The hardness reduction percentage in distilled water and artificial saliva was similar for all materials except for TC, where higher reduction was noted in artificial saliva. SIGNIFICANCE: The used 3D printed resins cannot yet be considered viable alternatives to milled materials intended for definitive restorations but are preferable for use as temporary restorations.

3D printed denture base material: The effect of incorporating TiO2 nanoparticles and artificial ageing on the physical and mechanical properties.

OBJECTIVES: To evaluate the physical and mechanical properties of three-dimensional (3D) printed denture base resin incorporating TiO2 nanoparticles (NPs), subjected to a physical ageing process. METHODS: Acrylic denture base samples were prepared by a Stereolithography (SLA) 3D printing technique reinforced with different concentrations (0.10, 0.25, 0.50, and 0.75) of silanated TiO2 NPs. The resulting nanocomposite materials were characterized in terms of degree of conversion (DC), and sorption/solubility flexural strength, impact strength, Vickers hardness and Martens hardness and compared with unmodified resin and conventional heat-cured (HC) material. The nanocomposites were reassessed after subjecting them to ageing in artificial saliva. A fractured surface was studied under a scanning electron microscope (SEM). RESULTS: The addition of TiO2 NPs into 3D-printed resin significantly improved flexural strength/modulus, impact strength, Vickers hardness, and DC, while also slightly enhancing Martens hardness compared to the unmodified resin. Sorption values did not show any improvements, while solubility was reduced significantly. The addition of 0.10 wt% NPs provided the highest performance amongst the other concentrations, and 0.75 wt% NPs showed the lowest. Although ageing degraded the materials' performance to a certain extent, the trends remained the same. SEM images showed a homogenous distribution of the NPs at lower concentrations (0.10 and 0.25 wt%) but revealed agglomeration of the NPs with the higher concentrations (0.50 and 0.75 wt%). SIGNIFICANCE: The outcomes of this study suggested that the incorporation of TiO2 NPs (0.10 wt%) into 3D-printed denture base material showed superior performance compared to the unmodified 3D-printed resin even after ageing in artificial saliva. The nanocomposite has the potential to extend service life of denture bases in future clinical use.

Effect on martens hardness and pushout bond strength of fiber post to canal dentin final irrigated with fotoenticine, chitosan, and ozone.

AIMS: To estimate the effect of contemporary final root canal irrigants (Ozonated water (OW), Chitosan, and Fotoenticine (FTC) on the bond scores of glass fiber post (GFP) and Martens hardness (MH) of root dentin. MATERIALS AND METHODS: Sixty extracted human premolars having a single straight canal that ends in a closed apex were included. Specimens were de-crowned till the cementoenamel junction preserving 12 mm of root length and were mounted vertically. Canal therapy was performed using a crown-down approach. Obturation was performed followed by post-space preparation. Samples were allocated into 4 groups based on chemical irrigations and photosensitizers used(n = 15). Group 1 (5.25% NaOCl + 17% EDTA), group 2 (5.25% NaOCl + FTC), group 3 (5.25% NaOCl + Chitosan), group 4 (5.25% NaOCl + OW). The ultra microhardness tester was put under a load of 5 mN at a speed of 1.5 mN/s for 1 s to assess the MH. The fiber post was luted with dual-cure cement and slices of 1 mm were prepared from each third of the tooth. PBS and failure mode analysis were performed using a universal testing machine (UTM) and stereomicroscope respectively. ANOVA and Tukey multiple comparisons t-tests for assessment of PBS and MH p > 0.05 RESULTS: Group 1 (5.25% NaOCl + 17% EDTA) exhibited the highest MH (0.19 ± 0.04 GPa). Whereas, group 2 (5.25% NaOCl + FTC) displayed the lowest MH (0.011 ± 0.14 GPa). The highest PBS was exhibited by the coronal third of group 1 (5.25% NaOCl + 17% EDTA) (7.11 ± 0.81 MPa). The apical section of group 3 specimens (5.25% NaOCl + Chitosan) (2.33 ± 0.26 MPa) unveiled the lowest PBS. Intergroup comparison analysis revealed that group 2 and group 3 displayed comparable outcomes of PBS. Group 1 and Group 4 also demonstrated no significant difference in the bond scores in all three sections. CONCLUSION: OW as a final irrigant can be used as an alternative to EDTA as it improves the bond strength with minimum impact on marten hardness.

