Review of the global evolution of regulations on single-use plastics and lessons drawn for Canada.

Plastic pollution is a global problem and many countries are strengthening their regulations to mitigate the related environmental degradation and health risks and to support the development and deployment of circular economy for various types of plastics. As Canada also develops its strategy for regulating single-use plastic as one element of the plastic pollution, aligned federal and provincial policies are essential. This study presents an analysis of existing and emerging policies to provide guidance on Canada's future regulations. Qualitative and quantitative data regarding plastic regulations were gathered from similar countries including Australia, the United Kingdom, the European Union, the United States and relevant scientific articles. Analysis was also conducted of current Canadian regulations that both impact and guide the path for plastic regulation, international examples provided guidance for future Canadian regulations. The analysis found that there is a need for public education on the gravity of plastic pollution to gain their support; for establishing pioneering provinces or cities in plastic regulations to learn from and provide other cities with support; and to start with banning items with available alternatives, to be followed by phasing out other items that are more difficult to replace. The study also showed potential areas of improvement in impact data. The need for reliable regulatory performance data against a baseline scenario; consistency in methodology; and proper scoping to reduce the risk of displacement or exclusivity in policy were identified.

Effect of biofilm formation on different types of plastic shopping bags: Structural and physicochemical properties.

Plastics and biofilms have a complicated relationship that has great interest. Bacterial cell attachment and biofilm formation is considered to cause health and environmental risks from plastic waste accumulation. In water, plastic waste could serve as a new substrate for bacteria. In our study, the attachment of Escherichia coli K12, to four types of plastic shopping bags (biodegradable polylactic acid and the non-biodegradable polypropylene, polyethylene and polyvinyl chloride) was investigated. The change in physicochemical phenomena of each plastic, such as reduced hydrophobicity and higher exopolysaccharide concentrations (total extractable protein and carbohydrate) resulted in increased biofilm content on the plastic surfaces. The bacterial colonization of different plastic surfaces controls the ionic strength of the nutrition sources. The adhesion of Escherichia coli K12 cells on the surfaces were revealed by SEM images. The finding shows that increases surface roughness, besides favor for adhesion of bacterial cells due to hydrophobicity leading to a rapid attachment of Escherichia coli K12 on the surfaces. In addition, we used Derjaguin-Landau-Verwey-Overbeek theory to predict the attachment of Escherichia coli K12, which gave result of adhesion due to the high energy barrier. This present study added to our knowledge of the possible consequences of plastics acting as a new habitat for microbes in different aquatic condition.

The effects of environmental information provision on plastic bag use and marine environment status in the context of the environmental levy in Greece.

The focus of this study is to examine the level of awareness, as well as the impacts of environmental information provision, regarding plastic bag consumption in Greece, taking into consideration the effects of plastic pollution in the marine environment within the framework of the environmental levy. This study was conducted through the use of two structured questionnaires as web-based surveys. The aim of both questionnaires was to explore citizen attitudes towards the marine environment in addition to their preferences with regard to the implementation of a program aimed at marine conservation and the reduction of plastic bag use. Data on plastic bag consumption at a national level were also incorporated. This research was carried out according to the contingent valuation method aimed at estimating citizen willingness-to-pay (WTP) on both structured questionnaires. The first questionnaire utilized the minimal legal WTP (ML-WTP) model resulting in 834 responses in total, while the second questionnaire applied a double-bounded dichotomous choice method and amassed 713 responses in aggregate. Based on the results of the first questionnaire, pre-existing environmentally friendly behaviour was further enhanced by the introduction of the environmental levy on plastic bags. The second questionnaire revealed that marine conservation is based both on collective as well as individual responsibility. This study provides evidence that the utilization of both economic and non-economic measures may be very effective in considerably reducing plastic bag consumption and its detrimental impact on the marine environment.

Influence of nonylphenol from multilayer plastic films on artificial insemination of sows.

