Plasma-Driven Tuning of Dielectric Permittivity in Graphene.

Materials with tunable negative electromagnetic performance, i.e., where dielectric permittivity becomes negative, have long been pursued in materials research due to their peculiar electromagnetic (EM) characteristics. Here, this promising feature is reported in materials on the case of plasma-synthesized nitrogen-doped graphene sheets with tunable permittivity over a wide (1-40 GHz) frequency range. Selectively incorporated nitrogen atoms in a graphene scaffold tailor the electronic structure in a way that provides an ultra-low energy (0.5-2 eV) 2D surface plasmon excitation, leading to subunitary and negative dielectric constant values in the Ka-band, from 30 up to 40 GHz. By allowing the tailoring of structures at atomic scale, this novel plasma-based approach creates a new paradigm for designing 2D nanomaterials like nanocarbons with controllable and tunable permittivity, opening a path to the next generation of 2D metamaterials.

Composition-Property Relations for GAx FAy MA1- x - y PbI3 Perovskites.

Halide perovskites are materials for diverse optoelectronic applications owing to a combination of factors, including their compositional flexibility. A major source of this diversity of compositions comes from the use of mixed organic cations in the A-site of such compounds to form solid solutions. Many organic cations are possible for this purpose. Although significant progress is made over years of intensive research, the determination of systematic relationships between the compositions and properties of halide perovskites is not exploited accordingly. Using the MAPbI3 prototype, a wide range of compositions substituted by formamidinium (FA+ ) and guanidinium (GA+ ) cations are studied. From a detailed collection of experimental data and results reported in the literature, heat maps correlating the composition of GAx FAy MA1- x - y PbI3 solid solutions with phase transition temperatures, dielectric permittivity, and activation energies are constructed. Considering the characteristics of organic cations, namely their sizes, dipole moments, and the number of N─H bonds, it is possible to interpret the heat maps as consequences of these characteristics. This work brings a systematization of how obtaining specific properties of halide perovskites might be possible by customizing the characteristics of the A-site organic cations.

Large improvement in RF magnetic fields and imaging SNR with whole-head high-permittivity slurry helmet for human-brain MRI applications at 7 T.

PURPOSE: To optimize the design and demonstrate the integration of a helmet-shaped container filled with a high-permittivity material (HPM) slurry with RF head coil arrays to improve RF coil sensitivity and SNR for human-brain proton MRI. METHODS: RF reception magnetic fields ( B 1 - $$ {\mathrm{B}}_1^{-} $$ ) of a 32-channel receive-only coil array with various geometries and permittivity values of HPM slurry helmet are calculated with electromagnetic simulation at 7 T. A 16-channel transmit-only coil array, a 32-channel receive-only coil array, and a 2-piece HPM slurry helmet were constructed and assembled. RF transmission magnetic field ( B 1 + $$ {\mathrm{B}}_1^{+} $$ ), B 1 - $$ {\mathrm{B}}_1^{-} $$ , and MRI SNR maps from the entire human brain were measured and compared. RESULTS: Simulations showed that averaged B 1 - $$ {\mathrm{B}}_1^{-} $$ improvement with the HPM slurry helmet increased from 57% to 87% as the relative permittivity (εr) of HPM slurry increased from 110 to 210. In vivo experiments showed that the average B 1 + $$ {\mathrm{B}}_1^{+} $$ improvement over the human brain was 14.5% with the two-piece HPM slurry (εr ≈ 170) helmet, and the average B 1 - $$ {\mathrm{B}}_1^{-} $$ and SNR were improved 63% and 34%, respectively, because the MRI noise level was increased by the lossy HPM. CONCLUSION: The RF coil sensitivity and MRI SNR were largely improved with the two-piece HPM slurry helmet demonstrated by both electromagnetic simulations and in vivo human head experiments at 7 T. The findings demonstrate that incorporating an easily producible HPM slurry helmet into the RF coil array significantly enhances human-brain MRI SNR homogeneity and quality at ultrahigh field. Greater SNR improvement is anticipated using the less lossy HPM and optimal design.

A review of recent developments and applications of high-permittivity dielectric shimming in magnetic resonance.

