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1.
Sensors (Basel) ; 24(12)2024 Jun 17.
Artigo em Inglês | MEDLINE | ID: mdl-38931697

RESUMO

Integrated thin film-based shape memory polyimide composites (SMPICs) are potentially attractive for efficient and compact design, thereby offering cost-effective applications. The objective of this article is to design and evaluate a mirror manipulator using an SMPIC as an actuator and a sensor with control. A sensor-less control strategy using the SMPIC (a self-sensing actuator) with a proportional derivative combined variable structure controller (PD-VSC) is proposed for position control of the mirror in both the vertical and angular directions. The mirror manipulator is able to move the mirror in the vertical and angular directions by 3.39 mm and 10.5 deg, respectively. A desired fast response is obtained as the performance under control. In addition, some benefits from the proposed control realization include good tracking, stable switching, no overshoot, no steady state oscillations, and robust disturbance rejection. These superior properties are experimentally validated to reflect practical feasibility.

2.
Sensors (Basel) ; 24(11)2024 May 28.
Artigo em Inglês | MEDLINE | ID: mdl-38894266

RESUMO

This paper describes the design, fabrication, integration, characterization, and demonstration of a novel flexible double-sided curvature sensor array for use in soft robotics. The paper explores the performance and potential applications of a piezoresistive sensor array consisting of four gold strain gauges on a flexible polyimide (PI) substrate arranged in a Wheatstone bridge configuration. Multiple sensor strips were arranged like the fingers of a hand. Integrating Shape Memory Alloy (SMA) foils alongside the fingers was explored to mimic a human hand-gripping motion controlled with temperature, while curvature sensor array strips measure the resulting finger shapes. Moreover, object sensing in a flexible granular material gripper was demonstrated. The sensors were embedded within Polydimethylsiloxane (PDMS) to enhance their tactile feel and adhesive properties. The findings of this study are promising for future applications, particularly in robotics and prosthetics, as the ability to accurately mimic human hand movements and reconstruct sensor surfaces paves the way for robotic hand functionality.

3.
Sheng Wu Yi Xue Gong Cheng Xue Za Zhi ; 41(4): 766-774, 2024 Aug 25.
Artigo em Chinês | MEDLINE | ID: mdl-39218603

RESUMO

The locking mechanism between bracket and shape memory alloy (SMA) archwire in the newly developed domestic orthodontic device is the key to controlling the precise alignment of the teeth. To meet the demand of locking force in clinical treatment, the tightening torque angle of the locking bolt and the required torque magnitude need to be precisely designed. For this purpose, a design study of the locking mechanism is carried out to analyze the correspondence between the tightening torque angle and the locking force and to determine the effective torque value, which involves complex coupling of contact, material and geometric nonlinear characteristics. Firstly, a simulation analysis based on parametric orthogonal experimental design is carried out to determine the SMA hyperelastic material parameters for the experimental data of SMA archwire with three-point bending. Secondly, a two-stage fine finite-element simulation model for bolt tightening and archwire pulling is established, and the nonlinear analysis is converged through the optimization of key contact parameters. Finally, multiple sets of calibration experiments are carried out for three tightening torsion angles. The comparison results between the design analysis and the calibration experiments show that the deviation between the design analysis and the calibration mean value of the locking force in each case is within 10%, and the design analysis method is valid and reliable. The final tightening torque angle for clinical application is determined to be 10° and the rated torque is 2.8 N∙mm. The key data obtained can be used in the design of clinical protocols and subsequent mechanical optimization of novel orthodontic devices, and the research methodology can provide a valuable reference for force analysis of medical devices containing SMA materials.


Assuntos
Análise de Elementos Finitos , Fios Ortodônticos , Torque , Ligas de Memória da Forma , Humanos , Braquetes Ortodônticos , Desenho de Aparelho Ortodôntico , Estresse Mecânico , Teste de Materiais , Simulação por Computador , Análise do Estresse Dentário
4.
Small ; 19(8): e2206269, 2023 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-36504286