Artificial insemination is common practice in mass livestock farming. Recently, it was shown that chemicals leaching from multilayer plastic bags affect the fertility of boars, although common quality tests did not show any impact on the sperm. It is not clear whether this incidence was a single case or whether it could be a systematic problem. Therefore, we studied six multilayer plastic bags. A total of 49 compounds were found, but most of them were at very low intensity. Nonylphenols in the range of 19-99 µg/g plastic were found. Migration tests using water and 10% ethanol as simulants, to mimic the behavior of semen with the extender, were performed. The most interesting migrants in terms of potential reprotoxicity were identified as nonylphenols. The identification in depth demonstrated the presence of 10 isomers of nonylphenol with a total concentration range between 16 to 58 µg/Kg simulant, among other migrants at lower concentration. The influence of these nonylphenols and their maximum tolerable concentration in direct contact with semen from boars was studied. Motility, viability, mitochondrial activity and acrosomes reacted were significantly affected at 10 mg/Kg of nonylphenols in contact with the sperm, but in vitro penetration rate was significantly decreased with only 2 mg/Kg. Insight into the mode of action is also provided.

A green approach for the automatic quantitative analysis of additives in plastic samples using in-tube extraction dynamic headspace sampling technique coupled to GC-MS/MS.

BACKGROUND: Many of the chemicals frequently used as additives have been recognised as hazardous substances, and therefore their analysis is necessary to evaluate plastic contamination risk. Additives analysis in plastic samples is usually performed by methods involving high volumes of toxic solvents or having high detection limits. In this work, a novel, fast, solventless and reliable green method was developed for the automated analysis of plastic additives from plastic samples. The proposed method consists of in-tube extraction dynamic headspace sampling (ITEX-DHS) combined with gas chromatography (GC) and mass spectrometry (MS/MS) determination. RESULTS: Several parameters affecting the ITEX-DHS extraction of 47 additives in plastic samples (including phthalates, bisphenols, adipates, citrates, benzophenones, organophosphorus compounds, among others) were optimised. The use of matrix-matched calibration, together with labelled surrogate standards, minimises matrix effects, resulting in recoveries between 70 and 128%, with good quantitation limits (below 0.1 µg g-1 for most compounds) and precision (<20%). The method proposed can be applied to any type of polymer, but due to the existence of the matrix effect, calibrates with the adequate matrix should be performed for each polymer. SIGNIFICANCE: This method represents an effective improvement compared to previous methods because it is fast, solvent-free, fully automated, and provides reliable quantification of additives in plastic samples.

DNA recovery after sequential processing of latent fingerprints on black polyethylene plastic.

Latent fingerprints on plastic substrates can be visualized by using sequential treatments to enhance the contrast between the fingerprint residues and underlying substrate; however, the extent to which these processes affect subsequent DNA analysis is mostly unknown. Latent fingerprints deposited on black plastic by one donor were visualized with single-process fingerprint powders (i.e., white powder, bichromatic powder, or bichromatic magnetic powder) or sequential treatments (i.e., laser → reflected ultraviolet imaging system (RUVIS) → CA fuming → RUVIS → Rhodamine 6G, Ardrox, and MBD (RAM) or CA fuming → RAM/laser → bichromatic magnetic powder). Samples were examined after the addition of each treatment. DNA was collected using cotton swabs, extracted, quantified, and amplified. DNA yields, peak heights, number of alleles obtained, and percentage of DNA profiles eligible for CODIS upload were examined. Latent fingerprints processed with the laser and up to three sequential treatments generated DNA profiles with significantly higher peaks heights than those of the untreated samples. Fingerprints processed with the laser and up to two sequential treatments generated DNA profiles with significantly more alleles. All methods beginning with laser enhancement generated more CODIS-eligible profiles. Additional research is needed to determine the extent to which initial laser enhancement impacts the success of downstream DNA profiling results. Although DNA profile development is not guaranteed due to the variable quantities of DNA contained within latent fingerprints, the selection of an appropriate latent fingerprint visualization method could maximize both fingerprint detection and the generation of CODIS-eligible DNA profiles.

Spallation and particles infusion into the extracorporeal circuit during CRRT: a preventable phenomenon.