We present a review outlining the basic mechanism, background, recent technical developments, and clinical applications of aqueous dielectric padding in the field of MRI. Originally meant to be a temporary solution, it has gained traction as an effective method for correcting B1 + inhomogeneities due to the unique properties of the calcium titanate and barium titanate perovskites used. Aqueous dielectric pads have used a variety of high-permittivity materials over the years to improve the quality of MRI acquisitions at 1.5 and 3 T and more recently for 7 T neuroimaging applications. The technical development and assessment of these pads have been advanced by an increased use of mathematical modeling and electromagnetic simulations. These tools have allowed for a more complete understanding of the physical interactions between dielectric pads and the RF coil, making testing and safety assessments more accurate. The ease of use and effectiveness that dielectric pads offer have allowed them to become more commonplace in tackling imaging challenges in more clinically focused environments. More recently, they have seen usage not only in anatomical imaging methods but also in specialized metabolic imaging sequences such as GluCEST and NOEMTR . New colossally high-permittivity materials have been proposed; however, practical utilization has been a continued challenge due to unfavorable frequency dependences as well as safety limitations. A new class of metasurfaces has been under development to address the shortcomings of conventional dielectric padding while also providing increased performance in enhancing MRI images.

Fast high-resolution electric properties tomography using three-dimensional quantitative transient-state imaging-based water fraction estimation.

In this study, we aimed to develop a fast and robust high-resolution technique for clinically feasible electrical properties tomography based on water content maps (wEPT) using Quantitative Transient-state Imaging (QTI), a multiparametric transient state-based method that is similar to MR fingerprinting. Compared with the original wEPT implementation based on standard spin-echo acquisition, QTI provides robust electrical properties quantification towards B1 + inhomogeneities and full quantitative relaxometry data. To validate the proposed approach, 3D QTI data of 12 healthy volunteers were acquired on a 1.5 T scanner. QTI-provided T1 maps were used to compute water content maps of the tissues using an empirical relationship based on literature ex-vivo measurements. Assuming that electrical properties are modulated mainly by tissue water content, the water content maps were used to derive electrical conductivity and relative permittivity maps. The proposed technique was compared with a conventional phase-only Helmholtz EPT (HH-EPT) acquisition both within whole white matter, gray matter, and cerebrospinal fluid masks, and within different white and gray matter subregions. In addition, QTI-based wEPT was retrospectively applied to four multiple sclerosis adolescent and adult patients, compared with conventional contrast-weighted imaging in terms of lesion delineation, and quantitatively assessed by measuring the variation of electrical properties in lesions. Results obtained with the proposed approach agreed well with theoretical predictions and previous in vivo findings in both white and gray matter. The reconstructed maps showed greater anatomical detail and lower variability compared with standard phase-only HH-EPT. The technique can potentially improve delineation of pathology when compared with conventional contrast-weighted imaging and was able to detect significant variations in lesions with respect to normal-appearing tissues. In conclusion, QTI can reliably measure conductivity and relative permittivity of brain tissues within a short scan time, opening the way to the study of electric properties in clinical settings.

Enhancement of dielectric permittivity and Havriliak-Negami relaxation mechanism in MnFe2O4through Dy substitution.

Pristine and Dy substituted MnFe2O4,MnFe2-xDyxO4(x= 0.00, 0.02, 0.04, 0.06, 0.08 & 0.10) were successfully synthesized by sol-gel method to investigate the dielectric properties of the system. MnFe2O4exhibits a high dielectric permittivity of order 104which is further augmented by 60% through Dy substitution. This is owing to the rise in interfacial polarization resulting from localized states, dipolar polarization arising from the multiple valence states of Fe and Mn ions, atomic polarization due to structural distortion induced by strain, and electronic polarization stemming from the concentration of free charge carriers. The enhancement of induced strain, mixed valence ratio of Fe2+/Fe3+and Mn4+/Mn2+, localized states, and free charge carrier concentration are confirmed from the XRD, XPS, and optical studies, respectively. The dielectric relaxation mechanism of MnFe2-xDyxO4follows a modified Havriliak-Negami relaxation model with conductivity contribution. Complex impedance analyses further validate the contribution of grain-grain boundary mechanisms to the dielectric properties confirmed through Nyquist plots. A comprehensive analysis of conductivity reveals the significant impact of Dy substitution on the electrical conductivity of MnFe2O4. This influence is strongly related to the variations in the concentration of free charge carriers within the MnFe2-xDyxO4system. The understanding of the underlying physics governing the dielectric properties of Dy-substituted MnFe2O4not only enhances the fundamental knowledge of material behavior but also opens new avenues for the design and optimization of advanced electronic and communication devices.