RESUMO

In this paper, a quaternary dielectric soft-contact rotary triboelectric nanogenerator (QDSR-TENG) of low frictional resistance is fabricated for combining TENG with a shape memory alloy (SMA) engine. The introduction of rabbit fur brush and FEP brush results in charge pumps with a partially soft contact structure. Benefiting from the low friction loss of the structure, the QDSR-TENG can operate stably and continually for 100k cycles without significant output degradation. The SMA engine exhibits thermally induced phase transformation and super-elasticity and can be utilized for harnessing waste heat energy. The thermal-driven QDSR-TENG can operate with a water source of 43 °C with a distinguishable response to the variation of temperatures. Such a low starting temperature not only promotes the harvesting of low-grade thermal energy, but also results in a self-monitoring industrial cooling water system. The coupled elastocaloric power and cooling cycle proposed in the thermal-driven QDSR-TENG opens a new paradigm for the application in energy harvesting and smart sensing.

5.
Artif Organs ; 47(8): 1285-1297, 2023 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-36869693

RESUMO

BACKGROUND: Existing artificial anal sphincter studies have shown that biomechanical compatibility problem between artificial anal sphincter and rectum caused by long-term morphological changes of the tissue surrounding the implanted prosthesis can lead to device failure or tissue ischemic necrosis. In this article, a mechanical artificial anal sphincter with constant force clamping is designed based on the superelasticity of shape memory alloys, which improved the biomechanical compatibility of implantable artificial anal sphincter. METHODS: Firstly, the anatomical structure and the biomechanical properties of the rectum are analyzed to obtain the size parameters and material parameters of the rectal model. Secondly, a novel artificial anal sphincter with constant force is designed to improve the biomechanical compatibility between the artificial sphincter and the rectum. Thirdly, the static analysis of artificial anal sphincter is carried out by finite element analysis. RESULTS: The simulation results show that the artificial anal sphincter can maintain a constant clamping force of 4 N within a certain variation range of intestinal tissue thickness, which verifies the constant force characteristic of the artificial anal sphincter. The constant clamping force of the artificial anal sphincter to the rectum is 4 N that is greater than the clamping force 3.99 N required to close the rectum, which verifies the effectiveness the artificial anal sphincter. The surface contact stress and the minimum principal stress of the rectum in the clamping state are less than the pressure threshold, which verifies the safety of the artificial anal sphincter. CONCLUSIONS: The novel artificial anal sphincter has better biomechanical compatibility and improves the mechanical match between artificial sphincter and intestinal tissue. This study may provide more reasonable and effective simulation data for in vivo experiments of artificial anal sphincter in future, which may provide theoretical and technical support for further research about clinical application of artificial anal sphincter.


Assuntos
Incontinência Fecal , Esfíncter Urinário Artificial , Humanos , Canal Anal/cirurgia , Reto , Próteses e Implantes
6.
Sensors (Basel) ; 23(8)2023 Apr 13.
Artigo em Inglês | MEDLINE | ID: mdl-37112312

RESUMO

Pollutants in exhaust gases and the high fuel consumption of internal combustion engines remain key issues in the automotive industry despite the emergence of electric vehicles. Engine overheating is a major cause of these problems. Traditionally, engine overheating was solved using electric pumps and cooling fans with electrically operated thermostats. This method can be applied using active cooling systems that are currently available on the market. However, the performance of this method is undermined by its delayed response time to activate the main valve of the thermostat and the dependence of the coolant flow direction control on the engine. This study proposes a novel active engine cooling system incorporating a shape memory alloy-based thermostat. After discussing the operating principles, the governing equations of motion were formulated and analyzed using COMSOL Multiphysics and MATLAB. The results show that the proposed method improved the response time required to change the coolant flow direction and led to a coolant temperature difference of 4.90 °C at 90 °C cooling conditions. This result indicates that the proposed system can be applied to existing internal combustion engines to enhance their performance in terms of reduced pollution and fuel consumption.

7.
Sensors (Basel) ; 23(4)2023 Feb 12.
Artigo em Inglês | MEDLINE | ID: mdl-36850673

RESUMO

Force sensors are used in a wide variety of fields. They require different measurement ranges and sensitivities depending on the operating environment because there is generally a trade-off between measurement range and sensitivity. In this study, we developed a variable-sensitivity, variable-measurement-range force sensor that utilizes structural modification, namely changes in the distance between the force application point and the detection area, and changes in the cross-sectional area. The use of shape-memory materials allows the sensor structure to be easily changed and fixed by controlling the temperature. First, we describe the theory of the proposed sensor. Then, we present prototypes and the experimental methods used to verify the performance of the sensor. We fabricated the prototypes by attaching two strain gauges to two sides of a shape-memory alloy and shape-memory polymer plates. Experiments on the prototypes show that the relationship between the applied force and the detected strain can be changed by bending the plate. This allows the sensitivity and measurement range of the sensor to be changed.

