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The intrusive bodies in the study area are categorized into two intrusive units, γπK2 and ηoπK2, based on rock structure characteristics and intrusive contact relationships. The primary lithologies are granite porphyry and quartz monzonite porphyry. Through LA-ICP-MS zircon U-Pb dating, the weighted mean ages of zircon ^206Pb/^238U for these two units were determined to be 84.09 ± 0.86 Ma and 86.10 ± 0.76 Ma, respectively. According to geochemical characteristics and Sr-Yb granite classification, the quartz monzonite porphyry is classified as Zhejiang-Fujian type granite, and the granite porphyry as Nanling type granite. The study explores the geodynamic significance of granites in the area based on Sr-Yb granite classification, identifying the lower crust metamorphic facies as amphibolite facies. The source rocks are primarily basic granulites and felsic granulites, reflecting a thermally active lower crust with poorly developed fluids. Additionally, Sr-Yb granite classification aids in determining the crustal thickness of the lower crust, which is crucial for understanding continental geological evolution. This paper discusses the optimal locations and conditions for mineralizing fluid precipitation, noting that tungsten-tin mineralization is associated with Nanling type granites and that the mineralization process generally occurs later than the diagenetic process under conditions of low pressure and low oxygen fugacity. Tungsten-tin prospecting should focus on areas where the surrounding rock temperature ranges from 300 to 500 °C, with particular attention to the contact zones of sedimentary rocks or near structural fault zones.
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Groundwater is an essential freshwater resource utilized in industry, agriculture, and daily life. In the Huaibei Plain (HBP), where groundwater significantly influences socio-economic development, information about its quality, hydrochemistry, and related health risks remains limited. We conducted a comprehensive groundwater sampling in the HBP and examined its rock characteristics, water quality index (WQI), and potential health risks. The results revealed that the primary factors shaping groundwater hydrochemistry were rock dissolution and weathering, cation exchange, and anthropogenic activities. WQI assessment indicated that only 73% of the groundwaters is potable, as Fe2+, Mn2+, NO3-, and F- contents in the water could pose non-carcinogenic hazards to humans. Children were more susceptible to these health risks through oral ingestion than adults. Uncertainty analysis indicated that the probabilities of non-carcinogenic risk were approximately 57% and 31% for children and adults, respectively. Sensitivity analysis further identified fluoride as the primary factor influencing non-carcinogenic risks, indicating that reducing fluoride contamination should be prioritized in future groundwater management in the HBP.
Assuntos
Água Subterrânea , Poluentes Químicos da Água , Criança , Adulto , Humanos , Monitoramento Ambiental/métodos , Fluoretos/análise , Poluentes Químicos da Água/análise , Qualidade da Água , Água Subterrânea/química , China , Medição de RiscoRESUMO
The water quality of mine water is obviously improved after being stored in underground reservoir, but the process of water-rock interaction and the purification mechanism of mine water quality are not clear. In this study, the water samples and rock samples collected in the underground reservoir of Daliuta coal mine were taken as the research object. Based on the analysis of the hydrochemical characteristics of the reservoir water samples and the characterization of the rock samples, combined with PHREEQC analysis, the mechanism of water quality purification of mine water was discussed. The results showed that the rocks in the underground reservoir had layered silicate structure and flaky kaolinite structure, with some irregular edges and microcracks, and higher specific surface area and total pore volume. These characteristics made the rocks have a certain adsorption and removal capacity for heavy metal ions and other pollutants in the mine water. The water-rock interaction, such as the dissolution of albite and halite, the precipitation of gypsum and kaolinite, and the cation exchange, resulted in the increase of the concentration of Na+ and the decrease of the concentration of Ca2+, Mg2+, and TDS in the outlet water, and the hydrochemical type changed from SO42--Cl-/Ca2+ type to SO42--Cl-/Na+ type. Moreover, this study shows that PHREEQC analysis can be used to analyze the water-rock interaction of coal mine underground reservoir and can obtain more detailed information; therefore, it may have the potential ability to help assess the migration and transformation of pollutants during the storage process of mine water in underground reservoirs.