Dielectrophoretic characterization of peroxidized retinal pigment epithelial cells as a model of age-related macular degeneration.

BACKGROUND: Age-related macular degeneration (AMD) is a prevalent ocular pathology affecting mostly the elderly population. AMD is characterized by a progressive retinal pigment epithelial (RPE) cell degeneration, mainly caused by an impaired antioxidative defense. One of the AMD therapeutic procedures involves injecting healthy RPE cells into the subretinal space, necessitating pure, healthy RPE cell suspensions. This study aims to electrically characterize RPE cells to demonstrate a possibility using simulations to separate healthy RPE cells from a mixture of healthy/oxidized cells by dielectrophoresis. METHODS: BPEI-1 rat RPE cells were exposed to hydrogen peroxide to create an in-vitro AMD cellular model. Cell viability was evaluated using various methods, including microscopic imaging, impedance-based real-time cell analysis, and the MTS assay. Healthy and oxidized cells were characterized by recording their dielectrophoretic spectra, and electric cell parameters (crossover frequency, membrane conductivity and permittivity, and cytoplasm conductivity) were computed. A COMSOL simulation was performed on a theoretical microfluidic-based dielectrophoretic separation chip using these parameters. RESULTS: Increasing the hydrogen peroxide concentration shifted the first crossover frequency toward lower values, and the cell membrane permittivity progressively increased. These changes were attributed to progressive membrane peroxidation, as they were diminished when measured on cells treated with the antioxidant N-acetylcysteine. The changes in the crossover frequency were sufficient for the efficient separation of healthy cells, as demonstrated by simulations. CONCLUSIONS: The study demonstrates that dielectrophoresis can be used to separate healthy RPE cells from oxidized ones based on their electrical properties. This method could be a viable approach for obtaining pure, healthy RPE cell suspensions for AMD therapeutic procedures.

Measuring Sedimentation Profiles for Nanoparticle Characterization through a Square Spiral Resonator Sensor.

Metallic nanoscale particles attract a growing interest in several fields, thanks to their unique bonding characteristics; applications are appearing in the literature in the fields of, for example, sensor coatings and biochemical compound detection. However, the controlled fabrication of such nanopowders is often cumbersome, especially because their characterization is normally slow, involving procedures such as electron microscopy. On the other hand, microwave sensors based on near-field effects on materials are being developed with high sensitivity and show promising characteristics. In this paper, the authors show how a microwave sensor based on a Square Spiral Resonator can be used to characterize paraffin dispersions of nanoparticles conveniently and cost-effectively.

An Adaptation of the Split-Cylinder Resonator Method for Measuring the Microwave Properties of Thin Ferroelectric Films in a "Thin Film-Substrate" Structure.

The split-cylinder resonator method was adapted to measure the microwave properties (dielectric permittivity and loss tangent) of thin ferroelectric films on a dielectric substrate. The mathematical model for calculating the resonance frequency of the split-cylinder resonator was adjusted for the "ferroelectric film-substrate" structure. An approach for correcting the gap effect based on calibrating with a single-layer dielectric was introduced and used to study two-layer dielectrics. The prototype of a split-cylinder resonator designed to measure single-layer dielectric plates at a frequency of 10 GHz was presented. The resonator calibration was performed using dielectric PTFE samples and fused silica, and an example of the correction function was suggested. The measurement error was estimated, and recommendations on the acceptable parameter range for the material under investigation were provided. The method was demonstrated to measure the microwave properties of a ferroelectric film on a fused silica substrate.

A Method for Sensing Dielectric Properties of Thin and Flexible Conductive Biocomposites.

