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1.
Small ; 20(6): e2306104, 2024 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-37775948

RESUMO

Microwave absorbers with high efficiency and mechanical robustness are urgently desired to cope with more complex and harsh application scenarios. However, manipulating the trade-off between microwave absorption performance and mechanical properties is seldom realized in microwave absorbers. Here, a chemistry-tailored charge dynamic engineering strategy is proposed for sparking hetero-interfacial polarization and thus coordinating microwave attenuation ability with the interfacial bonding, endowing polymer-based composites with microwave absorption efficiency and mechanical toughness. The absorber designed by this new conceptual approach exhibits remarkable Ku-band microwave absorption efficiency (-55.3 dB at a thickness of 1.5 mm) and satisfactory effective absorption bandwidth (5.0 GHz) as well as desirable interfacial shear strength (97.5 MPa). The calculated differential charge density depicts the uneven distribution of space charge and the intense hetero-interfacial polarization, clarifying the structure-performance relationship from a theoretical perspective. This work breaks through traditional single performance-oriented design methods and ushers a new direction for next-generation microwave absorbers.

2.
Entropy (Basel) ; 26(1)2024 Jan 10.
Artigo em Inglês | MEDLINE | ID: mdl-38248185

RESUMO

The microwave absorption performance of high-entropy alloys (HEAs) can be improved by reducing the reflection coefficient of electromagnetic waves and broadening the absorption frequency band. The present work prepared flaky irregular-shaped Al1.5Co4Fe2Cr and Al1.5Co4Fe2Cr@rGO alloy powders by mechanical alloying (MA) at different rotational speeds. It was found that the addition of trace amounts of reduced graphene oxide (rGO) had a favorable effect on the impedance matching, reflection loss (RL), and effective absorbing bandwidth (EAB) of the Al1.5Co4Fe2Cr@rGO HEA composite powders. The EAB of the alloy powders prepared at 300 rpm increased from 2.58 GHz to 4.62 GHz with the additive, and the RL increased by 2.56 dB. The results showed that the presence of rGO modified the complex dielectric constant of HEA powders, thereby enhancing their dielectric loss capability. Additionally, the presence of lamellar rGO intensified the interfacial reflections within the absorber, facilitating the dissipation of electromagnetic waves. The effect of the ball milling speed on the defect concentration of the alloy powders also affected its wave absorption performance. The samples prepared at 350 rpm had the best wave absorption performance, with an RL of -16.23 and -17.28 dB for a thickness of 1.6 mm and EAB of 5.77 GHz and 5.43 GHz, respectively.

3.
Nanotechnology ; 32(34)2021 Jun 04.
Artigo em Inglês | MEDLINE | ID: mdl-34086606

RESUMO

Ferrite nano-hollow spheres (NHS) are of great significance to improve electromagnetic (EM) wave absorption performance. Herein, the deposition of dielectric SiO2and ferrimagnetic CoFe2O4(CFO) layers on MnFe2O4(MnFO) NHS are found as an effective strategy to enhance EM wave attenuation. EM wave absorption properties of as-synthesized bare and bi-layered samples are investigated within a widely-used frequency range of 1-17 GHz. MnFO@CFO bi-layered NHSs exhibit an excellent reflection loss (RL) of -47.0 dB at only 20 wt% filler content with an effective broad bandwidth (BW) of ∼2.2 GHz (frequency region for RL < -10 dB). The attenuation constant is observed to increase from 191.6 Np m-1to 457.8 Np m-1for bare MnFO and MnFO@CFO NHSs respectively. Larger interfacial area, additional pairs of dipole, higher magnetic anisotropy, internal reflections and scattering from NHSs are responsible for superior absorption properties of MnFO@CFO NHSs. Moreover, the best impedance matching,∣Zin/Z0∣ âˆ¼ 1, promotes the optimum RL in MnFO@CFO at 5.96 GHz. MnFO@SiO2bi-layered NHSs result in a sufficiently high RL âˆ¼ -30.0 dB with a composite absorber of a thickness of only 3 mm. Analysis from theλ/4 model for best matching thickness (tm) displays a good agreement between experimental and simulatedtmvalues. This study demonstrates optimized MnFO@CFO NHS as a highly promising low-cost and lightweight EM wave absorber suitable for practical high-frequency applications.

