PLA/PCL/NR ternary blown films with high ductility and thermal shrinkage performance via dynamic vulcanization.

The low melt strength and brittleness of polylactic acid (PLA) significantly limit its application in high-performance and functional films. In this study, we successfully prepared ternary thermoplastic vulcanizates (TPVs) comprising of PLA, poly(caprolactone) (PCL) and natural rubber (NR), which exhibit co-continuous structure. During the peroxide-induced dynamic vulcanization process, PLA chains were effectively grafted and anchored to the cross-linked rubber network, thereby enhancing the melt strength of the material. This improvement allowed the ternary TPVs to be continuously and stably blown into films. The films exhibited excellent mechanical properties due to the synergistic effect of ductile PCL and elastic NR. Both the elongation at break and tear strength improved greatly. Interestingly, during the film blowing process, the highly stretched continuous NR crosslinked network stored large amounts of elastic energy, endowing the film with excellent heat shrinkage performance. With 15 phr NR, the heat shrinkage exceeded 35 %, which is sufficient for practical needs. This biodegradable film with heat-shrinkage properties can be processed on a large scale, offering a potential strategy to the urgent issue of plastic film pollution.

Effect of rheological behaviors of polyacrylonitrile grafted sericin solution on film structure and mechanical properties.

Sericin protein possesses excellent biocompatibility, antioxidation, and processability. Nevertheless, manufacturing large quantities of strong and tough pure regenerated sericin materials remains a significant challenge. Herein, we design a lightweight structural sericin film with high ductility by combining radical chain polymerization reaction and liquid-solid phase inversion method. The resulting polyacrylonitrile grafted sericin films exhibit the ability to switch between high strength and high toughness effortlessly, the maximum tensile strength and Young's modulus values are 21.92 ± 1.51 MPa and 8.14 ± 0.09 MPa, respectively, while the elongation at break and toughness reaches up to 344.10 ± 35.40 % and 10.84 ± 1.02 MJ·m-3, respectively. Our findings suggest that incorporating sericin into regenerated films contributes to the transformation of their mechanical properties through influencing the entanglement of molecular chains within polymerized solutions. Structural analyses conducted using infrared spectroscopy and X-ray diffraction confirm that sericin modulates the mechanical properties by affecting the transition of condensed matter conformation. This work presents a convenient yet effective strategy for simultaneously addressing the recycling of sericin as well as producing regenerated protein-based films that hold potential applications in biomedical, wearable, or food packaging.

Study on High-Ductility Geopolymer Concrete: The Influence of Oven Heat Curing Conditions on Mechanical Properties and Microstructural Development.

Low carbon and high performance have become key trends in the development of construction materials. Understanding the mechanism by which curing conditions affect the mechanical properties of high-ductility geopolymer concrete (HDGC) is of significant importance. This study investigated three sealing curing temperatures (room temperature, 45 °C, and 60 °C) and four curing durations (1 day, 3 days, 5 days, and 7 days), while considering two final curing ages (7 days and 28 days) to explore their effects on the axial tensile and compressive properties of HDGC. The results showed that both 45 °C and 60 °C could improve the brittle failure of HDGC under axial compressive loading. However, curing at 60 °C and for durations longer than 1 day in an oven would catalyze the formation of eight-faced zeolite crystals within the slag-fly ash geopolymer matrix, and it could weaken the matrix's pore structure and subsequently affect the material's later strength development. Nevertheless, oven heat curing enhanced the bridging effect between the fibers and the matrix, partially compensating for the reduction in the initial tensile strength of HDGC. This follows the pseudo-strain-hardening material's saturation cracking criterion to enhance the strain-hardening behavior of HDGC and improve its tensile energy absorption capacity. A curing condition of 45 °C for 5 days is recommended to maximize the ductility of HDGC. This study provides important theoretical support for the design and promotion of green, low-carbon, high-ductility composite materials.

Volume Stability and Frost Resistance of High-Ductility Magnesium Phosphate Cementitious Concrete.