This study investigates the dielectric properties of conductive biocomposites (CBs), which are integral to the development of advanced materials for flexible electronics and medical devices. A novel method employing Microwave Reflectometry (MR) is introduced, utilizing a miniaturized Vector Network Analyzer (m-VNA) and a dedicated sensing element (SE), to extract the dielectric properties of CBs. The method is grounded in a minimization principle, aligning the measured S11 reflection scattering parameter with its electromagnetic (EM) simulation, facilitating a refined process for determining the dielectric properties. The experimental setup was meticulously engineered, optimized, and validated using reference dielectric samples (RDSs) with known dielectric properties. The method was then applied to three innovative CBs, resulting in an accurate extrapolation of their dielectric properties. The findings highlight the method's versatility, cost-efficiency, and applicability to ultra-thin and flexible biopolymer films, offering significant potential for advancements in flexible electronics and bio-sensing applications.

Design and Performance Analysis of Compact Printed Ridge Gap Waveguide Phase Shifters for Millimeter-Wave Systems.

This paper introduces compact Printed Ridge Gap Waveguide (PRGW) phase shifters tailored for millimeter-wave applications, with a focus on achieving wide operating bandwidth, and improved matching and phase balance compared to single-layer technology. This study proposes a unique approach to achieve the required phase shift in PRGW technology, which has not been previously explored. This study also introduces a novel analytical approach to calculate the cutoff frequency and propagation constant of the PRGW structure, a method not previously addressed. Furthermore, the utilization of multi-layer PRGW technology enables the realization of multi-layer beamforming networks without crossing, thereby supporting wideband operation in a compact size. The proposed design procedure enables the realization of various phase shift values ranging from 0∘ to 135∘ over a broad frequency bandwidth centered at 30 GHz. A 45-degree phase shifter is fabricated and tested, demonstrating a 10 GHz bandwidth (approximately 33% fractional bandwidth) from 25 GHz to 35 GHz. Throughout the operating bandwidth, the phase balance remains within 45 ± 5∘, with a deep matching level of -20 dB. The proposed phase shifter exhibits desirable characteristics, such as compactness, low loss, and low dispersion, making it a suitable choice for millimeter-wave applications, including beyond 5G (B5G) and 6G wireless communications.

High-Sensitivity Differential Sensor for Characterizing Complex Permittivity of Liquids Based on LC Resonators.

This paper proposes a high-sensitivity microstrip differential sensor for measuring the complex permittivity of liquids. The prototype of the differential sensor was formed by cascading two LC resonators on a microstrip transmission line based on stepped impedance. A strong electric field was found to be distributed in the circular patch of the LC resonator; therefore, a cylindrical micropore was set in the center of the circular LC resonator to measure the dielectric sample, which maximized the disturbance of the dielectric sample on the sensor. By optimizing the size of the circular LC resonator, a high-sensitivity sensor circuit was designed and manufactured. The complex permittivity of the test sample was calculated by measuring the transmission coefficient of different molar concentrations of ethanol-water solutions. The experimental results show that the designed differential sensor can accurately measure the complex permittivity of liquid materials with an average sensitivity of 0.76%.

A Review of Microstrip Patch Antenna-Based Passive Sensors.

This paper briefly overviews and discusses the existing techniques using antennas for passive sensing, starting from the antenna operating principle and antenna structural design to different antenna-based sensing mechanisms. The effects of different electrical properties of the material used to design an antenna, such as conductivity, loss tangent, and resistivity, are discussed to illustrate the fundamental sensing mechanisms. Furthermore, the key parameters, such as operating frequency and antenna impedance, along with the factors affecting the sensing performance, are discussed. Overall, passive sensing using an antenna is mainly achieved by altering the reflected wave characteristics in terms of center frequency, return loss, phase, and received/reflected signal strength. The advantages and drawbacks of each technique are also discussed briefly. Given the increasing relevance, millimeter-wave antenna sensors and resonator sensors are also discussed with their applications and recent advancements. This paper primarily focuses on microstrip-based radiating structures and insights for further sensing performance improvement using passive antennas, which are outlined in this study. In addition, suggestions are made for the current scientific and technical challenges, and future directions are discussed.

Temperature-Corrected Calibration of GS3 and TEROS-12 Soil Water Content Sensors.