4.
Heliyon ; 10(11): e32423, 2024 Jun 15.
Artigo em Inglês | MEDLINE | ID: mdl-38961901

RESUMO

Torrefaction treatment improves biomass grindability by transforming the fibrous herbaceous to a more brittle and lighter coal-like material. Microwave-assisted torrefaction is a promising technology for biomass conversion into energy, fuels, and chemicals. The study applied microwave absorbers in the torrefaction process to improve the thermochemical characteristics and grindability of switchgrass. Switchgrass in two particle sizes was torrefied in a microwave reactor with biochar added as a microwave absorber under inert conditions. After torrefaction, the geometric mean particle and size distribution and selected physical characteristics were evaluated, and the grindability of the torrefied ground and chopped with and without biochar were compared with those of untreated switchgrass. The geometric diameter results decreased, and the specific energy required for grinding torrefied switchgrass with biochar was significantly reduced with extended residence times and at a torrefaction temperature of 300 °C. After grinding, the lowest grinding energy of 32.82 kJ at 300 °C/20 min was recorded with torrefied ground switchgrass/biochar. The 10% biochar added/250 °C resulted in deep cell wall disarrangement, whereas at a torrefaction temperature of 300 °C, large surface deformation and carbonized weight fractions were observed.

5.
Heliyon ; 10(9): e29815, 2024 May 15.
Artigo em Inglês | MEDLINE | ID: mdl-38699046

RESUMO

A million ton of cotton fabric is wasted during cutting process in garment industry as well as in textile dyeing industry due to faulty dyeing. Color stripping of cotton fabric has become a significant challenge in the textile industry because the harsh chemicals used in chemical stripping processes affects the quality of fabric very badly. Conventional stripping methods lead with severe effects due to prolonged treatment time and high chemical concentrations. Recently, microwave-assisted stripping techniques have been emerged as effective alternatives to improve stripping efficiency. In this research, the developed microwave assisted stripping system is improved by the application of Urea, which is utilized as a microwave absorber to further reduce stripping time, temperature, and chemical concentration kept focus on quality parameters of recycled cotton fabric. This study inspects the efficiency of microwave absorber-assisted alkali hydrolysis and reduction in terms of dye-fabric bond cleavage, chromophores removal, chemical consumption, and processing time and compared with sequential stripping, microwave assisted stripping without absorber and conventional methods. The results indicated that microwave absorber-assisted alkali hydrolysis and reduction achieved 90 % stripping efficiency by using lowest concentrations of chemicals, while sequential stripping yielded a stripping efficiency of 96 %. Similarly, microwave absorber assisted methods resulted in minor loss in tear strength and weight. These outputs highlight the superior performance of microwave absorber-assisted techniques, demonstrating their efficiency, novelty, time-saving nature, and reduced damage compared to other methods.