8.
Sensors (Basel) ; 23(4)2023 Feb 14.
Artigo em Inglês | MEDLINE | ID: mdl-36850745

RESUMO

As the use of drones grows, so too does the demand for physical protection against drone damage resulting from collisions and falls. In addition, as the flight environment becomes more complicated, a shock absorption system is required, in which the protective structure can be deformed based on the circumstances. Here, we present an origami- and kirigami-based structure that provides protection from various directions. This research adds a deformation capacity to existing fixed-shape guards; by using shape memory alloys, the diameter and height of the protective structure are controlled. We present three protective modes (1: large diameter/low height; 2: small diameter/large height; and 3: lotus shaped) that mitigate drone falls and side collisions. From the result of the drop impact test, mode 2 showed a 78.2% reduction in the maximum impact force at side impact. We incorporated kirigami patterns into the origami structures in order to investigate the aerodynamic effects of the hollow patterns. Airflow experiments yielded a macro understanding of flow-through behaviors on each kirigami pattern. In the wind speed experiment, the change in airflow velocity induced by the penetration of the kirigami pattern was measured, and in the force measurement experiment, the air force applied to the structure was determined.

9.
Sensors (Basel) ; 23(3)2023 Jan 19.
Artigo em Inglês | MEDLINE | ID: mdl-36772191

RESUMO

The modern industrial and consumer applications in accordance with the concepts of Industry 4.0 and the Internet of Things are characterized by autonomy and self-sufficiency. This has led to an increase in the interest for the so-called smart materials, capable of combining the functionalities of sensors, actuators and, in some applications, control systems. An important group of smart materials are shape-memory alloys, among which nickel-titanium (NiTi) alloys are the most known. In this article, the influence of phase transformation on the mechanical properties of thin NiTi alloy wires was investigated. During the test, the influence of the heating currents on the displacement and the force generated by the thin NiTi wires were analyzed. The temperature of the wires during heating was measured by a thermographic camera. This study proved the maximum value of the wires' displacement was related to the value of the heating current. During the research, the dependence of the transformation dynamics on the value of the heating currents was also proved. In addition, the influence of the surface inhomogeneity of the thin NiTi alloy wires on the accuracy of the thermographic measurements was analyzed. For the experimental research described in this article, we used the NiTi alloy whose trade name is Flexinol, produced by DYNALLOY (Inc. 2801 McGaw Ave. Irvine, CA, USA).

10.
Sensors (Basel) ; 23(3)2023 Jan 18.
Artigo em Inglês | MEDLINE | ID: mdl-36772174

RESUMO

The flexible arm easily vibrates due to its thin structural characteristics, which affect the operation accuracy, so reducing the vibration of the flexible arm is a significant issue. Smart materials are very widely used in the research topic of vibration suppression. Considering the hysteresis characteristic of the smart materials, based on previous simulation research, this paper proposes an experimental system design of nonlinear vibration control by using the interactive actuation from shape memory alloy (SMA) for a flexible arm. The experiment system was an interactive actuator-sensor-controller combination. The vibration suppression strategy was integrated with an operator-based vibration controller, a designed integral compensator and the designed n-times feedback loop. In detail, a nonlinear vibration controller based on operator theory was designed to guarantee the robust stability of the flexible arm. An integral compensator based on an estimation mechanism was designed to optimally reduce the displacement of the flexible arm. Obtaining the desired tracking performance of the flexible arm was a further step, by increasing the n-times feedback loop. From the three experimental cases, when the vibration controller was integrated with the designed integral compensator, the vibration displacement of the flexible arm was much reduced compared to that without the integral compensator. Increasing the number of n-times feedback loops improves the tracking performance. The desired vibration control performance can be satisfied when n tends to infinity. The conventional PD controller stabilizes the vibration displacement after the 7th vibration waveform, while the vibration displacement approaches zero after the 4th vibration waveform using the proposed vibration control method, which is proved to be faster and more effective in controlling the flexible arm's vibration. The experimental cases verify the effectiveness of the proposed interactive actuation vibration control approach. It is observed from the experimental results that the vibration displacement of the flexible arm becomes almost zero within less time and with lower input power, compared with a traditional controller.