The continuous monitoring of soil water content is commonly carried out using low-frequency capacitance sensors that require a site-specific calibration to relate sensor readings to apparent dielectric bulk permittivity (Kb) and soil water content (θ). In fine-textured soils, the conversion of Kb to θ is still challenging due to temperature effects on the bound water fraction associated with clay mineral surfaces, which is disregarded in factory calibrations. Here, a multi-point calibration approach accounts for temperature effects on two soils with medium to high clay content. A calibration strategy was developed using repacked soil samples in which the Kb-θ relationship was determined for temperature (T) steps from 10 to 40 °C. This approach was tested using the GS3 and TEROS-12 sensors (METER Group, Inc. Pullman, WA, USA; formerly Decagon Devices). Kb is influenced by T in both soils with contrasting T-Kb relationships. The measured data were fitted using a linear function θ = aKb + b with temperature-dependent coefficients a and b. The slope, a(T), and intercept, b(T), of the loam soil were different from the ones of the clay soil. The consideration of a temperature correction resulted in low RMSE values, ranging from 0.007 to 0.033 cm3 cm-3, which were lower than the RMSE values obtained from factory calibration (0.046 to 0.11 cm3 cm-3). However, each experiment was replicated only twice using two different sensors. Sensor-to-sensor variability effects were thus ignored in this study and will be systematically investigated in a future study. Finally, the applicability of the proposed calibration method was tested at two experimental sites. The spatial-average θ from a network of GS3 sensors based on the new calibration fairly agreed with the independent area-wide θ from the Cosmic Ray Neutron Sensor (CRNS). This study provided a temperature-corrected calibration to increase the accuracy of commercial sensors, especially under dry conditions, at two experimental sites.

Response of the TEROS 12 Soil Moisture Sensor under Different Soils and Variable Electrical Conductivity.

In this work, the performance of the TEROS 12 electromagnetic sensor, which measures volumetric soil water content (θ), bulk soil electrical conductivity (σb), and temperature, is examined for a number of different soils, different θ and different levels of the electrical conductivity of the soil solution (ECW) under laboratory conditions. For the above reason, a prototype device was developed including a low-cost microcontroller and suitable adaptation circuits for the aforementioned sensor. Six characteristic porous media were examined in a θ range from air drying to saturation, while four different solutions of increasing Electrical Conductivity (ECw) from 0.28 dS/m to approximately 10 dS/m were used in four of these porous media. It was found that TEROS 12 apparent dielectric permittivity (εa) readings were lower than that of Topp's permittivity-water content relationship, especially at higher soil water content values in the coarse porous bodies. The differences are observed in sand (S), sandy loam (SL) and loam (L), at this order. The results suggested that the relationship between experimentally measured soil water content (θm) and εa0.5 was strongly linear (0.869 < R2 < 0.989), but the linearity of the relation θm-εa0.5 decreases with the increase in bulk EC (σb) of the soil. The most accurate results were provided by the multipoint calibration method (CAL), as evaluated with the root mean square error (RMSE). Also, it was found that εa degrades substantially at values of σb less than 2.5 dS/m while εa returns to near 80 at higher values. Regarding the relation εa-σb, it seems that it is strongly linear and that its slope depends on the pore water electrical conductivity (σp) and the soil type.

Electric Susceptibility at Partial Coverage of a Circular One-Side Access Capacitive Sensor with Rigid Polyurethane Foams.

The capability of dielectric measurements was significantly increased with the development of capacitive one-side access physical sensors. Complete samples give no opportunity to study electric susceptibility at a partial coverage of the one-side access sensor's active area; therefore, partial samples are proposed. The electric susceptibility at the partial coverage of a circular one-side access sensor with cylinders and shells is investigated for polyurethane materials. The implementation of the relative partial susceptibility permitted us to transform the calculated susceptibility data to a common scale of 0.0-1.0 and to outline the main trends for PU materials. The partial susceptibility, relative partial susceptibility, and change rate of relative partial susceptibility exhibited dependence on the coverage coefficient of the sensor's active area. The overall character of the curves for the change rate of the relative partial susceptibility, characterised by slopes of lines and the ratio of the change rate in the centre and near the gap, corresponds with the character of the surface charge density distribution curves, calculated from mathematical models. The elaborated methods may be useful in the design and optimization of capacitive OSA sensors of other configurations of electrodes, independent of the particular technical solution.

The Effects of Mechanical Loading on Resonant Response of a Conformal Load-Bearing Antenna System.