Resin-Based Bulk-Fill Composites: Tried and Tested, New Trends, and Evaluation Compared to Human Dentin.

A more-and-more-accepted alternative to the time-consuming and technique-sensitive, classic, incremental-layering technique of resin-based composites (RBCs) is their placement in large increments. The so-called bulk-fill RBCs had to be modified for a higher polymerization depth and already have a 20-year history behind them. From the initial simple mechanisms of increasing the depth of cure by increasing their translucency, bulk-fill RBCs have evolved into complex materials with novel polymerization mechanisms and bioactive properties. However, since the materials are intended to replace the tooth structure, they must be comparable in mechanical behavior to the substance they replace. The study compares already established bulk-fill RBCs with newer, less-studied materials and establishes their relationship to dentin with regard to basic material properties such as hardness and indentation modulus. Instrumented indentation testing enables a direct comparison of tooth and material substrates and provides clinically relevant information. The results underline the strong dependence of the measured properties on the amount of filler in contrast to the small influence of the material classes into which they are classified. The main difference of RBCs compared to dentin is a comparable hardness but a much lower indentation modulus, emphasizing further development potential.

Effects of three food-simulating liquids on the roughness and hardness of CAD/CAM polymer composites.

OBJECTIVE: Implant-supported frameworks constructed from high-performance polymer CAD/CAM composites are exposed to liquids from the oral environment and routine care maintenance. Therefore, this study investigated the effect of food-simulating liquids (FSLs) on surface properties of three CAD/CAM polymer composite blocks. METHODS: The composites investigated were (i) a carbon fibre-reinforced composite (CarboCAD 3D dream frame; CC), (ii) a glass fibre-reinforced composite (TRINIA; TR), and (iii) a reinforced PEEK (DentoKeep; PK). The filler contents were determined by thermo-gravimetry. The surface properties were roughness, Vickers hardness (HV), properties measured by Martens force/depth indentation, namely: hardness (HM), modulus (EIT) and creep (CIT). Property measurements were made at baseline on polished specimens and then, where possible, after 1- and 7-days storage at 37 â„ƒ in three different media: water, 70% ethanol/water and MEK (methyl ethyl ketone). Specimens were selected for light and scanning electron microscopy. Statistical analysis was performed by two-way repeated measures ANOVA, one-way ANOVA, and multiple comparison tests (α = 0.05). RESULTS: The baseline roughness and hardness (HV, HM) and modulus (EIT) correlated approximately with filler content (wt%), with the fibre-reinforced composites being rougher, harder and stiffer than PK. At baseline, roughness (Sa) ranged from 0.202 to 0.268 µm; HV from 23.1 to 36.9; HM from 224.5 to 330.6 N/mm2; EIT: from 6 to 9.8 GPa. After ageing in 70% ethanol and MEK, more pronounced roughness and hardness changes were observed than in water. MEK caused greater deterioration for the FRC than 70% ethanol, while PK specimens showed slight changes in 70% ethanol. SIGNIFICANCE: Storage media adversely affected the surface and mechanical properties of each CAD/CAM composite. However, during ageing, the reinforced PEEK showed greater relative stability in these properties. Nevertheless, the deterioration may indicate the need for full protection by a veneer material on each surface of an implant-supported framework.

Effect of CAD/CAM aesthetic material thickness and translucency on the polymerisation of light- and dual-cured resin cements.