6.
ACS Appl Mater Interfaces ; 16(26): 33846-33854, 2024 Jul 03.
Artigo em Inglês | MEDLINE | ID: mdl-38899405

RESUMO

Exploring a convenient, scalable, yet effective broadband electromagnetic wave absorber (EMA) in the gigahertz (GHz) region is of high interest today to quench its expanding demand. Ni-Zn ferrite is considered as a potential EMA; however, their performance study as a scalable effective millimeter-length absorber is still limited. Herein, we investigated EM wave attenuation properties of Ni0.5Zn0.5Fe2O4 (NZF) samples substituting Mn ion in place of Fe3+ as well as Zn2+ within a widely used frequency range of 0.1-9 GHz. Through composition optimization, Ni0.5Zn0.4Mn0.1Fe2O4 (NZM0.1F) EMA demonstrates excellent microwave absorption performance accompanied by simultaneous maximum reflection loss (RL) of -50.2 dB and wide BW of 6.8 GHz (with RL < -10 dB, i.e., attenuation >90%) at an optimum thickness of 6 mm. Moreover, the attenuation constant significantly increases from ∼217 to 301 Np/m with Mn doping. The key contribution arises from magnetic-dielectric properties synergy along with enhanced dielectric and magnetic losses owing to cation chemistry and site occupation in spinel NZF. In addition, porosity is induced in the system by a controlled two-step heat treatment process that promotes total loss with multiple internal reflections of the EM wave. Furthermore, RL is simulated by varying incident EM wave angles for the NZM0.1F sample displaying its angle insensitivity up to 50°. Our results reveal NZM0.1F as a futuristic environment-friendly microwave absorber material that is suitable for practical high-frequency applications.

7.
Artigo em Inglês | MEDLINE | ID: mdl-36411549

RESUMO

BACKGROUND: In recent years, severe electromagnetic interference among electronic devices has been caused by the unprecedented growth of communication systems. Therefore, microwave absorbing materials are required to relieve these problems by absorbing the unwanted microwave. In the design of microwave absorbers, magnetic nanomaterials have to be used as fine particles dispersed in an insulating matrix. Besides the intrinsic properties of these materials, the structure and morphology are also crucial to the microwave absorption performance of the composite. In this study, Ni-Co-MWCNT composites were synthesized, and the changes in electric permittivity, magnetic permeability, and reflectance loss of the samples were evaluated at frequencies of 2 to 18 GHz. METHODS: Nickel-Cobalt-Multi Wall Carbon Nanotubes (MWCNT) composites were successfully synthesized by the co-precipitation chemical method. The structural, morphological, and magnetic properties of the samples were characterized and investigated by X-ray diffractometer (XRD), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), Vibrating Sample Magnetometer (VSM), and Vector Network Analyzer (VNA). RESULTS: The results revealed that the Ni-Co-MWCNT composite has the highest electromagnetic wave absorption rate with a reflectance loss of -70.22 dB at a frequency of 10.12 GHz with a thickness of 1.8 mm. The adequate absorption bandwidth (RL <-10 dB) was 6.9 GHz at the high-frequency region, exhibiting excellent microwave absorbing properties as a good microwave absorber. CONCLUSION: Based on this study, it can be argued that the Ni-Co-MWCNT composite can be a good candidate for making light absorbers of radar waves at frequencies 2- 18 GHz.

8.
Environ Technol ; 43(5): 658-672, 2022 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-32677866

RESUMO

In the present study, the raw materials and produced bio-oil were characterized in terms of physical and chemical properties. Response surface methodology (RSM) based on central composite was used to investigate the process parameter significance on bio-oil yield. The statistical significance is indicated by P-value of less than 0.05 at 95% confidence level. For raw material, coal lignite spectrum showed potential existence of phenols, alcohol and water linked to mineral water associated with the hydroxyl group found in stretching vibrations that are between 3200 and 3400 cm-1. The oxygen-containing groups such as C = O, C-O and aromatic skeletal lignin from lignocellulosic materials were observed on the coal lignite spectrum. Sewage sludge spectrum showed the presence of amide I, amide II, aliphatic methylene, lipids and fats. Si-O of clay minerals and silicates impurities were attributed by peaks 872 and 1031 cm-1 on the primary sewage sludge spectrum, respectively. The produced bio-oil results from Gas chromatography-Mass spectrometry (GC-MS) were in agreement with Nuclear magnetic resonance (NMR) and Fourier-transform infrared (FTIR) spectroscopy results. Maximum bio-oil of 42 wt% was obtained under the following conditions : temperature, 550°C, heating rate, 180.3°C/min and particle size 425 µm.