Patients in intensive care are exposed to the risk of microparticle infusion via extracorporeal lines and the resulting complications. A possible source of microparticle release could be the extracorporeal circuit used in blood purification techniques, such as continuous renal replacement therapy (CRRT). Disposable components of CRRT circuits, such as replacement bags and circuit tubing, might release microparticles such as salt crystals produced by precipitation in replacement bags and plastic microparticles produced by spallation. In-line filtration has proven effective in retaining microparticles both in in-vitro and in-vivo studies. In our study, we performed an in-vitro model of CRRT-treatment with the aim of detecting the microparticles produced and released into the circuit by means of a qualitative and quantitative analysis, after sampling the replacement and patient lines straddling a series of in-line filters. Working pressures and flows were monitored during the experiment. This study showed that microparticles are indeed produced and released into the CRRT circuit. The inclusion of in-line filters in the replacement lines allows to reduce the burden of microparticles infused into the bloodstream during extracorporeal treatments, reducing the concentration of microparticles from 14 mg/mL pre in-line filter to 11 mg/mL post in-line filter. Particle infusion and related damage must be counted among the pathophysiological mechanisms supporting iatrogenic damage due to artificial cross-talk between organs during CRRT applied to critically ill patients. This damage can be reduced by using in-line filters in the extracorporeal circuit.

Evaluating Effectiveness of Multi-Component Waste Plastic Bags on Bitumen Properties: Physical, Rheological, and Aging.

This study examines the applicability of an unknown composition waste plastic bag sample as bitumen modifier. The waste components were initially characterized to identify the type of plastics and the level of impurity. Asphalt binder performance was examined for rutting, thermal, and age resistance. The results revealed that the waste plastic bags, predominantly consisted of Low-Density Polyethylene (LDPE) and Linear Low-Density Polyethylene (LLDPE) and contained 6.1% impurities. The binder tests indicated that the waste plastic bags enhanced the rutting resistance of bitumen by one grade, with its modification more similar to LLDPE, rather than LDPE. The thermal degradation and aging properties of the modified binders demonstrated that the bitumen modified by the waste plastic bags exhibited slightly lower resistance to temperature and aging compared to virgin LDPE and LLDPE. This was attributed to the impurities contained in the waste plastic. In conclusion, the analyzed waste plastic bags proved to be suitable for use in binder modification, presenting a viable alternative to virgin LLDPE.

Does foil-like debris impair barnacles by covering them?

On 24 June 2024, we detected foil that tightly adhered to an intertidal wall in Vigo harbor (Spain) during low tide. It covered multiple barnacles, potentially threatening their survival. We present photos of this novel debris-animal interaction and discuss possible effects that such cover could have on barnacles.

Comparative Analysis of the Effects of Incorporating Post-Industrial Recycled LLDPE and Post-Consumer PE in Films: Macrostructural and Microstructural Perspectives in the Packaging Industry.

In accordance with the Circular Economy Package of the European directive, the Spanish government compels manufacturers of plastic bags to include into their products a minimum of 70% of polyethylene (PE) waste. Following this mandate can be challenging and requires a deep knowledge of the alterations produced by the recycling in the main components of a plastic bag film: lineal low-density polyethylene (LLDPE), the LLDPE recycled post-industry, generated as waste from an industrial process (rLLDPE) and the PE recycled from post-consumer use (rPE), that has been picked up, cleaned, and reprocessed. This study provides insight in the macro and microstructural changes produced by several cycles of recycling in these materials. Specimens in the form of film for supermarket bags formed with these polymers have been subjected to several recycling sequences. The process closely mimics industrial processes. Four cycles have been applied to the samples. The evolution of mechanical properties, including tensile strength, elongation at break, and tear and impact tests, shows an obvious decrease due to degradation that is not an impediment for practical use after the four cycles of recycling according to the main specifications defined by the producer. Colorimetric measurements reveal no significant variations in the color of the films. The results of the FTIR and TGA analysis show degradation phenomena and changes in crystallinity in branching and the apparition of crosslinking that are in consonance with the mechanical data. There is also a difference between both types of recycled PE. In general, rLLDPE is more affected by the recycling than rPE. According to our findings, the limiting property would be the tearing. By comparing these values with bags available in the market, manufactured from 70-80% recycled material, we can infer that while two reprocessing cycles can lead to good results, a maximum of four cycles of recycling is advisable.