Assuntos
Poluentes Ambientais , Poluentes Químicos da Água , China , Carvão Mineral/análise , Monitoramento Ambiental , Poluentes Ambientais/análise , Caulim , Poluentes Químicos da Água/análise , Qualidade da ÁguaRESUMO
Mobile intertidal gastropods can employ behavioural thermoregulation to mitigate thermal stress, which may include retreating under boulders when emersed. However, little is known about how gastropod occupancy of under-boulder habitats is associated with any variations in substrate temperature that exist under boulders. Thermal imagery was used to measure the temperature of boulder lower surfaces and investigate how three snail species were associated at low tide with the maximum and average temperatures underneath grey siltstone and quartzite. Lower boulder surfaces had heterogeneous temperatures, with grey siltstone having temperature gradients and quartzite temperature showing mosaics. Temperature differences between the hottest and coolest gradient or mosaic locations were >5 °C; thus there was a range of temperatures that snails could interact with. All three snail species occupied cooler parts of temperature mosaics or gradients, avoiding the hottest areas. Stronger associations were detected on the hotter grey siltstone and for the more-thermally sensitive Nerita atramentosa and Diloma concameratum. Even though snails were associated with cooler areas, some individuals were still exposed to extreme substratum heat (>50 °C). These results suggest that gastropod thermoregulatory behaviour is far more complex than simply retreating underneath boulders at low tide, as there is also a range of under-boulder temperatures that they interact with. Untangling interactions between intertidal gastropods and heterogenous substrate temperatures is important given rocky seashores already represent a thermally-variable and potentially-stressful habitat, which may be exacerbated further given predictions of warming temperatures associated with climate change.
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BACKGROUND: This study aimed to assess the whole-body vibration (WBV) exposure among large blast hole drill machine operators with regard to the International Organization for Standardization (ISO) recommended threshold values and its association with machine- and rock-related factors and workers' individual characteristics. METHODS: The study population included 28 drill machine operators who had worked in four opencast iron ore mines in eastern India. The study protocol comprised the following: measurements of WBV exposure [frequency weighted root mean square (RMS) acceleration (m/s(2))], machine-related data (manufacturer of machine, age of machine, seat height, thickness, and rest height) collected from mine management offices, measurements of rock hardness, uniaxial compressive strength and density, and workers' characteristics via face-to-face interviews. RESULTS: More than 90% of the operators were exposed to a higher level WBV than the ISO upper limit and only 3.6% between the lower and upper limits, mainly in the vertical axis. Bivariate correlations revealed that potential predictors of total WBV exposure were: machine manufacturer (r = 0.453, p = 0.015), age of drill (r = 0.533, p = 0.003), and hardness of rock (r = 0.561, p = 0.002). The stepwise multiple regression model revealed that the potential predictors are age of operator (regression coefficient ß = -0.052, standard error SE = 0.023), manufacturer (ß = 1.093, SE = 0.227), rock hardness (ß = 0.045, SE = 0.018), uniaxial compressive strength (ß = 0.027, SE = 0.009), and density (ß = -1.135, SE = 0.235). CONCLUSION: Prevention should include using appropriate machines to handle rock hardness, rock uniaxial compressive strength and density, and seat improvement using ergonomic approaches such as including a suspension system.
RESUMO
BACKGROUND: This study aimed to assess the whole-body vibration (WBV) exposure among large blast hole drill machine operators with regard to the International Organization for Standardization (ISO) recommended threshold values and its association with machine- and rock-related factors and workers' individual characteristics. METHODS: The study population included 28 drill machine operators who had worked in four opencast iron ore mines in eastern India. The study protocol comprised the following: measurements of WBV exposure [frequency weighted root mean square (RMS) acceleration (m/s2)], machine-related data (manufacturer of machine, age of machine, seat height, thickness, and rest height) collected from mine management offices, measurements of rock hardness, uniaxial compressive strength and density, and workers' characteristics via face-to-face interviews. RESULTS: More than 90% of the operators were exposed to a higher level WBV than the ISO upper limit and only 3.6% between the lower and upper limits, mainly in the vertical axis. Bivariate correlations revealed that potential predictors of total WBV exposure were: machine manufacturer (r = 0.453, p = 0.015), age of drill (r = 0.533, p = 0.003), and hardness of rock (r = 0.561, p = 0.002). The stepwise multiple regression model revealed that the potential predictors are age of operator (regression coefficient beta = -0.052, standard error SE = 0.023), manufacturer (beta = 1.093, SE = 0.227), rock hardness (beta = 0.045, SE = 0.018), uniaxial compressive strength (beta = 0.027, SE = 0.009), and density (beta = e1.135, SE = 0.235). CONCLUSION: Prevention should include using appropriate machines to handle rock hardness, rock uniaxial compressive strength and density, and seat improvement using ergonomic approaches such as including a suspension system.