To address the issue of pavement cracking due to brittle concrete in road and bridge engineering, this study explores the use of high-ductility magnesium phosphate cementitious concrete (HD-MPCC) for rapid repairs. The deformation and frost properties of HD-MPCC are analyzed to assess its suitability for this application. Deformation properties were tested for HD-MPCC specimens cured in both air and water. Subsequent tests focused on the frost performance and mechanical properties after freeze-thaw cycles. A mercury penetration technique was utilized to examine the pore structure. The findings reveal that the expansion deformation of HD-MPCC increases with curing age in both air and water conditions, and the quantitative relationship between the expansion deformation and curing age of HD-MPCC was analyzed. Additionally, the freeze-thaw cycles led to a decrease in mass loss, the relative dynamic elastic modulus, the ultimate tensile strength, the ultimate tensile strain, the flexural strength, and the peak deflection. The volume fraction of harmless and less harmful pores gradually decreased as the freeze-thaw cycle increased, while the volume fraction of more harmful pores increased, resulting in a decrease in the strength, ultimate tensile strain, and peak deflection.

Preparation of High-Ductility Cement-Calcined Coal-Gangue-Powder-Composite-Based Rapid Repair Material.

Coal gangue is a kind of solid waste. A high-ductility cement-calcined coal-gangue-powder-composite-based rapid repair material (HD-RRM) was prepared by partially replacing cement with calcined coal gangue powder (CCGP) for achieving high ductility and rapid hardening and conforming to the strength requirements of pavement layers. First, the physical and chemical properties and the reactivity of the CCGP were investigated. Second, HD-RRM material was prepared, and its tensile performance characteristic parameters were investigated. Lastly, the hydration products and microstructure of HD-RRM were characterized through tests (e.g., non-evaporable water content, scanning electron microscopy (SEM), X-ray diffraction (XRD), and comprehensive thermogravimetric analysis and differential scanning calorimetry (TG-DSC)). As indicated by the experimental results, the CCGP with a particle size of 1250 mesh exhibited the maximum potential reactivity. The optimal mixing ratio for HD-RRM in the experiments comprised a water-cement ratio of 0.27, a sand-cement ratio of 0.3, a fiber volume fraction of 2%, a cement content of 70%, a CCGP content of 20%, a fly ash (FA) content of 10%, and a superplasticizer content of 0.1%. Using the abovementioned mix design, the prepared HD-RRM was endowed with a 6 h ultimate elongation of 2.75%, an ultimate tensile strength of 7.58 MPa, a compressive strength of 45.4 MPa, and an average crack width of 125.53 µm, which meets the requirements of repair materials and provides a design method for CCGP resource utilization and asphalt concrete road and bridge deck repair.

Effect of Ambient Temperature on the Mechanical Properties of High Ductility Concrete.

This study analyzes the mechanical properties of high ductility concrete (HDC) under different ambient temperatures to provide a parameter basis for the design of HDC bridge deck link slabs. Five temperatures (-30, 0, 20, 40, and 60 °C) were designed to investigate the compressive, tensile, and flexural properties of HDC after temperature treatment and analyze the pore structure. The results show that, compared with the HDC performance at room temperature (20 °C), the compressive strength, ultimate tensile strength, and flexural strength decreased after treatment at low temperatures (-30 and 0 °C), while the strength increased after treatment at high temperatures (40 and 60 °C). After experiencing low- and high-temperature treatments, the ultimate tensile strain and ultimate deflection of the HDC increased. The tensile and flexural failures of the HDC exhibited multiple cracking, and the stress-strain/deflection curve showed a strain/deflection hardening stage. The tensile constitutive relationship can be simplified as a bilinear two-stage relationship. As the temperature increased, the porosity of harmless and less harmful pores in HDC gradually increased, while the porosity of harmful and more harmful pores gradually decreased, resulting in an increase in HDC strength. Based on the influence of temperature on HDC properties, design parameters for the HDC bridge deck link slab structure are proposed.

Shielding Effectiveness and Impact Resistance of Concrete Walls Strengthened by High-Strength High-Ductility Concrete.