11.
Int J Mol Sci ; 24(3)2023 Jan 26.
Artigo em Inglês | MEDLINE | ID: mdl-36768774

RESUMO

Shape memory alloys, especially ferromagnetic shape memory alloys, are interesting new materials for the manufacturing of stents. Iron-palladium alloys in particular can be used to manufacture self-expanding temporary stents due to their optimum rate of degradation, which is between that of magnesium and pure iron, two metals commonly used in temporary stent research. In order to avoid blood clotting upon the introduction of the stent, they are often coated with anticoagulants. In this study, sulfated pectin, a heparin mimetic, was synthesized in different ways and used as coating on multiple iron-palladium alloys. The static and dynamic prothrombin time (PT) and activated partial thromboplastin time (APTT) of the prepared materials were compared to samples uncoated or coated with polyethylene glycol. While no large differences were observed in the prothrombin time measurements, the activated partial thromboplastin time increased significantly with all alloys coated with sulfated pectin. Aside from that, sulfated pectin synthesized by different methods also caused slight changes in the activated partial thromboplastin time. These findings show that iron-palladium alloys can be coated with anticoagulants to improve their utility as material for temporary stents. Sulfated pectin was characterized by nuclear magnetic resonance (NMR) and Fourier-transform infrared (FTIR) spectroscopy, and the coated alloys by scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDX).


Assuntos
Anticoagulantes , Ligas de Memória da Forma , Paládio , Propriedades de Superfície , Ligas/química , Ferro , Materiais Revestidos Biocompatíveis/farmacologia , Materiais Revestidos Biocompatíveis/química
12.
Artif Organs ; 46(6): 1097-1106, 2022 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-35060136

RESUMO

BACKGROUND: Fecal incontinence caused by sphincter dysfunction is a difficult medical problem that has not been fully resolved. The artificial anal sphincter provides a new therapeutic strategy for fecal incontinence. In order to solve the biomechanical compatibility problem between the artificial anal sphincter and intestinal tissue in clinical application, a design of constant force artificial anal sphincter was assessed in this paper. METHODS: The constant force properties and safety of this novel device were evaluated by an experiment conducted in pig intestines with various thicknesses. The constant force characteristic of the device was evaluated by the intestinal pressure of the pig intestine. The safety of the device was evaluated by the surface contact stress of the pig intestine clamped by an artificial anal sphincter. RESULTS: The average measured value of the intestinal pressure of the pig intestines with three thicknesses is about 55.3 mm Hg, the maximum pressure difference is 1 mm Hg, and the fluctuation error of constant clamping load is about 1.8%. The constant clamping load fluctuation error of the four measuring points of the pig intestines with three thicknesses is less than 2%. Even if the thickness of the pig intestines is changed, the measured contact stress value is lower than 10 kPa, which may avoid bit damage for the intestinal tissue. CONCLUSIONS: This study demonstrates that the novel artificial sphincter has constant force properties and safety, which prevent ischemic necrosis of soft tissues caused by excessive pressure. Therefore, this study raises the possibility of the long-term efficacy of artificial anal sphincter.


Assuntos
Órgãos Artificiais , Incontinência Fecal , Canal Anal/cirurgia , Animais , Incontinência Fecal/etiologia , Incontinência Fecal/cirurgia , Desenho de Prótese , Ligas de Memória da Forma , Suínos
13.
Sensors (Basel) ; 22(13)2022 Jun 27.
Artigo em Inglês | MEDLINE | ID: mdl-35808360

RESUMO

This paper mainly focuses on various types of robots driven or actuated by shape memory alloy (SMA) element in the last decade which has created the potential functionality of SMA in robotics technology, that is classified and discussed. The wide spectrum of increasing use of SMA in the development of robotic systems is due to the increase in the knowledge of handling its functional characteristics such as large actuating force, shape memory effect, and super-elasticity features. These inherent characteristics of SMA can make robotic systems small, flexible, and soft with multi-functions to exhibit different types of moving mechanisms. This article comprehensively investigates three subsections on soft and flexible robots, driving or activating mechanisms, and artificial muscles. Each section provides an insight into literature arranged in chronological order and each piece of literature will be presented with details on its configuration, control, and application.