Assuntos
Pirólise , Esgotos , Biocombustíveis/análise , Carvão Mineral , Temperatura Alta , Micro-Ondas , Óleos de Plantas , Polifenóis
9.
ACS Appl Mater Interfaces ; 14(5): 7109-7120, 2022 Feb 09.
Artigo em Inglês | MEDLINE | ID: mdl-35080181

RESUMO

The positively charged MoO3/PDA microspheres are obtained by stacking and assembly of the sheet structure, and the negatively charged MXene nanosheets are wrapped on the surface through the principle of electrostatic self-assembly. After annealing, a nitrogen-doped carbon composite and a MXene-coated Mo2C wave absorber are obtained. The formation of the wrinkled surface provides a complex pore structure, and the multiple interface reflections between the nanosheets enhance the absorption performance. The existence of heterogeneous interfaces and the uneven distribution of space charges accumulated between the interfaces effectively reduce the minimum reflection loss (RLmin). This work explores the effects of the ratio between MoO3/PDA and MXene nanosheets and loading amount on the microwave absorption properties. Mo2C/NC@MXene-2 obtained when the ratio of the two is 3:1 has the best absorption performance under 25% loading. The RLmin is -59.36 dB, and the corresponding effective absorption bandwidth (EAB) is 4.6 GHz at 2.5 mm. This work expands the new applications of MXene-based and Mo2C-based materials and has a guiding significance for the design of electrostatic self-assembly materials.

10.
Polymers (Basel) ; 13(23)2021 Dec 03.
Artigo em Inglês | MEDLINE | ID: mdl-34883751

RESUMO

Ni0.5Zn0.5Fe2O4 nanofibers with an average diameter of 133.56 ± 12.73 nm were fabricated by electrospinning and calcination. According to our thermogravimetric-differential thermal analysis and X-ray diffraction results, the calcination temperature was 650 °C. The microstructure, crystal structure, and chemical composition of the nanofibers were observed using field-emission scanning electron, X-ray diffraction, and energy-dispersive X-ray spectroscopy. Commercial particle samples and samples containing 10 wt% and 20 wt% nanofibers were fabricated, and the electromagnetic properties were analyzed with a vector network analyzer and a 7.00 mm coaxial waveguide. Regardless of the nanofiber content, Ni0.5Zn0.5Fe2O4 was dominantly affected by the magnetic loss mechanism. Calculation of the return loss based on the transmission line theory confirmed that the electromagnetic wave return loss was improved up to -59.66 dB at 2.75 GHz as the nanofiber content increased. The absorber of mixed compositions with Ni0.5Zn0.5Fe2O4 nanofibers showed better microwave absorption performance. It will be able to enhance the performance of commercial electromagnetic wave absorbers of various types such as paints and panels.

11.
ACS Appl Mater Interfaces ; 13(28): 33496-33504, 2021 Jul 21.
Artigo em Inglês | MEDLINE | ID: mdl-34228430

RESUMO

The use of magnetic particles and carbon materials, particularly those with compatible dielectric and magnetic loss, is crucial in managing microwave pollution. However, the mismatched impedance of currently available absorbers constrains their practical applications. Herein, we demonstrate the potential of a metal-organic framework (MOF)-derived composite whose impedance matching is optimized through spraying and immersion of MOF precursors in carbon nanotube socks followed by carbonization. The composite presents extremely strong microwave absorption with a reflection loss of -30 dB, a thin thickness of 1.5 mm, and a wide frequency bandwidth of 7.8 GHz. The excellent absorption can still be maintained even at a fairly low temperature of -40 °C. Such results are primarily attributed to the synergistic effect between the hierarchical architecture and multiple components that greatly optimizes the impedance matching. We believe that the composite is a promising microwave absorber that can help to solve the critical electromagnetic wave pollution.