Following the fourth Industrial Revolution, electronic and data-based technology is becoming increasingly developed. However, current research on enhancing electromagnetic interference (EMI) shielding and the physical protection performance of structures incorporating these technologies is insufficient. Therefore, in this study aiming for the improvement of EMI shielding and structural performance of structures, twelve concrete walls were fabricated and tested to determine their shielding effectiveness and drop-weight impact resistance. Concrete walls strengthened by three thickness types of high-strength, high-ductility concrete (HSDC) have been considered. The test results showed that the shielding effectiveness with strengthening thickness increased by approximately 35.6-46.2%. Specimens strengthened by more than 40% and 10% of the strengthening area ratio of single- and double-layer, respectively, exhibited more than 20 dB of shielding effectiveness. Moreover, the relationship between the damaged area ratio and shielding effectiveness was evaluated by means of the drop-weight impact test. The structural performance and EMI shielding effectiveness improved as the HSDC thickness increased.

Experimental Study on Mechanical Properties of High-Ductility Concrete against Combined Sulfate Attack and Dry-Wet Cycles.

Concrete will deteriorate and damage under sulfate attack.In order to study the degradation characteristics of HDC under sulfate attack, the mechanical properties of high-ductility concrete (HDC) were investigated using the uniaxial compressive strength test of HDC specimens soaked in different concentrations of sulfate solution and subjected to different times of dry-wet cycles. The variations in the compressive strength, loss rate of compressive strength, and the max compressive strength under the action of sulfate attack and dry-wet cycles were analyzed. The analytical expressions of damage variables were given. SEM was used to observe the microstructure of the sample, and the microdamage mechanism of the HDC was explored. The deterioration of the HDC was found to be the result of the combined action of sulfate attack and dry-wet cycles and was caused by physical attack and chemical attack. PVA prevented the rapid development of deterioration. On the basis of the change of compressive strength, the damage variable was established to quantitatively describe the degree of damage to HDC. The experimental results showed that with the increase in the number of dry-wet cycles, the compressive strength of HDC generally increased first and then decreased. As the concentration of the sulfate solution increased, the loss rate of the compressive strength of HDC generally increased and the max compressive strength gradually decreased. With the increase inthe number of dry-wet cycles, HDC first showed self-compacting characteristics and then gradually became destroyed. Compared with ordinary concrete (OC), HDC is superior to OC in sulfate resistance and dry-wet cycles. This study provided a test basis for the engineering application of HDC in sulfate attack and dry-wet cycles environment.

Bond Strength and Flexural Capacity of Normal Concrete Beams Strengthened with No-Slump High-Strength, High-Ductility Concrete.

This study investigates the flexural behavior of normal-strength concrete (NSC) beams that were strengthened with no-slump, high-strength, high-ductility concrete (NSHSDC). A set of slant shear tests was performed to investigate the initial performance of the NSC substrate strengthened with NSHSDC. Slant shear tests considered two types of roughness of interface and five angles of the interface between NSC and NSHSDC. The test results showed that except for specimens with a 75° interface angle, the specimens with high roughness were conformed to the properties (14-21 MPa for 28 days) of the ACI Committee 546 recommendation. For flexural strength tests, NSC beams strengthened with an NSHSDC jacket on the top and bottom sides, three sides, and four sides resulted in strength increments of about 8%, 29%, and 40%, respectively, compared to the beams without NSHSDC jacket. Therefore, the use of NSHSDC is an effective method to improve the performance of NSC beams and is recommended for strengthening reinforced concrete members.

Experimental Research on Concrete Beams Reinforced with High Ductility Steel Bars and Strengthened with a Reactive Powder Concrete Layer in the Compression Zone.

The article describes four-point bending tests of three reinforced concrete beams with identical cross-sections, spans, and high-ductility steel reinforcement systems. Two beams were strengthened in the compressed section with a thin layer of reactive powder concrete (RPC) bonded with evenly spaced stirrups. Their remaining sections, and the third reference beam, were made of ordinary concrete. Measurements of their deflections, strains and axis curvature; ultrasonic tests; and a photogrammetric analysis of the beams are the main results of the study. For one of the beams with the RPC, the load was increased in one stage. For the two remaining beams, the load was applied in four stages, increasing the maximum load from stage to stage in order to allow the analysis of the damage evolution before reaching the bending resistance. The most important effect observed was the stable behaviour of the strengthened beams in the post-critical state, as opposed to the reference beam, which had about two to three times less energy-absorbing capacity in this range. Moreover, thanks to the use of the RPC layer, the process of concrete cover delamination in the compression zone was significantly reduced, the high ductility of the rebars was fully utilized during the formation of plastic hinges, and the bending capacity was increased by approximately 12%.