OBJECTIVES: This study investigated potential variations in polymerisation of light- and dual-cured (LC and DC) resin cements photoactivated through four CAD/CAM restorative materials as a function of substrate thickness. METHODS: Four CAD/CAM materials [two resin composites CeraSmart (CS) and Grandio Blocs (GB); a polymer infiltrated ceramic Vita Enamic (VE) and a feldspathic ceramic Vita Mark II (VM)], with five thicknesses (0.5, 1, 1.5, 2, and 2.5 mm) were prepared and their optical characteristics measured. 1 mm discs of LC and DC resin cement (Variolink® Esthetic, Ivoclar AG) were photoactivated through each specimen thickness. After 1 h post-cure, polymerisation efficiency was determined by degree of conversion (DC%) and Martens hardness (HM). Interactions between materials, thicknesses and properties were analysed by linear regressions, two-way ANOVA and one-way ANOVA followed by post hoc multiple comparisons (α = 0.05). RESULTS: All substrates of 0.5- and 1.0-mm thickness transmitted sufficiently high peak irradiances at around 455 nm: (It = 588-819 mW/cm2) with translucency parameter TP = 21.14 - 10.7; ranked: CS> GB = VM> VE. However, increasing the substrate thickness (1.5-2.5 mm) reduced energy delivery to the luting cements (4 - 2.8 J/cm2). Consequently, as their thicknesses increased beyond 1.5 mm, HM of the cement discs differed significantly between the substrates. But there were only slight reduction of DC% in LC cements and DC cement discs were not affected. SIGNIFICANCE: Photoactivating light-cured Ivocerin™ containing cement through feldspathic ceramics and polymer-infiltrated ceramics achieved greater early hardness results than dual-cured type, irrespective of substrate thickness (0.5 - 2.5 mm). However, only 0.5 and 1 mm-thick resin composites showed similar outcome (LC>DC). Therefore, for cases requiring early hardness development, appropriate cement selection for each substrate material is recommended.

Damping Behaviour and Mechanical Properties of Restorative Materials for Primary Teeth.

The energy dissipation capacity and damping ability of restorative materials used to restore deciduous teeth were assessed compared to common mechanical properties. Mechanical properties (flexural strength, modulus of elasticity, modulus of toughness) for Compoglass F, Dyract eXtra, SDR flow, Tetric Evo Ceram, Tetric Evo Ceram Bulk Fill, and Venus Diamond were determined using a 4-point bending test. Vickers hardness and Martens hardness, together with its plastic index (ηITdis), were recorded using instrumented indentation testing. Leeb hardness (HLD) and its deduced energy dissipation data (HLDdis) were likewise determined. The reliability of materials was assessed using Weibull analysis. For common mechanical properties, Venus Diamond always exhibited the significantly highest results and SDR flow the lowest, except for flexural strength. Independently determined damping parameters (modulus of toughness, HLDdis, ηITdis) invariably disclosed the highest values for SDR flow. Composite materials, including SDR flow, showed markedly higher reliabilities (Weibull modulus) than Compoglass F and Dyract eXtra. SDR flow showed pronounced energy dissipation and damping characteristics, making it the most promising material for a biomimetic restoration of viscoelastic dentin structures in deciduous teeth. Future developments in composite technology should implement improved resin structures that facilitate damping effects in artificial restorative materials.

Methodology investigation: Impact of crown geometry, crown, abutment and antagonist material and thermal loading on the two-body wear of dental materials.

OBJECTIVES: To investigate the impact of crown geometry, crown/abutment/antagonist material and thermal loading on the two-body wear of dental materials caused by chewing simulation. MATERIALS AND METHODS: For the crown geometry, crowns (polymethylmethacrylate (PMMA), polyetheretherketone (PEEK) and silicate ceramic (SiO2)) were milled with a flat, steep, or medium cusp inclination (CINC). For the crown/abutment material, crowns (PMMA, PEEK and SiO2) were combined with PMMA, polymer-infiltrated-ceramic-network (PICN), cobalt-chrome alloy (CoCr) and natural teeth (ENAM) abutments. For the antagonist material, antagonists were fabricated from PICN, CAD/CAM resin composite (RECO), steatite (STEA), steel (STL) and ENAM and tested against flat specimens (substrates) made of veneering ceramic (VC). For thermal loading, the duration (30 s, 60 s, 120 s) and presence of temperature changes (37 °C versus 5 °C/55 °C) was varied. Material losses were determined by matching scanned specimens before and after aging (400,000 chewing cycles, 50 N, 1.3 Hz). Martens parameters were determined for the antagonists/substrates. Data were analyzed using Kolmogorov-Smirnov-test, Kruskal-Wallis H, Scheffé-Post-Hoc-tests, pairwise comparisons, Bonferroni correction, one-way ANOVA, Mann-Whitney-U and Spearman rho. RESULTS: PMMA crowns presented the highest and PEEK the lowest material losses. Flat CINC showed the lowest material losses for PEEK and SiO2 crowns. CoCr and ENAM abutments presented material losses in the same range. Antagonist and cumulative material losses for RECO and ENAM were similar. Thermal loading did not influence material losses. SIGNIFICANCE: Crown geometry influences the crown and antagonists wear, with an increased cusp inclination entailing increased wear. For in vitro set-ups, CoCr abutments and RECO antagonists present valid alternatives to natural teeth. For polymers, in vitro chewing simulations may be performed at a constant temperature (37 °C).