12.
Waste Manag ; 119: 91-100, 2021 Jan 01.
Artigo em Inglês | MEDLINE | ID: mdl-33045490

RESUMO

The sustainable future of contemporary society has been compromised due to environmental pollution from industrial systems and the generation of solid waste. Consequentially, the managed exploitation of natural resources to a sustainable level within the Earth's capacity remains a present and future challenge. Furthermore, the pursuit of materials free from toxic substances made from renewable sources is a tendency towards effective cleaner production and waste management. To address these problems, this article reports the results of exploratory and experimental research that developed a novel eco-efficient product - a pyramidal absorber of electromagnetic radiation - from rice husks and MDF (Medium Density Fibreboard) residues through design from waste principles. Key findings indicated that the technical performance of the absorber is better in the frequency of 2.45 GHz, resulting in a difference of -18.71 dB concerning the reflective metal plate used in the tests. This result is above the expected limit of -10 dB found in similar commercial products. This study is an innovation in improving the design from waste of pyramidal microwave absorbers used in radio frequency anechoic chambers. The product represents a new and sustainable alternative to similar products in the market that are produced from toxic materials extracted from non-renewable raw materials. The limitations and technical characteristics of usage for which the pyramidal absorbers of electromagnetic radiation are applicable should be considered.


Assuntos
Oryza , Gerenciamento de Resíduos , Poluição Ambiental , Micro-Ondas , Resíduos Sólidos
13.
Micromachines (Basel) ; 11(12)2020 Dec 06.
Artigo em Inglês | MEDLINE | ID: mdl-33291239

RESUMO

This work presents lightweight epoxy foams loaded with very low weight percentages (≤0.5 wt.%) of carbon fibers (CFs) with different lengths (3 mm, 6 mm, and 12 mm) as broadband microwave absorbing materials for anechoic chamber application. The effect of CF length on microwave absorption, especially on the absorption frequency band, is investigated for frequencies between 1 and 15 GHz. For the elaboration of composites, three different methods-spatula, shear mixing, and ultrasounds-are used for the dispersion of CFs. The observation of these CFs, after the dispersion step, shows a high fiber breakage rate when shear mixing is used, unlike when spatula or ultrasounds methods are used. On the other hand, the characterization of the elaborated composites highlights a correlation between the mixing methods, hence the fiber brakeage, and the measured reflection coefficient (reflection loss) of the composites. As a result, the minimum value of the reflection coefficient is shifted toward the high frequencies when the fiber breakage is observed, suggesting that short CFs absorb at high frequencies while long CFs absorb at low frequencies. Dielectric properties, extracted from the measurement in free space, of composites elaborated with different fiber lengths (3 mm, 6 mm, and 12 mm) confirm that short CFs (3 mm) show maximum losses at high frequencies (around 15 GHz) while long CFs (12 mm) show maximum dielectric losses at low frequencies (below 4 GHz). However, no significant variation is observed on the real part of the relative permittivity, as a function of fiber length, for these porous composites loaded with very low CF rates. A hybrid composite, with a mix of different CF lengths, is prepared and characterized. The simulation of the absorption performance of a pyramidal absorber, based on this hybrid composite, is compared to the one of pyramidal absorber based on composites loaded with a single length of carbon fibers. The pyramidal absorber-based hybrid composite predicts the best absorption performance, especially at the low frequency band. The simulated reflection coefficient of this absorber is less than -12 dB in all the studied frequency range, and less than -40 dB for frequencies higher than 3 GHz. This result confirms the interest of using a mix of carbon fiber lengths to achieve a broadband microwave absorber.