What not to do with dog poop.

This short communication paper comments on the controversial but highly unpleasant topic of littered plastic dog waste bags in the environment. Littered plastic dog waste bags are a source of plastic and microplastic pollution and dog faeces contained in these littered bags also pose human and ecological health risks. This short communication suggests that this littering may be occurring due to confusion by pet owners, who may believe that these so called 'biodegradable' bags are compositable, which in the absence of industrial composting facilities, are not. Thus, plastic dog waste bags continue to be a source of plastic and microplastic pollution in the environment long after they have been littered. All pet owners should deposit plastic dog poop bags in appropriate waste bins, not in the environment.

Assessment of plastic pollution in coastal areas of Karachi: Case study of West Warf, Kemari Jetty, and Manora.

This study focused on marine pollution in coastal areas of Karachi, particularly West Warf, Kemari Jetty, and Manora. The research examined the sources and quantities of waste, from boat manufacturing, export units, and local commercial activities. Stakeholder interviews were conducted to understand waste management practices and identify the key contributors to ocean litter. The results indicated that restaurants, export units, boat construction, and tourist and commuter activities were the primary sources of marine pollution. Plastic was found to be the most prevalent litter category, with LDPE (e.g., single-use bags) and polystyrene (e.g., material in floating docks) being the most common types. Additionally, multi-layer packaging, such as chip wrappers, was frequently observed in the surveyed areas. Overall, this research highlights the urgent need for improved waste management and compliance measures in coastal regions to mitigate marine pollution.

Indigestible foreign bodies in the forestomach of slaughtered goats in Mogadishu, Somalia.

Background and Aim: The primary domestic animal in Somali communities is the goat. Their main economic importance is as a food source and a main form of agriculture in the country. There has been a recent decline in the goat population in Somalia, which may be due to the shortage of feed and an increasingly contaminated environment that is affecting the population's food supply and nutritional status. This study aimed to estimate the prevalence and the factors associated with indigestible foreign bodies (IFBs) ingestion in goats in Mogadishu, Somalia. Materials and Methods: A cross-sectional study was conducted at the Somalia Meat Company in Mogadishu, Somalia, in February 2022. A total of 250 goats were included in this study, and records were kept on age, sex, body condition, and location. Following the slaughter, goats were inspected for IFBs, and their stomach compartments were incised and examined. Indigestible foreign body classifications was noted and subjected to analysis using the Statistical Package for the Social Sciences version 26.0. Results: A total of 90/250 (36%; 95% confidence interval [CI]: 30.1-42.3) goats presented IFBs, being 71/90 (79%; 95% CI: 69-87) in the rumen, 12/90 (13%; 95% CI: 7-22) in the reticulum, and seven/90 (8%; 95% CI: 3-15) on both. The most observed IFBs were plastic in 71/90 (79%; 95% CI: 69-87), followed by ropes in eight/90 (10%; 95% CI: 5-18). A high IFB prevalence was observed in goats aged >2-≤3 years (44%), followed by >3 years (36%). The lowest frequency was observed in goats aged <2 years (30%). Overall, there was an association between IFBs in goats and poor body conditions (χ2 = 47%, p < 0.04). Conclusion: The absence of a plastic waste disposal system in the area, and communal free-grazing of livestock in highly contaminated sites, appeared to be significant contributors to the high occurrence of IFBs in goats. Therefore, appropriate policies for solid waste management should be implemented.

A multi-jurisdictional study on the quantification of COVID-19 household plastic waste in six Latin American countries.