Mechanical and optical properties of indirect veneering resin composites after different aging regimes.

This study tested and compared properties of six modern indirect veneering resin composites (VRC), namely Ceramage (Shofu), dialog Vario (Schütz Dental), Gradia Plus (GC Europe), in:joy (Dentsply), Signum composite (Heraeus Kulzer), and SR Nexco (Ivoclar Vivadent). Specimens were fabricated from dentin and enamel pastes and following properties were analyzed: (1) two-body wear (TB), (2) surface roughness (SR), (3) Martens hardness parameters (HM and EIT), and (4) translucency (T). The highest impact on HM and EIT was exerted by VRC brand (HM: ηP2=0.960/ EIT: ηP2=0.968; p<0.001), followed by VRC paste material (HM: ηP2=0.502/ EIT: ηP2=0.580; p<0.001), and aging duration (HM: ηP2=0.157/ EIT: ηP2=0.112; p<0.001). Lowest and highest TB were measured for Signum composite and dialog Vario, respectively (p<0.001). Highest T was showed Signum composite and Ceramage (p<0.001). VRCs should be individually selected with respect to the indication area, due to different surface properties.

The Effect of Touch-Cure Polymerization on the Conversion and Hardness of Core Build-Up Resin Composites: A Laboratory Study.

To improve the self-curing capacity and interfacial strength with dentine of dual-cured composite materials, touch-cure activators have been introduced. The aim of the study was to evaluate the effect of these activators on the hardness and conversion of dual-cured resin composite core build-up restoratives. The materials tested were Clearfil DC Core Plus (CF) and Gradia Core (GC) with the corresponding adhesives Clearfil S3 Bond Plus (for CF) and G-Premio Bond/G-Premio DCA activator (for GC). Disk-shaped specimens (n = 6/group) were prepared for the following groups: dual-cured, self-cured and self-cured in contact with the adhesive activators at the bottom surface. After a 3-week storage period (dark/dry/37 °C) the Martens hardness (HM) and degree of conversion (DC%) were determined for the previously mentioned groups and the top surfaces of groups in contact with the adhesives. A statistical analysis was performed by a one-way ANOVA and Holm-Sidak test per material and a Pearson's correlation analysis (HM vs. DC%) at an α = 0.05. The self-cured specimens resulted in significantly lower HM and DC% values from the dual-cured group, as expected. However, in the presence of the adhesives with touch-cure activators, the conversion of the self-cured groups showed insignificant differences in HM and DC% from the dual-cured in both composite materials. The improvements on the bottom composite surfaces in contact with the adhesives did not extend to the entire specimen length. Nevertheless, improved interfacial curing may improve interfacial durability.

Impact of polymerization and storage on the degree of conversion and mechanical properties of veneering resin composites.

To investigate the degree of conversion (DC), Martens hardness (HM), elastic indentation modulus (EIT), and flexural strength (FS) of veneering resin composites (SR Nexco Paste (NP), Ceramage Incisal (CI), Gradia Plus (GP); n=60/group) cured with different polymerization devices (bre.Lux Power Unit, Labolight DUO, Otoflash G171, LC-3DPrint Box, PCU LED; n=12/subgroup) after storage. Otoflash G171 and Labolight DUO showed increased DC/HM/EIT. CI presented the lowest DC and highest HM/EIT. NP showed the highest DC and lowest HM/EIT. Within Otoflash G171, Laboligth DUO and PCU LED, highest FS was observed for CI. Storage did not affect DC/HM/EIT for specimens cured with Otoflash G171 or Labolight DUO. With storage not showing an influence on the tested parameters for polymerization devices that otherwise presented superior results, increased storage time cannot be recommended. For the tested resin composites, this study observed a high/low degree of conversion to coincide with respectively low/high amounts of fillers/mechanical properties.

