Geochemical evaluation, ecological and human health risk assessment of potentially toxic elements in urban soil, Southern India.

Roadside soil contamination is mostly caused by human-caused pollutant deposition. PTEs are among the many substances that are harmful for both humans and the environment. PTE concentrations in roadside soil in Chennai, southern India, have been determined in this study. To evaluate the seriousness of the threats, more environmental and geochemical indices have been applied. 83 soil samples have been obtained from the study regions and focusing on important roads. Elemental analysis has been analyzed with ED-XRF and sieve-filtered samples focused on PTEs such as arsenic, barium, cobalt, chromium, copper, iron, potassium, nickel, lead, thorium, titanium, zinc, and uranium. Significant metallic variations have been found in soil samples around roads by the investigation. The elements this study examined section ascending in the following sequence: Fe > Ti > Zn > Cr > Pb > Cu > Ni > Th > As > U > K. In the research area, the CD classification denotes high contamination, whereas the CF indices show mild to significant pollution. PLI indicates moderate to high pollution, whereas EF suggests excessive enrichment. Igeo demonstrates a range from uncontaminated to highly contaminated. PERI showed high levels in the northern study region, whereas GUFI shows several hot spots indicating moderate to severe pollution. The Hazard Index (HI) values for all metals were less than one, demonstrating the absence of non-carcinogenic risks for both adults and children. Multivariate data show natural and anthropogenic PTEs in roadside soil. In addition, a soil quality monitoring system is needed to mitigate continual contamination risks.

Bioaccumulation, transfer characteristics of metals in six vascular plants, and soil pollution assessment from Wachangping karst bauxite residue areas.

Bauxite residue (BR) is a large volume by-product generated during bauxite smelting process and metal pollution problem is becoming increasingly prominent in residue areas. Accumulation and transfer of metals in six vascular plants were analyzed and soil environment was evaluated. Results found levels of Al (2,110-26,280 mg kg-1), Fe (990 to 9,880 mg kg-1), Ca (8,020 to 49,250 mg kg-1), Mg (2,060 to 17,190 mg kg-1), K (16,840 to 39,670 mg kg-1), and Ti (80 to 1,240 mg kg-1) in plants. Metal concentrations in soils exceeded background levels. Bioconcentration factor (BCF) found that Al, Fe, and Ti in plants (roots, stems, and leaves) were relatively depleted (BCF <1). Transfer factor (TF) of Al, Fe, Ca, K, and Ti in plants was distinctly higher than 1 and mainly concentrated in stems and leaves. Pollution indices revealed that soil environment was at moderated to serious contaminated risk. Principal components analysis (PCA) showed that Artemisia caruifolia Buch. and Siegesbeckia orientalis L. plants had a good ability to absorb Al and Fe, which can be used as biological indicators and restoration materials.

Currently, soil environment was exposed to moderated to serious contaminated risk from Wachangping karst bauxite residue areas.Bioconcentration factor (BCF) analysis found that Al, Fe, and Ti in six vascular plants (roots, stems, and leaves) were relatively depleted (BCF <1).Transfer factor (TF) of Al, Fe, Ca, K, and Ti in vascular plants was distinctly higher than 1, which mainly concentrated in stems and leaves.PCA revealed that Artemisia caruifolia Buch. and Siegesbeckia orientalis L. plants had a good ability to absorb Al and Fe, which can be used as biological indicators and ecological restoration materials.

A water quality assessment model involving novel fluorescence technology.

The reasonable utilization of water resources and real-time monitoring of water pollution are the core tasks of current world hydrological and water conservancy work. Novel technologies and methods for monitoring water pollution are important means to ensure water health. However, the absence of intuitive and simple analysis methods for the assessment of regional pollution in large-scale water bodies has prevented scientists from quickly grasping the overall situation of water pollution. In this study, we propose a strategy based on the unique combination of fluorescence technology and simple kriging (SK) interpolation (FL-SK) for the first time. This strategy could present the relative magnitude and distribution of the physicochemical indicators of a whole natural lake intuitively and accurately. The unique FL-SK model firstly offers a simple and effective water quality method that provides the pollution index of different sampling points in lakes. The macroscopic evaluation of large-scale water bodies by the FL-SK model primarily relies on the fluorescence response of the RDM-TPE to the comprehensive indicators of the water body, as experimental results have revealed a good correlation between fluorescent responses and six normalized physicochemical indicators. Multiple linear regression and fluorescence response experiments on RDM-TPE indicate that to some extent, the fluorescence signals of the FL-SK model may originate from a certain type of sulfide in the water body. Pattern discovery could enable the analysis of pollution levels in other ecosystems and promote early pollution assessment in the future.