Assuntos
Robótica , Ligas , Fenômenos Mecânicos , Músculos , Ligas de Memória da Forma
14.
Sensors (Basel) ; 22(5)2022 Feb 24.
Artigo em Inglês | MEDLINE | ID: mdl-35270945

RESUMO

The aim of this study was to solve the frequently occurring rotor-stator rub-impact fault in aero-engines without causing a significant reduction in efficiency. We proposed a fault mitigation scheme, using shape memory alloy (SMA) wire, whereby the tip clearance between the rotor and the stator is adjusted. In this scheme, an acoustic emission (AE) sensor is utilized to monitor the rub-impact fault. An active control actuator is designed with pre-strained two-way SMA wires, driven by an electric current via an Arduino control board, to mitigate the rub-impact fault once it occurs. In order to investigate the feasibility of the proposed scheme, a series of tests on the material properties of NiTi wires, including heating response rate, ultimate strain, free recovery rate, and restoring force, were carried out. A prototype of the actuator was designed, manufactured, and tested under various conditions. The experimental result verifies that the proposed scheme has the potential to mitigate or eliminate the rotor-stator rub-impact fault in aero-engines.

15.
Sensors (Basel) ; 22(20)2022 Oct 20.
Artigo em Inglês | MEDLINE | ID: mdl-36298354

RESUMO

This paper provides a novel Finite Element (FE) simulation to estimate the out-of-plane response of masonry prisms retrofitted with Shape Memory Alloy (SMA) stripes. Empirical data were utilized to develop the computational analysis parameters (mechanical parameters for brick, mortar, and SMA materials) as well as the calibration of the computational FE-based models. For this purpose, a complete micro-modeling approach was applied, assuming perfect contact between mortar joints and brick units. A Concrete Damage Plasticity (CDP) model was developed to define the constitutive relation between brick and mortar. SMA stripes were mortar-installed on the surface of the prisms with a perfect connection. The masonry prism's verified computational model was utilized to generate parametric research to explore the effect of varying SMA stripe thicknesses and different SMA usage (Ni-Ti or Cu-Zn-Al). The FE study findings indicated that, independent of their material type or thickness, using SMA stripes greatly minimizes brick prism deterioration. SMA stripes greatly decreased residual displacement and plastic strains. Parametric tests, however, revealed that employing Ni-Ti SMA and increasing its thickness is more effective with respect to the masonry prism out-of-plane response than Cu-Zn-Al SMA.


Assuntos
Ligas , Ligas de Memória da Forma , Plásticos
16.
Sensors (Basel) ; 22(19)2022 Oct 01.
Artigo em Inglês | MEDLINE | ID: mdl-36236559

RESUMO

This article presents the design and implementation of a linear actuator based on NiTi Shape Memory Alloys with temperature and position measurements based on a magnetic sensor array and a set of thermistors. The position instrumentation is contact free to avoid friction perturbations; the position signal conditioning is carried out through the calculation of the response of each magnetic sensor, selecting the closest sensor to ensure accurate results on the full range of movement. Experimental results validate the accuracy of the position sensing with a competitive behaviour.

17.
Sensors (Basel) ; 22(2)2022 Jan 10.
Artigo em Inglês | MEDLINE | ID: mdl-35062471

RESUMO

The behavior of masonry shear walls reinforced with pseudoelastic Ni-Ti shape memory alloy (SMA) strips and engineered cementitious composite (ECC) sheets is the main focus of this paper. The walls were subjected to quasi-static cyclic in-plane loads and evaluated by using Abaqus. Eight cases of strengthening of masonry walls were investigated. Three masonry walls were strengthened with different thicknesses of ECC sheets using epoxy as adhesion, three walls were reinforced with different thicknesses of Ni-Ti strips in a cross form bonded to both the surfaces of the wall, and one was utilized as a reference wall without any reinforcing element. The final concept was a hybrid of strengthening methods in which the Ni-Ti strips were embedded in ECC sheets. The effect of mesh density on analytical outcomes is also discussed. A parameterized analysis was conducted to examine the influence of various variables such as the thickness of the Ni-Ti strips and that of ECC sheets. The results show that using the ECC sheet in combination with pseudoelastic Ni-Ti SMA strips enhances the energy absorption capacity and stiffness of masonry walls, demonstrating its efficacy as a reinforcing method.