Modern CAD/CAM silicate ceramics, their translucency level and impact of hydrothermal aging on translucency, Martens hardness, biaxial flexural strength and their reliability.

OBJECTIVES: To investigate the impact of hydrothermal aging on Martens parameter (Martens hardness: HM/elastic indentation modulus: EIT) and biaxial flexural strength (BFS) of recently available CAD/CAM silicate ceramics. METHODS: 220 specimens (diameter: 12 mm, thickness: 0.95 mm) were fabricated from six CAD/CAM ceramics in two translucency levels (LT/HT): (a) two lithium disilicate (Amber Mill, ABM; IPS e.max CAD, IEM), (b) one lithium metasilicate (Cetra Duo, CEL), (c) one lithium alumina silicate (n!ce, NIC), and (d) two leucite ceramics (Initial LRF Block, LRF; IPS Empress CAD, IPR). HM/EIT and BFS were measured initially and after hydrothermal aging (134 °C/0.2 MPa/100 h) in an autoclave. The Kolmogorov-Smirnov-test, t-test, one-way ANOVA with post-hoc Scheffé test, Kruskal-Wallis-test, Mann-Whitney-U-test with Bonferroni correction and Weibull statistics were performed (α = 0.05). RESULTS: CEL and IEM showed the highest and the leucite ceramics the lowest Martens parameter. Within HT, ABM and NIC were in same initial HM value range with CEL and IEM. ABM and NIC showed lower initial EIT values than CEL and IEM, however higher than IPR. The lowest aged values were analyzed for ABM. After aging, Martens parameter decreased for LRF, ABM, and CEL. IEM showed the initial highest BFS, followed by ABM. NIC and LRF showed the lowest BFS. IEM and ABM presented the highest aged BFS. Hydrothermal aging increased BFS values for LRF (HT), IPR, CEL (HT), and NIC (HT) compared to the initial values. CAD/CAM leucite ceramics showed higher Weibull modul values compared to lithium silicate ceramics. SIGNIFICANCE: The well-considered selection of ceramics in relation to the areas of indication has the highest influence on the long-term stability of restorations: CAD/CAM lithium disilicate ceramics presented the highest and leucite ceramics the lowest mechanical properties, whereas the reliability was better for leucite than for lithium silicate ceramics.

Mapping of the Micro-Mechanical Properties of Human Root Dentin by Means of Microindentation.

The extensive knowledge of root dentin's mechanical properties is necessary for the prediction of microstructural alterations and the teeth's deformations as well as their fracture behavior. Standardized microindentation tests were applied to apical, medial, and cervical root sections of a mandibular human first molar to determine the spatial distribution of the hard tissue's properties (indentation modulus, indentation hardness, Martens hardness, indentation creep). Using an indentation mapping approach, the inhomogeneity of mechanical properties in longitudinal as well as in transversal directions were measured. As a result, the tooth showed strongly inhomogeneous material properties, which depended on the longitudinal and transversal positions. In the transversal cutting planes of the cervical, medial, apical sections, the properties showed a comparable distribution. A statistical evaluation revealed an indentation modulus between 12.2 GPa and 17.8 GPa, indentation hardness between 0.4 GPa and 0.64 GPa and an indentation creep between 8.6% and 10.7%. The established standardized method is a starting point for further investigations concerning the intensive description of the inhomogeneous mechanical properties of human dentin and other types of dentin.

Evaluation of translucency, Marten's hardness, biaxial flexural strength and fracture toughness of 3Y-TZP, 4Y-TZP and 5Y-TZP materials.