Pollution and source-specific risk analysis of potentially toxic metals in urban soils of an oasis-tourist city in northwest China.

Source-specific risk apportionment for soil potentially toxic metals (PTMs) is of great significance for contamination prevention and risk management in urban environments. Eighty-five urban soil samples were obtained from an oasis-tourist city, China and examined for eight PTMs (As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn). The pollution levels, sources, and ecological risk of soil PTMs were quantified, and their source-specific ecological and human health effects were also estimated using the multi-proxy approaches. The results demonstrated that accumulation of Cd, Hg, Pb, Cr, Cu, and Zn in soils was observed compared to their background levels, and the soils experienced varying degrees of PTMs pollution, especially at sites with high-intensity anthropogenic activities. Natural sources, atmospheric deposition, industrial sources, vehicular emissions, and comprehensive inputs were the principal sources, with contributions of 29.28%, 25.86%, 20.13%, 16.50%, and 8.23%, respectively. The integrated ecological risks of PTMs in soils were moderate at most sites, with atmospheric deposition being the dominant contributor to ecological risks. Children exhibited pronounced non-cancer risks, but adults had no notable non-cancer risks. Moreover, there were potential carcinogenic risks for both children and adults within the study region. Non-cancer and carcinogenic risks were more significant for children than adults, and traffic emissions were the primary contributor to non-cancer risks (adults: 20.53%, children: 20.49%) and carcinogenic risks (adults: 22.95%, children: 22.08%). The industrial and traffic activities were considered as priority control sources for soil pollution control and risk management, with Hg, Cd, Zn, and Pb corresponding to the priority elements. This study highlights the source-specific ecological and human health effects of PTMs pollution in urban soils, thereby providing valuable information for targeted pollution control and priority source management.

Assessing the pollution level of a subtropical lake by using a novel hydrogen sulfide fluorescence technology.

Hydrogen sulfide (H2S) is an important environmental toxin with bi-directional biological effects on organisms. In natural waters, H2S complexes with heavy metal ions in an anaerobic environment influence heavy metals' bioavailability and induce phosphorus release and eutrophication in water columns. Traditional detection techniques, such as colorimetric, electrochemical, and chromatographic, cannot simultaneously detect H2S and pollution assessment of subtropical lakes. To address these technical defects, we developed small-molecule fluorescent probes to evaluate the pollution level in natural water bodies. This method relies on the combination of the probes' response signals to raw water and the water quality index, thereby enhancing the accuracy and reliability of water quality assessments. Furthermore, this novel material has a large Stokes shift. It can detect complex levels of H2S concentrations in natural water bodies by correlating the degree of contamination and fluorescence signals. The development of this visual research tool for detecting environmental H2S levels in natural water bodies is expected to have meaningful, practical applications.

Spatial distribution, source identification, and risk assessment of heavy metals in riparian soils of the Tibetan plateau.

Riparian soils in the lower sections of the Lhasa River were chosen as the research focus, to examine the characteristics and sources of heavy metals in riparian soils of high-cold regions. To investigate the influence of various factors on the geographical distribution of heavy metals, three horizontal and one vertical profiles were considered. The geoaccumulation index, prospective ecological risk index, and enrichment factor were used to evaluate the extent of soil contamination. Correlation analysis and the positive-matrix-analysis receptor model were used to quantitatively examine the sources of the elements. According to the soil-evaluation, the topsoil was more polluted than the deep soil. Overall, the soil was slightly degraded and posed minor ecological concern. Cd was the primary contributor to the overall contamination, with moderate and considerable risk levels at certain locations. Five sources were identified for the six heavy metals. Transportation and agricultural production were the principal sources of Cd. Ni and Cr were mostly connected to agricultural practices and weathering of parent-soil materials. Pb and Zn were mostly related to geological history, geothermal development, and traffic pollution. Mineral resource development has had a major impact on Cu. Non-carcinogenic risk index of each heavy metal and their total value were <1, indicating they are not harmful to human health. The riparian soil of the Lhasa River Basin contains heavy metals from various sources; therefore, it is important to monitor these heavy metals. This study provides a scientific foundation for the safe utilization and classification of soils in high cold regions.