Glass fibre-reinforced polymer (GFRP) is a suitable substrate material for constructing a Conformal Load-Bearing Antenna Structure (CLAS). The relative permittivity of the CLAS substrate, which determines its resonant frequency, is affected by damage sustained by GFRP. This paper investigates the effects of damage (induced by mechanically loading the substrate) on the resonant response of the CLAS. Decoupling the antenna from the substrate was essential to evaluate the CLAS's true response to the induced damage. This paper details a systematic investigation examining how the frequency response of a "pristine" antenna and a surface-mounted antenna respond to a substrate subjected to quasi-statically induced mechanical damage and cyclic fatigue loading. The results demonstrate that the resonant frequency of the CLAS varies as a function of the substrate's mechanical damage. The prepared CLAS is tolerant to a certain degree of mechanical loading and related damage with its resonant frequency remaining within an acceptable bandwidth.

Dual-Frequency Soil Moisture Meter Method for Simultaneous Estimation of Soil Moisture and Conductivity.

The measurement of soil water content is a very important factor in plant cultivation, both from an economic and ecological point of view. Proper estimation of moisture content not only allows for proper yields but can also contribute to ecologically appropriate use of fresh water, of which the world's resources are limited. It is important, for example, that the moisture content in the root area of plants is optimal for their growth, while over-watering can result in losses in the form of water, which seeps below the root layer and is lost. The novel, inexpensive electronic meter for measuring soil moisture is presented in the article. The meter, based on a capacitive method, uses an optimization algorithm to calculate soil electrical permeability and a simplified new formula between soil electrical permeability and volumetric moisture content. Moreover, by using two high-frequency signals for measurements, it is possible not only to estimate moisture content but also soil conductivity. Both readings obtained from the meter not only allow for rational management of crop optimization for economic reasons but are also important for environmental protection. In addition, the inexpensive meter, based on the principle of operation presented, can be made as an IoT module, which allows for its wide application.

Permittivity-Asymmetric Quasi-Bound States in the Continuum.

Breaking the in-plane geometric symmetry of dielectric metasurfaces allows us to access a set of electromagnetic states termed symmetry-protected quasi-bound states in the continuum (qBICs). Here we demonstrate that qBICs can also be accessed by a symmetry breaking in the permittivity of the comprising materials. While the physical size of atoms imposes a limit on the lowest achievable geometrical asymmetry, weak permittivity modulations due to carrier doping, and electro-optical Pockels and Kerr effects, usually considered insignificant, open the possibility of infinitesimal permittivity asymmetries for on-demand, dynamically tunable resonances of extremely high quality factors. As a proof-of-principle, we probe the excitation of permittivity-asymmetric qBICs (ε-qBICs) using a prototype Si/TiO2 metasurface, in which the asymmetry in the unit cell is provided by the permittivity contrast of the materials. ε-qBICs are also numerically demonstrated in 1D gratings, where quality-factor enhancement and tailored interference phenomena of qBICs are shown via the interplay of geometrical and permittivity asymmetries.

Percolation-Triggered Negative Permittivity in Nano Carbon Powder/Polyvinylidene Fluoride Composites.

Percolating composites exhibiting negative permittivity have garnered considerable attention due to their promising applications in the realm of electromagnetic shielding, innovative capacitance devices, coil-less inductors, etc. Nano carbon powder/polyvinylidene fluoride (CP/PVDF) percolating composites were fabricated that exhibit Drude-type negative-permittivity behavior upon reaching the CP percolation threshold. This phenomenon is attributed to the formation of a plasmonic state within the interconnected CP network, enabling the delocalization of electrons under the alternating electric field. Furthermore, a significant (nearly two orders of magnitude) increase in the conductivity of sample is observed at a CP content of 12.5 wt%. This abrupt change coincides with the percolation phenomenon, suggesting a transition in the conduction mechanism. To elucidate this behavior, comprehensive analyses of the phase composition, microstructure, AC conductivity, and relative permittivity were performed. Additionally, the sample containing 5 wt% CP exhibits a remarkably high permittivity of 31.5, accompanied by a relatively low dielectric loss (tanδ < 0.2). The findings expand the potential applications of PVDF, while the fabricated percolating composites hold promise for electromagnetic shielding, antennas, and other electromagnetic devices.