OBJECTIVES: Testing and comparing of different non-shaded zirconia materials (3Y-TZP, 4Y-TZP and 5Y-TZP) on optical and mechanical properties. MATERIALS AND METHODS: Zirconia materials (N = 320, Opaque O, Translucent T, Extra Translucent ET, High Translucent HT) were investigated on translucency, Martens parameter, biaxial flexural strength, Chevron-Notch-Beam (CNB) fracture toughness (KIC) and grain size. The grain size was analyzed using a scanning electron microcopy (SEM). Univariate ANOVA, post-hoc Scheffé, partial eta-squared, Kolmogorov-Smirnov-, Kruskal-Wallis- and Mann-Whitney-U-tests (p < 0.05) were performed. The reliability of flexural strength was calculated with two-parametric Weibull analysis and 95 % confidence level. RESULTS: The translucency of ET and HT increased with the thermo-mechanical aging (p < 0.001). The zirconia material and aging had no impact on the Martens hardness and the indentation modulus. ET showed the highest flexural strength values after initial and thermo-mechanical aging (p < 0.001 - 0.683). All four materials showed the highest flexural strength after thermo-mechanical aging after 1.2 Mio cycles. Thermo-mechanically (1.2 Mio cycles) aged HT presented the highest Weibull modulus (m = 15.0) regardless of aging. Within initial groups, T (p ≤ 0.001) showed the highest fracture toughness, followed by O (p ≤ 0.001), ET (p < 0.003) and HT (p ≤ 0.001). SIGNIFICANCE: Translucency of ET and HT increases with thermo-mechanical aging. Chevron-Notch-Beam (CNB) is a valid alternative to the single-edge-V-notched beam (SEVNB) method for testing fracture toughness.

New method to differentiate surface damping behavior and stress absorption capacities of common CAD/CAM restorative materials.

OBJECTIVES: To assess energy dissipation capacities and surface damping abilities of different CAD/CAM restorative materials (CRMs) to characterize stress resistance during load peaks. METHODS: Using instrumented indentation testing (IIT), Martens hardness (HM) together with its elastic (ηIT) and plastic index (ηITdis) and Leeb hardness (HLD) together with its deduced energy dissipation (HLDdis) were determined for eight ceramic, eight composite, and four polymer-based materials as well as three metals. The results were compared to those of bovine enamel. Ten indentations per material were performed at room temperature (23 ± 1 °C) on two separate specimens (12.0 × 12.0 × 3.5 mm3) after water storage (24 h; 37.0 ± 1.0 °C). Hardness parameters were recorded, and data were analyzed with one-way MANOVA (Games-Howell post hoc tests, α = 0.05). Correlations between different parameters were tested (Pearson, α = 0.05). RESULTS: Independently determined HLDdis, and ηITdis values substantiated different energy dissipation characteristics of CRM, whereby a strong correlation was observed for the two datasets (r = 0.956, p = 0.011). Ceramics had the significantly lowest values (p < 0.001) while both parameters revealed the highest surface damping effects for metals (p < 0.001), followed in both cases by bovine enamel. Energy dissipation of polymer and composite CRM was in between ceramics and bovine enamel (p < 0.001), whereas only for HLDdis did both show no significant difference (p > 0.05). SIGNIFICANCE: Promising new HLDdis and ηITdis data allow a reliable differentiation of energy dissipation and surface damping capacities of CRMs. Previously published rankings of edge chipping and loss tangent results were perfectly reproduced, especially by HLDdis.

Spatial Distribution of the Micro-Mechanical Properties in High-Translucent CAD/CAM Resin-Composite Blocks.

Industrially cured, high-translucent computer-aided design/computer-aided manufacturing (CAD/CAM) resin-based composites (RBC) are the most recently launched dental restoratives. Clinical treatments and laboratory tests are based on a homogeneous distribution of properties within CAD/CAM blocks to obtain constant and reproducible results. The study therefore aims to determine the spatial distribution of various micro-mechanical parameters (Vickers hardness, Martens hardness, indentation modulus, creep, elastic and total indentation work) in five representative CAD/CAM RBCs. The properties of the tooth structure were evaluated under similar conditions. Filler size and shape were analyzed by scanning electron microscopy. A multivariate analysis (general linear model) identified a very strong influence of the material on all measured properties (p < 0.001; partial eta squared ηP2 > 0.943), whereby the most sensitive parameters when identifying differences within regions were the indentation modulus and the elastic indentation work. CAD/CAM RBC blocks show gradually varying properties that can increase or decrease from central to peripheral areas regardless of the chemical composition of the materials or the inorganic filler fraction. The degree of variation in the measured properties is material-specific and less than 8.7%. Clinical applications and in vitro study designs should consider slight inhomogeneity in CAD/CAM RBC blocks, while the location of the regions with best mechanical performance depends on the material.