A method of assessing the depth of contaminated sediments that should be removed in lakes: a case study of Tangxun Lake, China.

The depth of contaminated sediments constrains the water environment of large shallow lakes and can affect shallow lake water quality through sediment resuspension and nutrient release. Although such effects can be avoided by sediment dredging methods, we still cannot precisely quantify the depth of sediment dredging. Therefore, we used organic index method, pollution index method and potential ecological risk evaluation to evaluate the contamination status of split samples of in situ sediments layer by layer, and established a comprehensive contamination index evaluation method for layer-by-layer sediments, then combined with the contamination release characteristics of split samples to assess the contamination degree of the sediments obtained. The results show that the content of nitrogen and phosphorus in the surface layer of Lake Townsend sediments is generally higher than that in the middle and bottom sediments, and the heavy metals also satisfy this pattern, which is consistent in the sediments of both east and west regions. We also simulated the release process of nitrogen and phosphorus nutrients in the in situ sediment of Tangxun Lake in 2019, and the experimental results showed that the risk of nitrogen and phosphorus nutrient release in the sediment was mainly concentrated in the surface and middle layers, and the risk of elemental nitrogen release was significantly greater than that of phosphorus release. Finally, a comprehensive evaluation was carried out to obtain the desilting depth of the sediments in Lake Townsend, and it can be determined that the recommended desilting depth is about 20 cm for West Lake and 30 cm for East Lake. The results show that the recommended dredging depth can be determined based on this method, which provides an important scientific basis for sediment dredging in Tangxun Lake and even provides a new paradigm for sediment dredging depth estimation in similar large shallow lakes.

Characterization of heavy metal content distribution and evaluation of soil pollution in Maqin County, Qinghai Province, China.

The Qinghai-Tibet Plateau stands as the loftiest geographical area on our planet, frequently denoted as the "Crown of the Globe." To acquire an exhaustive comprehension of the heavy metal contamination situation in the topsoil of Maqin County, Qinghai Province, a total of 1616 surface soil specimens were gathered across a 6300 km2 area. An examination was carried out on 12 metallic elements to investigate the impact of diverse geological contexts, soil categorizations, and land utilization practices on the levels of heavy metals. Additionally, the fundamental factors contributing to these trends were probed. The findings unveiled that the mean levels of the 12 metallic elements in the topsoil of Maqin County surpassed or equaled the baseline values of soil heavy metal concentrations within the research region. The coefficients of variation (CV) values for Hg, Sb, Ni, and Pb exceeded 30%, with Hg showing strong variation. The overall pollution level in the study area was classified as mild, posing a moderate ecological risk. In this study, we performed a multi-factor analysis of the significant differences in heavy metal concentrations among different geological backgrounds, soil types, and land-use types. The results showed that geological background had extremely significant impacts on elements such as Ba, Be, Cd, Cr, Cu, Hg, Ni, Sb, Tl, and Zn (p < 0.01). Soil type had an extremely significant influence on Be, Cd, Cu, and Zn (p < 0.01), as well as a significant influence on Ba (p < 0.05). Land-use type had an extremely significant impact on Ba (p < 0.01) and a significant impact on Cd (p < 0.05). Building upon the amalgamation of the outcomes from the Pearson correlation analysis, it was inferred that the main source of heavy metals in Maqin County, Qinghai Province, was the geological background.

Detrimental influence of industrial effluents, especially heavy metals, on limnological parameters of water and nutritional profile in addition to enzymatic activities of fish, Sperata seenghala (Sykes, 1839) from diverse Ramsar sites, India (Punjab).