14.
ACS Appl Mater Interfaces ; 12(1): 1222-1231, 2020 Jan 08.
Artigo em Inglês | MEDLINE | ID: mdl-31805765

RESUMO

Microwave absorbing materials have attracted much attention in solving electromagnetic interference and pollution problems. Hierarchical cobalt selenides have been obtained through a facile selenization annealing process. The as-prepared samples exhibit distinct reflection losses (RL) and frequency responses via tailoring their crystalline configurations, with excellent absorption in Ku, X, or C band. All of the samples show RL greater than or near -50 dB with effective bandwidths more than 4 GHz, indicating that they may serve as high-efficient and frequency-tunable microwave absorbers. Especially, the sample annealed at 400 °C shows a competitive RL of -62.04 dB at 9.92 GHz with a thickness of 2.25 mm; meanwhile, its effective absorption bandwidth reaches 5.36 GHz with a thickness as small as 1.56 mm. The cobalt selenides as microwave absorbers exhibit a promising prospect applied in complex electromagnetic environments.

15.
Micromachines (Basel) ; 11(9)2020 Aug 26.
Artigo em Inglês | MEDLINE | ID: mdl-32858924

RESUMO

The current research reports the preparation of a microwave absorber containing CoFe2O4/NiFe2O4/Carbon fiber (H/S/CF) coated with polypyrrole polymer (PPy@H/S/CF) through sol-gel and in-situ polymerization processes. X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), vibrating sample magnetometer (VSM), and a vector network analyzer (VNA) are utilized to evaluate the features of the prepared composite. The microstructure analysis results revealed carbon fibers well decorated with submicron-size particles having hard/soft magnetic phases and thoroughly coated with polymer. The paraffin-based microwave absorber sample filled with 45 wt.% of PPy@H/S/CF has simultaneously both magnetic and dielectric losses in the 8.2-12.4 GHz frequency range. The absorber is used in a Salisbury screen configuration aiming at reducing the radar cross-section of objects. A minimum reflection loss of -55 dB at 10.6 GHz frequency with 5 GHz bandwidth is obtained for the sample with a 2 mm thickness. Different mechanisms, such as interfacial polarization, ferromagnetic resonance, and electron hopping, are the main factors for achieving such an appropriate microwave absorption. These results suggest that the PPy@H/S/CF composite is an ideal candidate for microwave absorption applications requiring high performance and low thickness.

16.
Materials (Basel) ; 11(1)2018 Jan 11.
Artigo em Inglês | MEDLINE | ID: mdl-29324686

RESUMO

Optically Transparent Microwave Metamaterial Absorber (OTMMA) is of significant use in both civil and military field. In this paper, equivalent circuit model is adopted as springboard to navigate the design of OTMMA. The physical model and absorption mechanisms of ideal lightweight ultrathin OTMMA are comprehensively researched. Both the theoretical value of equivalent resistance and the quantitative relation between the equivalent inductance and equivalent capacitance are derived for design. Frequency-dependent characteristics of theoretical equivalent resistance are also investigated. Based on these theoretical works, an effective and controllable design approach is proposed. To validate the approach, a wideband OTMMA is designed, fabricated, analyzed and tested. The results reveal that high absorption more than 90% can be achieved in the whole 6~18 GHz band. The fabricated OTMMA also has an optical transparency up to 78% at 600 nm and is much thinner and lighter than its counterparts.

17.
Materials (Basel) ; 11(10)2018 Oct 20.
Artigo em Inglês | MEDLINE | ID: mdl-30347784

RESUMO

In order to extend the performance of radar absorbing materials, it is necessary to design new structures with wideband properties and large angles of incidence which are also as thin as possible. The objective of this work, realized within the framework of the SAFAS project (self-complementary surface with low signature) is, then, the development of an ultra-wideband microwave absorber of low thickness. The design of such material requires a multilayered structure composed with dielectric layers, metasurfaces, and wide-angle impedance matching layers. This solution has been realized with on-the-shelf materials, and measured to validate the concept. At normal incidence, the bandwidth ratio, defined for a magnitude of the reflection coefficient below -10 dB, is 4.7:1 for an absorber with a total thickness of 11.5 mm, which corresponds to λ/7 at the lowest operating frequency. For an incidence of 60°, this bandwidth ratio is reduced to 3.8:1, but the device remains ultra-wideband.