Using Green Supplementary Materials to Achieve More Ductile ECC.

To improve the greenness and deformability of engineered cementitious composites (ECC), recycled powder (RP) from construction and demolition waste with an average size of 45 µm and crumb rubber (CR) of two particle sizes (40CR and 80CR) were used as supplements in the mix. In the present study, fly ash and silica sand used in ECC were replaced by RP (50% and 100% by weight) and CR (13% and 30% by weight), respectively. The tension test and compression test demonstrated that RP and CR incorporation has a positive effect on the deformability of ECC, especially on the tensile strain capacity. The highest tensile strain capacity was up to 12%, which is almost 3 times that of the average ECC. The fiber bridging capacity obtained from a single crack tension test and the matrix fracture toughness obtained from 3-point bending were used to analyze the influence of RP and CR at the meso-scale. It is indicated that the replacement of sand by CR lowers the matrix fracture toughness without decreasing the fiber bridging capacity. Accordingly, an explanation was achieved for the exceeding deformability of ECC incorporated with RP and CR based on the pseudo-strain hardening (PSH) index.

In Vitro and in Vivo Evaluation of Multiphase Ultrahigh Ductility Mg-Li-Zn Alloys for Cardiovascular Stent Application.

Magnesium alloys have been extensively studied as a novel biodegradable metallic material for cardiovascular stent application. However, the ductility limitation of magnesium alloy has been a key issue for biodegradable stents applications. In this study, two different multiphase ultrahigh ductility Mg-Li-Zn alloys, LZ61 and LZ91, are fabricated in the form of extruded rods and evaluated both in vitro and in vivo. The microstructure, mechanical properties and in vitro degradation are evaluated as well as in vitro cytotoxicity. The in vivo degradation, tissue response, and systematic toxicity are evaluated in a mouse subcutaneous model. Measurements show that LZ61 and LZ91 exhibit more than 40% elongation at fracture without significantly compromising the strength. Both in vitro and in vivo degradation showed low degradation rates for LZ61 but high degradation rate for the LZ91 alloy. Excellent biocompatibility is observed both in vivo and in vitro for LZ61 and LZ91. In summary, this study successfully demonstrates that the ultraductility multiphase Mg-Li-Zn alloy has the potential to be used for stent applications. Compared to LZ91, the LZ61 alloy shows better balance of mechanical properties, corrosion resistance, and biocompatibility, indicating its promise for cardiovascular stent applications.

Mechanical Properties of Hybrid Ultra-High Performance Engineered Cementitous Composites Incorporating Steel and Polyethylene Fibers.

This paper presents the authors' newly developed hybrid ultra-high performance (HUHP) engineered cementitious composite (ECC) with steel (ST) and polyethylene (PE) fibers. From this point on it will be referred to as HUHP-ECC. The volumes of steel and PE fibers were adjusted to obtain different mechanical properties, including compressive strength, tensile, and flexural properties. We found that tensile and flexural properties, including bending strength and ductility indexes, increased with higher PE fiber amounts but reduced with the increased ST fiber volume. Notably, the compressive strength had the opposite tendency and decreased with increases in the PE volume. The ST fiber had a significantly positive effect on the compressive strength. The fluidity of HUHP-ECC improved with the increasing amount of ST fiber. The pseudo strain-hardening (PSH) values for all the HUHP-ECC mixtures were used to create an index indicating the ability of strain capacity; thus, the PSH values were calculated to explain the ductility of HUHP-ECC with different fiber volumes. Finally, the morphology of PE and ST fibers at the fracture surface was observed by an environmental scanning electron microscope (ESEM).