The present research was designed to determine the nutritive value of the liver and intestine of fish, Sperata seenghala, the impact of effluence load on limnological parameters of water and proximate composition of fish organs, especially on fatty acids, liver enzymatic activities, seasonal variations in the nutritional profile of fish, and to check and compare the pollution status of Ramsar sites in Punjab by calculating the water quality index, heavy metal pollution index, and metal index from June 2018 to August 2020. WQI of Harike wetland was found to be 53.95, which depicts that water quality in this region is "poor". At Nangal wetland, water quality index was reported to be "excellent" quality water and fit for the whole ecological unit. Overall heavy metal pollution index for Harike wetland was reported 174.569, whereas for Nangal wetland it was 5.994, depicting massive contaminant loads in a polluted region. MI value was also recorded as being higher (6.9336) in polluted habitat than in control habitat (0.8175). In fish liver, significant (p < 0.05) higher mean total lipids (6.73%), total proteins (3.98%), moisture (77.69%), ash (3.56%), and carbohydrates (3.79%) were observed in the samples from Nangal wetland than Harike wetland. A similar trend was reported in all biochemical contents of the fish intestine. Enzyme activities such as aspartate-aminotransferase and alanine-aminotransferase were significantly elevated (p < 0.05) in the specimens collected from the polluted region. The mean total n-3 (except in spring), n-6 polyunsaturated fatty acids (except in winter), and average monounsaturated and saturated fatty acids diminished significantly (p < 0.05) in the liver of fish from contaminated habitat than control site. In the intestine of fish collected from the polluted region, significant reductions in the mean total n-3 (except in autumn as well as summer), total n-6 PUFAs (in autumn and winter), and total SFAs were reported than control site.

Integrated survey on the heavy metal distribution, sources and risk assessment of soil in a commonly developed industrial area.

The Jiangzhe Area was relatively common area that rely on industrial process for rapid development with serious heavy metals contamination. This study investigated the spatial, vertical and speciation distribution, correlation of heavy metals, as well as assessed pollution and health risks in three representative contamination industries at Jingjiang (electroplating site), Taizhou (e-waste recycling site) and Wenzhou (leather production site) in the Jiangzhe Area. The results indicated that the Cr(VI) pollution was serious in all three sites and there was a tendency to gradually decrease with depth. As for other heavy metals, not only the total concentration, but also the addition of acid soluble and reducible speciation generally decreased with soil depth at Jingjiang and Taizhou sites. Significantly positive correlations supported by correlation analysis were detected between the following elements: Cu-Ni (p < 0.01), Cr(VI)-Ni (p < 0.05) and Cr(VI)-Cu (p < 0.05) at Jingjiang site, Cu-Ni (p < 0.01), Cu-Cd (p < 0.01) and Ni-Cd (p < 0.05) at Taizhou site indicating possibly the same sources and pathways of origin, while the significantly negative correlation of Cd-Ni (p < 0.05) at Wenzhou site meaning the different sources. As regards the pollution assessment of topsoil, the mean PI value indicated that Cr(VI) contaminated severe in all three sites. In general, Jingjiang site was severe pollution (4.06), while Taizhou and Wenzhou (2.27 and 2.66) were moderate pollution, as NIPI value shown. In terms of health risk assessment that received much attention, non-carcinogenic risks caused by Pb contamination were significant for children at Jingjiang and Taizhou sites, with the HI values of 3.42E+ 00 and 2.03E+ 00, respectively. Ni caused unacceptable carcinogenic risk for both adults and children at all three sites. The present study can help to better understand the contamination characteristics of heavy metals in the commonly developed industrial area, and thus to control the environmental quality, so as to truly achieve the goal of "Green Deal objectives ".

Effect of sewage sludge-based fertilizers on biomass growth and heavy metal accumulation in plants.

This study was focused on an assessment of the agronomic efficiency of organo-mineral fertilizers based on sewage sludge and possible accumulation of heavy metals in plant biomass. Fertilizers optimized for industrial crops (rape, maize, sunflower) were used in the study. The impact of fertilizers based on sewage sludge on early stage plant growth was assessed using germination tests, and the impact on further growth and development was assessed using pot trials. The germination index of cress, sorghum and mustard was in the range of 50-92% depending on the type and dose of fertilizer and on the plant tested, which corresponded to moderate to zero toxicity. The results of pot trials showed a significant impact of fertilizers based on sewage sludge on the biomass growth of selected plants. The use of fertilizers caused an increase in fresh mass of 75-138% for rape, 96-138% for maize and 23-54% for sunflower with respect to the control sample. An increase in the dose of fertilizers for rape did not significantly affect the heavy metal content in plants, except for the content of Ni. In the case of fertilizers optimized for maize and sunflower, an increase in the dose caused an accumulation of Cd, Ni, Pb and Cr in the biomass of the tested plants. However, it should be noted that the pollution level of plant biomass for all treatments was zero to medium (1.00-1.66).

Chemometric approach in environmental pollution analysis: A critical review.