18.
ACS Appl Mater Interfaces ; 9(49): 43072-43080, 2017 Dec 13.
Artigo em Inglês | MEDLINE | ID: mdl-29139298

RESUMO

Fiber alignment is a key factor that determines the physical properties of nanofiber mats. In this work, SiC nanofiber mats with or without fiber alignment are fabricated via electrospinning and the microwave electromagnetic properties of their silicone resin composites (5 wt %) are investigated in 2-18 GHz. By comparing with the composite containing SiC whisker, it is found that the nanofiber mats show superior dielectric loss and a minimal reflection loss (RL) of around -49 dB at 8.6 GHz and 4.3 mm thickness, associated with a broad effective absorption (<-10 dB) bandwidth (EAB) of about 7.2 GHz at 2.8 mm thickness. Moreover, the performance can be further enhanced (RL = -53 dB at 17.6 GHz and 2.3 mm thickness) by aligning the nanofiber in the plane of mat, accompanied by the shift of absorption peak to higher-frequency direction and broader EAB up to 8.6 GHz at 3 mm. In addition, the stacking ways of aligned SiC nanofiber mats (either parallel or perpendicular) are proved to have a negligible effect on their microwave properties. Compared with parallel stacking of the aligned mats, cross-stacking (perpendicular) only leads to a slight drop of the attenuation ability. It confirms that alignment of nanofiber in the mats offers a more effective approach to improve the microwave absorption properties than changing the ways of stacking. Furthermore, it is worth mentioning that the low loading fraction (5 wt %) is a great advantage to reduce the weight as well as the cost for large-scale production. All of these facts indicate that the aligned SiC nanofiber mats can serve as a great lightweight and broad-band microwave absorber.

19.
Environ Technol ; 37(24): 3139-45, 2016 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-27133358

RESUMO

The aim of this study is to explore catalytic microwave pyrolysis of crude oil storage tank sludge for fuels using granular activated carbon (GAC) as a catalyst. The effect of GAC loading on the yield of pyrolysis products was also investigated. Heating rate of oily sludge and yield of microwave pyrolysis products such as oil and fuel gas was found to depend on the ratio of GAC to oily sludge. The optimal GAC loading was found to be 10%, while much smaller and larger feed sizes adversely influenced production. During oily sludge pyrolysis, a maximum oil yield of 77.5% was achieved. Pyrolytic oils with high concentrations of diesel oil and gasoline (about 70 wt% in the pyrolytic oil) were obtained. The leaching of heavy metals, such as Cr, As and Pb, was also suppressed in the solid residue after pyrolysis. This technique provides advantages such as harmless treatment of oily sludge and substantial reduction in the consumption of energy, time and cost.


Assuntos
Carbono/química , Micro-Ondas , Esgotos/química , Catálise , Temperatura Alta , Metais Pesados/análise
20.
ACS Appl Mater Interfaces ; 7(47): 26226-34, 2015 Dec 02.
Artigo em Inglês | MEDLINE | ID: mdl-26575796

RESUMO

Electromagnetic wave absorbing materials that can exhibit effective absorption in a broad bandwidth at a thin thickness are strongly desired due to their widespread applications in electronic devices. In this study, hybrids of MoS2 and reduced graphene oxide (RGO) were prepared and their microwave absorption performance was investigated for the first time. It was found that a thin sample consisting of 10 wt % MoS2/RGO hybrid in the wax matrix exhibited an effective microwave absorption bandwidth of 5.72 GHz at the thickness less than 2.0 mm. The highest reflection loss of -50.9 dB was observed at 11.68 GHz for a sample with a thickness of 2.3 mm. Results obtained in this study indicate that hybrids of MoS2 and RGO are promising microwave absorbing materials, which can exhibit broad effective absorption bandwidth at low filler loading and thin thickness.

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