Assuntos
Próteses e Implantes , Ligas de Memória da Forma , Resinas Epóxi
18.
Sensors (Basel) ; 22(15)2022 Jul 27.
Artigo em Inglês | MEDLINE | ID: mdl-35957170

RESUMO

Shape memory materials are smart materials that stand out because of several remarkable properties, including their shape memory effect. Shape memory alloys (SMAs) are largely used members of this family and have been innovatively employed in various fields, such as sensors, actuators, robotics, aerospace, civil engineering, and medicine. Many conventional, unconventional, experimental, and numerical methods have been used to study the properties of SMAs, their models, and their different applications. These materials exhibit nonlinear behavior. This fact complicates the use of traditional methods, such as the finite element method, and increases the computing time necessary to adequately model their different possible shapes and usages. Therefore, a promising solution is to develop new methodological approaches based on artificial intelligence (AI) that aims at efficient computation time and accurate results. AI has recently demonstrated some success in efficiently modeling SMA features with machine- and deep-learning methods. Notably, artificial neural networks (ANNs), a subsection of deep learning, have been applied to characterize SMAs. The present review highlights the importance of AI in SMA modeling and introduces the deep connection between ANNs and SMAs in the medical, robotic, engineering, and automation fields. After summarizing the general characteristics of ANNs and SMAs, we analyze various ANN types used for modeling the properties of SMAs according to their shapes, e.g., a wire as an actuator, a wire with a spring bias, wire systems, magnetic and porous materials, bars and rings, and reinforced concrete beams. The description focuses on the techniques used for NN architectures and learning.


Assuntos
Ligas , Ligas de Memória da Forma , Inteligência Artificial , Redes Neurais de Computação , Porosidade
19.
Sensors (Basel) ; 22(18)2022 Sep 12.
Artigo em Inglês | MEDLINE | ID: mdl-36146225

RESUMO

Earthquakes threaten humanity globally in complex ways that mainly include various socioeconomic consequences of life and property losses. Resilience against seismic risks is of high importance in the modern world and needs to be sustainable. Sustainable earthquake resilience (SER) from the perspective of structural engineering means equipping the built environment with appropriate aseismic systems. Shape memory alloys (SMAs) are a class of advanced materials well suited for fulfilling the SER demand of the built environment. This article explores how this capability can be realized by the innovative SMA-based superelasticity-assisted slider (SSS), recently proposed for next-generation seismic protection of structures. The versatility of SSS is first discussed as a critical advantage for an effective SER. Alternative configurations and implementation styles of the system are presented, and other advantageous features of this high-tech isolation system (IS) are studied. Results of shaking table experiments, focused on investigating the expected usefulness of SSS for seismic protection in hospitals and conducted at the structural earthquake engineering laboratory of the University of Bonab, are then reported. SSS is compared with currently used ISs, and it is shown that SSS provides the required SER for the built environments and outperforms other ISs by benefitting from the pioneered utilization of SMAs in a novel approach.


Assuntos
Terremotos , Ligas de Memória da Forma
20.
Microsc Microanal ; : 1-7, 2021 Sep 10.
Artigo em Inglês | MEDLINE | ID: mdl-34503599

RESUMO

The properties and the shape memory effect depend, among other things, on chemical composition, as well as the method of shape memory alloy (SMA) production. One of the manufacturing methods that leads to the amorphous/nanocrystalline SMA is high-energy ball milling combined with annealing. Using this technique, an SMA memory alloy, with the nominal chemical composition of Ni25Ti50Cu25, was produced from commercial elemental powders (purity −99.7%). The structure and morphology were characterized (at the various stages of its production) by the use of X-ray diffraction, as well as electron microscopy (both scanning and transmission). Choosing the appropriate grinding time made it possible to produce an NiTiCu alloy with a different crystallite size. Its average size changed from 6.5 nm (after 50 h) to about 2 nm (100 h). Increasing the grinding time up to 140 h resulted in the formation of areas that showed the B19 martensite and the Ti2(Ni,Cu) phase with the average crystallite size of about 6 nm (as milled). After crystallization, the average size increased to 11 nm.

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