With the ever-increasing global population and industrialization, it has become a call of the hour to start taking care of the environment to balance the ecosystem. For this, effective monitoring and assessment are required, which involves collecting and measuring environmental details, temporal and spatial readings of environmental data, and parameters. However, assessment of the environment is very tedious as it includes monitoring target analytes, identifying their sources, and reporting, which invariably implies that detailed environmental monitoring would be an intricate and expensive process. The traditional protocols in environmental measures are often manual and time demanding, which makes it further difficult. Moreover, several changes also occur within the environment, which could be chemical, physical, or biological, and since these environmental impacts are often cumulative, it becomes difficult to measure an isolated system. Furthermore, the chances of skipping significant results and trends become high. Also, experimental data obtained from the environmental analysis are usually non-linear and multi-variant due to different associations among various contributing variables. Therefore, it is implied that accurate measurements and environment monitoring are not using traditional analytical protocols. Thus, the need for a chemometric approach in environmental pollution analysis becomes paramount due to the inherent limitations associated with the conventional approach of analyzing environmental datasets. Chemometrics has appeared as a potential technique, which enhances the particulars of the chemical datasets by using statistical and mathematical analysis methods to analyze chemical data beyond univariate analysis. Utilizing chemometrics to study the environmental data is a revolutionary idea as it helps identify the relationship between sources of contaminations, environmental drivers, and their impact on the environment. Hence, this review critically explores the concept of chemometrics and its application in environmental pollution analysis by briefly highlighting the idea of chemometrics, its types, applications, advantages, and limitations in the environmental domain. An attempt is also made to present future trends in applications of chemometrics in environmental pollution analysis.

Composition, environmental implication and source identification of elements in soil and moss from a pristine spruce forest ecosystem, Northwest China.

The environmental quality of remote alpine ecosystem has been drawn increasing attention owing to the increasingly severe atmospheric pollution. This study investigated the composition and sources of elements in the soil and moss collected from a pristine spruce forest in the Qilian Mountains, Northwest China. The order of mean concentrations of elements investigated in soil was Fe > K > Na > Mg > Ca > Mn > Cr > Zn > Pb > Ni > Cu > As > Cd > Hg, and that of moss was Ca > Fe > Mg > K > Na > Mn > Cr > Zn > Pb > Ni > Cu > As > Cd > Hg. The concentrations of trace metals (except for As) in soil were greater than the soil background values, with Pb contamination more serious than the other elements. The Nemerow integrated pollution index (NIPI) values indicated that the soils were heavily polluted by Pb, Cd and Ni. The potential ecological risk index (PERI) suggested that the soils were at moderate risk. In particular, Hg and Cd were the most critically potential factors for ecological risk. According to the bioaccumulation factors (BAF), the accumulated concentrations of Ca, Hg, Cd, Pb, Ni, Mg, Cr and Zn in moss were higher than those in soil. By performing the multivariate analyses, natural sources (airborne soil particles) were identified to be the major contributors for all elements, whereas anthropogenic sources also contributed to the accumulations of Pb and Cd in the soil and moss in this region.

Pollution characteristics and health risk assessment of potentially toxic elements in soils around China's gold mines: a meta-analysis.

Since toxic element pollution is widespread in soils near gold mines due to increasing mining activities, the adverse effects of potentially toxic elements (PTEs) in the soils on ecological systems and human health cannot be ignored. However, assessments of PTE pollution in soils and their ecological-health risks on a national scale are still limited. Here, the concentrations of eight PTEs in soils near gold mines throughout China were obtained from published articles. Based on these data, the pollution levels and ecological-health risks of the eight PTEs in soils were comprehensively estimated. The results showed that the average contents of As, Cr, Cd, Pb, Hg, Cu, Ni, and Zn were 81.62, 79.82, 1.04, 206.03, 2.05, 40.82, 71.82, and 130.42 mg kg-1, respectively, which exceeded the corresponding background values for soils. Most of the examined soils were heavily polluted by Hg and Cd, and higher pollution levels were found in the Henan and Shaanxi Provinces than in other regions. The average potential ecological risk value of all PTEs was 2534.71, indicating the presence of very high risks. Contribution of Hg to the potential ecological risk was more than 80%. For adults, all hazard index (HI) values of noncarcinogenic risks were below the safe level of 1.00. For children, none of the HI values exceeded the safe level, with the exception of As (HI = 1.81); nevertheless, four PTEs (As, Cr, Cu, and Ni) presented unacceptable carcinogenic risks. This study provides scientific basis for controlling PTE contamination and reducing the health risks in soils near gold mines worldwide.