This study examines urban plastic waste generation using a citizen science approach in six Latin American countries during a global pandemic. The objectives are to quantify generation rates of masks, gloves, face shields, and plastic bags in urban households using online survey and perform a systematic cross-jurisdiction comparisons in these Latin American countries. The per capita total mask generation rates ranged from 0.179 to 0.915 mask cap-1 day-1. A negative correlation between the use of gloves and masks is observed. Using the average values, the approximate proportion of masks, gloves, shields, and single-use plastic bags was 34:5:1:84. We found that most studies overestimated face mask disposal rate in Latin America due to the simplifying assumptions on the number of masks discarded per person, masking prevalence rate, and average mask weight. Unlike other studies, end-of-life PPE quantities were directly counted and reported by the survey participants. Both of the conventional weight-based estimates and the proposed participatory survey are recommended in quantifying COVID waste. Participant' perception based on the Likert scale is generally consistent with the waste amount generated. Waste policy and regulation appear to be important in daily waste generation rate. The results highlight the importance of using measured data in waste estimates.

Optimistic narrative future visions: a communication tool for promoting sustainable (plastic) behavior.

Plastic pollution is a pressing global issue, necessitating a focus on consumer behavior to curb this problem at its source. To effectively promote sustainable practices, communication strategies that employ future visions have gained attention. This study examines the effects of a narrative video intervention depicting an optimistic future vision concerning single-use plastic bag consumption in South Africa, compared to a representation of the prevailing status quo. Using a preregistered within-subject design, we assess the psychological and emotional responses to two scenarios of which one is illustrating adaptive behaviors toward reduced plastic bag usage, and the other showcasing current consumption patterns. Parametric analyses revealed a shift in emotional states, characterized by a greater experience of positive emotions and a reduced experience of negative emotions following the exposure to the optimistic future scenario video, as compared to the status quo video. Moreover, engagement with the optimistic future scenario was associated with higher levels of perceived behavioral control and behavioral intentions. No significant changes were found regarding sense of responsibility. These findings point to the potential of optimistic future visions to influence individuals at psychological and emotional levels. This renders optimistic future vision communication as an effective tool for sustainable behavior change, particularly in relation to the sustainable use of plastic shopping bags.

Rapid photo aging of commercial conventional and biodegradable plastic bags.

Biodegradable plastic (BPs) bags are introduced and widely used as alternatives to conventional commercial plastic bags in an effort to mitigate the adverse impacts of nondegradable (conventional) plastics. However, being used as packaging, the stability and safeness of the BPs and even the conventional plastics with photo irradiation in short duration remain unknown. In this study, we systematically explored the photo aging of commercial BPs bags and conventional plastic bags in film forms in both outdoor and laboratory experiments in short duration (~ one month) under the scenario of ordinary daily use. Conventional plastic bags (polyethylene (PE)) and BPs bags (hybrids of polylatic acid (PLA) and poly(butylene adipate-co-terephthalate) (PBAT) with additives (Magadiite or Starch)) were investigated. In contrast with the visually negligible surface change of PE films in both outdoor and laboratory environments, obvious surface alteration as surface deterioration with cracks and holes was obtained for BPs from SEM images in direct irradiation by both natural and simulated sunlight. Consistently, AFM results also indicated that the surface of BPs had the tendency to be rougher after photo aging process. Further FTIR and XPS results demonstrated that though the visual surface alteration of conventional and biodegradable plastics are distinct, the mechanisms dominating the change of C-H/C-C bonds to carbon­oxygen functional groups (i.e., C-O/C=O/O-C=O) for both conventional plastics and BPs during the photo aging process are similar. Moreover, tensile strength tests demonstrated that BPs bags being easily broken compared with the conventional PE bags might attribute to the difference in their mechanical properties. The findings of this study suggest that the potential risk of MPs and NPs released from the BPs bags via photo aging process are great new threats to natural environment and even human health.

Dog poop bags: A non-negligible source of plastic pollution.

Plastic pollution derived from the disposal of plastic bags in the environment is clearly evidenced. However, little attention has been directed towards plastic waste derived from plastic dog poop bags (DPBs), which are widely used and can never be recycled. Herein, we raise concerns about the contribution of DPBs to plastic pollution in the environment. Combining the weight of each DPB, the number of bags daily used for a dog, and the number of pet dogs around the world, we estimated the number of annual consumed and disposed DPBs at more than 415 billion, or equivalently 0.76-1.23 million tons of plastics based on various weights of different DPBs. Although plastic waste produced by DPBs only accounts for a small fraction (0.6%) of the total plastic waste generation, the extremely short life cycle of DPBs has made them a non-negligible source of plastic pollution in the environment.

