Gold nanoparticle-based sensors activated by external radio frequency fields.

A novel molecular beacon (a nanomachine) is constructed that can be actuated by a radio frequency (RF) field. The nanomachine consists of the following elements arranged in molecular beacon configuration: a gold nanoparticle that acts both as quencher for fluorescence and a localized heat source; one reporter fluorochrome, and; a piece of DNA as a hinge and recognition sequence. When the nanomachines are irradiated with a 3 GHz RF field the fluorescence signal increases due to melting of the stem of the molecular beacon. A control experiment, performed using molecular beacons synthesized by substituting the gold nanoparticle by an organic quencher, shows no increase in fluorescence signal when exposed to the RF field. It may therefore be concluded that the increased fluorescence for the gold nanoparticle-conjugated nanomachines is not due to bulk heating of the solution, but is caused by the presence of the gold nanoparticles and their interaction with the RF field; however, existing models for heating of gold nanoparticles in a RF field are unable to explain the experimental results. Due to the biocompatibility of the construct and RF treatment, the nanomachines may possibly be used inside living cells. In a separate experiment a substantial increase in the dielectric losses can be detected in a RF waveguide setup coupled to a microfluidic channel when gold nanoparticles are added to a low RF loss liquid. This work sheds some light on RF heating of gold nanoparticles, which is a subject of significant controversy in the literature.

Design and fabrication of multi-material broadband electromagnetic absorbers for use in cavity-backed antennas.

We investigated the feasibility of designing and fabricating novel broadband radiofrequency (RF) absorbers for use in cavity-backed antennas. Fabricating the absorber involved a multi-material additive manufacturing (AM) approach that combined two polymer filaments: a low-loss dielectric filament and a lossy carbon-loaded filament. An iterative optimization algorithm was developed to deploy these filaments and create gradient distributions of material properties that minimize reflectance over a desired frequency band and a range of incident angles to achieve wideband electromagnetic absorption. The chosen material profiles were effectively realized using a spatially varying subwavelength lattice structure printed via fused filament fabrication. Experimentally, validation results demonstrated low reflectance over a wide frequency band, 10 to 40 GHz, and a range of incident angles, 0°-50°. Finally, this printed multi-material absorber was integrated within a cavity-backed spiral antenna and used to suppress backlobe radiation while maintaining an acceptable radiation pattern in the forward direction. While this study investigated cavity-backed antennas, these computational and experimental methods are potentially useful for a wide range of other applications.