Preparation of Mixed Few-Layer GeSe Nanosheets with High Efficiency by the Thermal Sublimation Method.

Two-dimensional (2D) GeSe has been proven promising in fast and broadband optoelectronic applications for its complicated band structure, inert surface property, and excellent stability. The major challenge is the deficiency of the effective technique for controllably prepared large-scale few-to-monolayer GeSe films. For this purpose, a layer-by-layer thinning method by thermal sublimation for manufacturing large-scale mixed few-layer GeSe with direct bandgaps is proposed, and an optimized sublimation temperature of 300 °C in vacuum is evaluated by atomic force microscopy. Scanning electron microscopy, transmission electron microscopy, energy-dispersive spectra, and fluorescence mapping measurements are performed on the thinned GeSe layers, and results are well-indexed to the orthorhombic lattice structure with direct bandgaps with an atomic ratio of Ge/Se ≈ 5:4. Raman and fluorescence spectra show an α-type crystalline structure of the thinned GeSe films, indicating the pure physical process of the sublimation thinning. Both the bulk and few-layer GeSe films demonstrate broadband absorption. Conductivity of the few-layer GeSe device indicates the overall crystalline integrity of the film after thermal thinning. Given the convenience and efficiency, we provide an effective approach for fabrication of large-scale 2D materials that are difficult to be prepared by traditional methods.

Microfiltration Membranes Modified with Zinc by Plasma Treatment.

Polymer membranes play an important role in various filtration processes. The modification of a polyamide membrane surface by one-component Zn and ZnO coatings and two-component Zn/ZnO coatings is presented in this work. The technological parameters of the Magnetron Sputtering-Physical Vapor Deposition method (MS-PVD) for the coatings deposition process show an impact on the influence on the membrane's surface structure, chemical composition, and functional properties. The characterization of surface structure and morphology were analyzed by scanning electron microscopy. In addition, surface roughness and wettability measurements were also made. For checking the antibacterial activity, the two representative strains of bacteria Escherichia coli (Gram-negative) and Staphylococcus aureus (Gram-positive) were used. The filtration tests showed that polyamide membranes covered with three types of coatings, one-component Zn coatings, ZnO coatings, and two-component Zn/ZnO coatings, presented similar properties. The obtained results show that using the MS-PVD method for modification of the membrane's surface is a very promising perspective in the prevention of biofouling.

Comparison Study of PVD Coatings: TiN/AlTiN, TiN and TiAlSiN Used in Wood Machining.

In this paper, we analyze the possibilities of the protection of tools for wood machining with PVD (Physical Vapor Deposition) hard coatings. The nanolayered TiN/AlTiN coating, nanocomposite TiAlSiN coatings, and single layer TiN coating were analyzed in order to use them for protection of tools for wood machining. Both nanostructured coatings were deposited in an industrial magnetron sputtering system on the cutting blades made of sintered carbide WC-Co, while TiN single layer coating was deposited by evaporation using thermionic arc. In the case of TiN/AlTiN nanolayer coatings the thickness of the individual TiN and AlTiN layer was in the 5-10 nm range, depending on the substrate vertical position. The microstructure and chemical composition of coatings were studied by scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) method. Additionally, in the case of the TiN/AlTiN coating, which was characterized by the best durability characteristics, the transmission electron microscope (TEM) and X-ray photoelectron spectroscopy (XPS) methods were applied. The coatings adhesion to the substrate was analyzed by scratch test method combined with optical microscopy. Nano-hardness and durability tests were performed with uncoated and coated blades using chipboard. The best results durability characteristics were observed for TiN/AlTiN nanolayered coating. Performance tests of knives protected with TiN and TiAlSiN hard coatings did not show significantly better results compared to uncoated ones.

Influence of Different Types of Cemented Carbide Blades and Coating Thickness on Structure and Properties of TiN/AlTiN and TiAlN/a-C:N Coatings Deposited by PVD Techniques for Machining of Wood-Based Materials.

The influence of different types of cemented carbide blades and thickness of TiAlN/a-C:N and TiN/AlTiN protective coatings used in the wood industry on cutting performance has been studied. Three types of WC-Co cemented carbide blades with different cobalt content were used in the study. The thicknesses of both types of coatings were ~2 and ~5 µm. The structure, chemical and phase composition were studied using transmission and scanning electron microscopy (TEM, SEM), X-ray dispersion spectroscopy (EDX) and X-ray diffraction (XRD), respectively. The adhesion was evaluated by scratch test. Nanohardness and durability tests of uncoated and coated blades were performed. We found that the blades covered with 5 µm TiN/AlTiN coatings exhibited the best durability characteristic. The cutting distances were within the range ~6700-~7080 depending on the substrates in comparison with pure substrates (~4300-~4900) and 2 µm TiN/AlTiN coatings (~5400-~6600). The presence of a thin and soft outer a-C:N layer aggravates the nanohardness and durability of the coated blades.

Influence of Deposition Parameters of TiO2 + CuO Coating on the Membranes Surface Used in the Filtration Process of Dairy Wastewater on Their Functional Properties.

A novel approach of the deposition of two-component coating consisting of TiO2 and CuO on polymer membranes by MS-PVD method was presented in this work. This confirmed the possibility of using thin functional coatings for the modification of polymer membranes. The influence of technological parameters of the coating deposition on the membrane's structure, chemical composition and functional properties (hydrophilic, photocatalytic and bactericidal properties) were analyzed using SEM. Model microorganism such as Escherichia coli and Bacillus subtilis have been used to check the antibacterial properties. The results indicated that doping with CuO highlights the potential of bactericidal efficiency. The surface properties of the membranes were evaluated with the surface free energy. For evaluating photocatalytic properties, the UV and visible light were used. The filtration tests showed that polymer membranes treated with two-component TiO2 + CuO coatings have a permeate flux similar to the reference material (non-coated membrane). The obtained results constitute a very promising perspective of the potential application of magnetron sputtering for deposition of TiO2 + CuO coatings in the prevention of biofouling resulted from the membrane filtration of dairy wastewater.