Source apportionment and health risk assessment of potentially toxic elements in soil from mining areas in northwestern China.

Soil contaminated with toxic elements from mining activities is a public health concern. In order to obtain a comprehensive understanding of the status and potential risks of inorganic toxic elements in soil resulting from mining activities, Cu, Pb, Cr, Zn, Ni, As, and Cd were selected to evaluate a total of 42 soil samples collected from Gannan mining areas in northwestern China. The concentrations of As and Cd were much higher than their respective background values, while the concentrations of the other elements fluctuated around their background values. Results of combined multivariate statistical analyses and the distribution patterns of the individual pollutants imply that the toxic elements were originated from different sources even for one element in different sampling locations. The pollution index values indicated that As and Cd have a moderate to high pollution levels. The geo-accumulation indexes (Igeo) indicated that Cu, Pb, Cr, Zn, and Ni are likely of geologic origin, while As and Cd have been significantly affected by anthropogenic activities. Potential ecological risk indexes further showed that soils from mining areas within the study area pose a high potential ecological risk, and As and Cd were major risk contributors. Based on the calculated Hazard Index, the ingestion of soil particles appeared to be the main exposure route resulting in a higher risk, followed by dermal contact. The potential health risks of children and adults for As were greater than the safe level. The carcinogenic risk associated with As for local residents was also higher than the accepted levels, indicating a serious health risk to local residents. These results suggest that proper management strategies and various remediation practices should be implemented in the Gannan mining area in northwestern China.

Pollution status and human health risk assessment of potentially toxic elements and polycyclic aromatic hydrocarbons in urban street dust of Tyumen city, Russia.

This study investigated levels and sources of pollution and potential health risks associated with potentially toxic elements (PTEs) and polycyclic aromatic hydrocarbons (PAHs) in urban street dust collected from Tyumen city, a large transport centre with one of the highest motorization rates in Russia. Twenty street dust samples were collected from four grades of roads in five different land use areas. Research methods included measurements of physical and chemical properties of street dust, concentrations of 18 PTEs using inductively coupled plasma mass spectrometry, 12 PAHs using high-performance liquid chromatography, and statistical analysis of the data. Concentrations of Ni, Cr, Sb, and Mo, as well as medium and high molecular weight PAHs in urban street dust, were notably higher than in soils within the city, which indicates that transport is the main source of these elements. Concentrations of Cu, Cd, Pb, Zn, Mn, and As in street dust of Tyumen were lower compared to many large cities, while Cr, Ni, and Co were higher. Concentrations of PAH were comparable to other large nonindustrial cities. Total contamination of street dust by both PTEs and PAHs showed more robust relationships with the number of roadway lanes rather than land use. The estimated carcinogenic risks were low in 70% of samples and medium in 30% of samples. Noncarcinogenic risks were attributed to exposure to Co, Ni, V, and As. The total noncarcinogenic risk for adults was found to be negligible, while the risk was found to be moderate for children.

Inferences on metal pollution in the natural spawning zone of Bangladesh river and pollution management strategies.

The purpose of this study was to evaluate the metal concentrations in the Halda River in Bangladesh to determine the quality of the water and sediment in the natural spawning zone. Fe > Zn > Cr > Cd > Cu was the order of the metals in water, whereas Fe > Zn > Cd > Cu was the order in sediments. Almost all of the heavy metals in the water and sediment had been found within the established limits, with the exception of Cr and Fe in the river and Cu in the sediment. In the case of water, Cr vs. Zn was found to have the strongest correlation (r = 0.96). Due to the coagulation and adsorption processes, it was shown that Fe and Zn had a substantial correlation of 0.96, Cu and Cd of 0.91, and Cr of 0.78 with Zn. Hazard quotient values of Cd show the not potable nature of Halda river surface water and might give adverse health effects for all age groups except Cu and Zn. Pollution load index values indicated the uncontaminated nature of the river bottom sediments. Natural and human activities were the key factors influencing the accumulation and movement of heavy metals in the water and sediments. Contamination sources are industrial effluents, garbage runoff, farming operations, and oil spills from fishing vessels which are comparable according to multivariate statistical analysis. Ion exchange, absorption, precipitation, complexation, filtration, bio-absorption, redox reaction, and reverse osmosis were considered to be effective for the degradation of metal concentrations. The feasibility of the suggested metal reduction procedures has to be studied to know which is optimally appropriate for this river region. It is expected that this study could provide a useful suggestion to decrease the metal pollution in the river.