The road to sustainable use and waste management of plastics in Portugal.

As a European Union (EU) member, Portugal must comply with reductions in plastic waste. In Portugal, the 330 items/100 m of beach litter, comprising up to 3.9 million pieces and of which 88% is plastic, is higher than the EU median (149 items/100 m) and must be reduced to 20 items/100 m (94%). Integrative measures are needed to reduce littering and improve plastics' use and disposal under the circular economy. Of this 414 kt of plastic packaging waste, 163 kt were declared plastic packaging, 140 kt subjected to recycling, and 94 kt to energy recovery. The current recycling rate of plastic packaging (34%) should be improved to reach EU recycling averages (42%) and goals and to provide widespread benefits, considering revenues of 167 €/t. As a net importer of waste, Portugal could benefit from the valorization of imported waste. Besides increased recycling, pyrolysis and gasification could provide short-term alternatives for producing value-added substances from plastic waste, such as hydrogen, consistent with the National Plan of Hydrogen and improving ongoing regulations on single-use plastics. This manuscript provides an integrative view of plastics in Portugal, from use to disposal, providing specific recommendations under the circular economy. ELECTRONIC SUPPLEMENTARY MATERIAL: Supplementary material is available in the online version of this article at 10.1007/s11783-021-1439-x and is accessible for authorized users.

Anthropogenic litter in freshwater bodies and their estuaries: an empirical analysis in Lesvos, Greece.

The last decade increasing attention to litter accumulation in the marine environment revealed the issue of the terrestrial fluxes of plastic pollution into the oceans. However, limited studies investigate the macro-litter abundance and composition particularly in freshwater ecosystems and the adjusted coastal environment. In this study, we conducted an empirical analysis of anthropogenic litter (AL) in two freshwater streams and their estuaries of Lesvos island (Greece), strongly affected by the waste mismanagement in the Moria refugee camp. A total of 1,622 litter items were collected from five sites during the field campaign between the 3rd and 6th of June 2019. Among these, artificial polymer items (mainly drink bottles, single-use plastic bags, cutlery, and trays) irrespective of the site location constituted the major part ranging from 46 to 91% of total AL by mass. Drink bottles and plastic cutlery are found in higher percentage at Moria camp river and its estuary, while packaging and bag litter are more abundant at upstream sites. The operation of the camp has increased the AL abundance 13 times more than the reference site, causing severe threat to human health and to freshwater and marine environment. It is therefore important to improve the waste management system at (inter)national (change in production and packaging policy) and local scale (introducing sustainable solutions to refugee camp design) by promoting recycling and circular economy projects to diminish AL pollution.

Microplastics formation based on degradation characteristics of beached plastic bags.

Environmental pollution from plastic bags is a significant issue in the global environment. Plastic bags can be transferred by the wind and ocean currents everywhere in the three dimensions and be fragmented into small particles, termed film-shaped microplastics. The purpose of this study is to provide insights on the degradation of beached plastic bags. Monitoring and sampling were performed to determine plastic bag fragmentation and the possible mechanisms. On selected samples, various spectroscopic techniques and microscopy were used. Before the imposition of the "green" plastic bag fee in Greece, field monitoring suggested that the majority of the coastal plastic bags were fragmented whereas after the "green" fee, less fragmented bags were observed. Evidence of three degradation mechanisms were observed in this study. For oxodegradable plastic bags, degradation takes place for the starch additives and the polymer part stays in the environment as microplastic particles. For thin light density polyethylene plastic bags, mechanical fragmentation takes place in the environment creating microplastics before significant chemical alterations in functional groups were observed and once chemical alteration (oxidation) is observed, fragmentation (of HC or CC bonds) is also taking place. Thus, regulating thin plastic bags usage removes problems related to plastic bags but also to film-shaped microplastics.