Do trace metal(loid)s in road soils pose health risks to tourists? A case of a highly-visited national park in China.

Nowadays, more people tend to spend their recreational time in large national parks, and trace metal(loid)s in soils have attracted long-term attention due to their possible harm to human health. To investigate the pollution levels, potential sources and health risks of trace metal(loid)s in road soils, a total of eight trace metal(loid)s (including As, Cd, Cr, Cu, Ni, Pb, Zn and Hg) from 47 soil samples along roads were studied in the Huangshan National Park in Southeast China. The results showed that the concentrations of As, Cd, Pb, Zn and Hg appeared different degrees of pollution compared with their corresponding background values. According to the pollution indices, Hg and Cd were recognized as significant pollutants presenting moderate to high ecological risk. Combining principal component analysis and positive matrix factorization model, the results showed that traffic, industrial, agricultural and natural sources were the potential origins of trace metal(loid)s in this area, with contribution rates of 39.93%, 25.92%, 10.53% and 23.62%, respectively. Non-carcinogenic risks were all negligible, while the carcinogenic risk of As was higher than the limit (1 × 10-6). Moreover, children were more susceptible to trace metal(loid)s by ingestion which appeared to be a more important exposure pathway than dermal contact and inhalation. The contribution rates of different sources to non-carcinogenic risks and carcinogenic risks were similar among children and adults, while traffic and industrial sources have a significant impact on health risks. This study will give more insights to control the environmental risks of trace metal(loid)s in national parks.

Evaluating Lower Athabasca River Sediment Metal Concentrations from Alberta Oil Sands Monitoring Programs Using Predevelopment Baselines.

Since 1997, sediment metal concentrations have been monitored in the Alberta Oil Sands Region (AOSR) of the Lower Athabasca River by the Regional Aquatics Monitoring Program (RAMP; 1997-2002), the Joint Oil Sands Monitoring Program (JOSM; 2012-2014), and the Oil Sands Monitoring Program (OSM; 2015-present). However, it has remained difficult to differentiate industrial sources from natural sources and quantify the extent of pollution due to inadequate knowledge of predevelopment reference conditions. Here, baselines were constructed using predevelopment (i.e., pre-1967) sediment concentrations of US EPA priority pollutants (Be, Cr, Cu, Ni, Pb) and V, an element elevated in bitumen and associated waste materials, normalized to Al concentration in cores from floodplain and upland lakes within the AOSR to characterize the natural range of variability. The Lower Athabasca River sediment metal monitoring data were examined in the context of the predevelopment baselines. Most metals are below the threshold for minimal enrichment (<1.5x baseline) except for chromium (up to 4.8x) in some RAMP samples. The predevelopment baselines for sediment metal concentrations will be of particular importance as the oil sands industry potentially shifts from a no-release policy to the treatment and release of oil sands process waters directly to the Lower Athabasca River.

An improved weighted index for the assessment of heavy metal pollution in soils in Zhejiang, China.

Soil heavy metal pollution assessment is an important procedure in soil quality and ecological risk management, for which different mathematical models have been developed. However, these models have often failed to consider the characteristics of both heavy metals and the polluted sites. In this study, we analyzed the concentrations of seven heavy metals in soils in Zhejiang Province, China, and developed an improved weighted index (IWI) model to evaluate pollution levels. In contrast to traditional models, weights were assigned to different heavy metals using statistical tools, including hierarchical cluster analysis and principal component analysis. Of the 89 sites, 61.8% were considered unpolluted with IWI values < 1; 32.58% were slighted polluted with IWI values from 1 to 2, and only 2.25% of the sites were seriously polluted with IWI values > 3. The IWI results agree well with two traditional integrated index models, but can be also applied to much wider heavy metal concentration ranges. Possible pollution sources were then proposed based on the IWI model. The IWI overcame several shortcomings of the traditional indices and could be very beneficial for assessing heavy metal pollution in soil. Overall, this study developed a new model for soil pollution assessment and soil ecological risk management and comprehensively evaluated the current pollution status of soil surrounding potable surface water sources in Zhejiang Province, China.