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1.
Nano Lett ; 24(21): 6344-6352, 2024 May 29.
Artigo em Inglês | MEDLINE | ID: mdl-38687224

RESUMO

Anisotropic two-dimensional materials present a diverse range of physical characteristics, making them well-suited for applications in photonics and optoelectronics. While mechanical properties play a crucial role in determining the reliability and efficacy of 2D material-based devices, the fracture behavior of anisotropic 2D crystals remains relatively unexplored. Toward this end, we herein present the first measurement of the anisotropic fracture toughness of 2D Ta2NiSe5 by microelectromechanical system-based tensile tests. Our findings reveal a significant in-plane anisotropic ratio (∼3.0), accounting for crystal orientation-dependent crack paths. As the thickness increases, we observe an intriguing intraplanar-to-interplanar transition of fracture along the a-axis, manifesting as stepwise crack features attributed to interlayer slippage. In contrast, ruptures along the c-axis surprisingly exhibit persistent straightness and smoothness regardless of thickness, owing to the robust interlayer shear resistance. Our work affords a promising avenue for the construction of future electronics based on nanoribbons with atomically sharp edges.

2.
Cell Tissue Bank ; 25(3): 765-772, 2024 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-38776014

RESUMO

Tissue engineering is a set of techniques for producing or reconstructing tissue that primarily aims to restore or improve the function of tissues in the human body. The aim of the present study was to evaluate the mechanical and histological characteristics of decellularized tracheal scaffolds prepared in comparison with fresh trachea for use in tracheal repair. In order to prepare the scaffold, sheep's trachea was prepared and after cleaning the waste tissues, they were decellularized. Then decellularized scaffolds were evaluated histologically and laboratory and numerical study of the nonlinear mechanical behavior of tracheal tissue and scaffold and their comparison. Examining the results of histological evaluations showed that the decellularization of the scaffolds was completely done. These results were confirmed by hematoxylin-eosin staining. Also, the exact hyperelastic properties of tracheal tissue and scaffold were used in biomechanical models, and according to the presented results, the five-term Mooney-Rivlin strain energy density function became a suitable behavioral model for modeling the hyperelastic behavior of trachea and scaffold. In total, the results of this research showed that the scaffolds obtained from decellularization by preserving the main compositions of the desired tissue can be a suitable platform for investigating cell behaviors.


Assuntos
Engenharia Tecidual , Alicerces Teciduais , Traqueia , Traqueia/citologia , Traqueia/fisiologia , Animais , Alicerces Teciduais/química , Ovinos , Fenômenos Biomecânicos , Engenharia Tecidual/métodos
3.
Sheng Wu Yi Xue Gong Cheng Xue Za Zhi ; 41(1): 136-143, 2024 Feb 25.
Artigo em Chinês | MEDLINE | ID: mdl-38403614

RESUMO

In order to understand how the biomechanical properties of rabbit cornea change over time after corneal ablation, 21 healthy adult rabbits were used in this study, with the left eye as experimental side and the right eye as the control side. Firstly, a lamellar knife was used to remove a portion of the anterior corneal surface tissue (30%~50% of the original corneal thickness) from the left eye of each rabbit, as an animal model simulating corneal refractive surgery. Secondly, postoperative experimental rabbits were kept for one, three, or six months until being euthanized. Strip specimens were produced using their corneas in vitro to perform a uniaxial tensile test with an average loading-unloading rate of approximately 0.16 mm/s. Finally, the visco-hyperelastic material constitutive model was used to fit the data. The results showed that there was a significant difference in the viscoelastic parameters of the corneas between the experimental and the control eyes at the first and third postoperative months. There was a difference in tangential modulus between the experimental and the control eyes at strain levels of 0.02 and 0.05 at the third postoperative month. There was no significant difference in biomechanical parameters between the experimental and the control eyes at the sixth postoperative month. These results indicate that compared with the control eyes, the biomechanical properties of the experimental eyes vary over postoperative time. At the third postoperative month, the ratio of corneal tangential modulus between the experimental and the control eyes significantly increased, and then decreased. This work lays a preliminary foundation for understanding the biomechanical properties of the cornea after corneal refractive surgery based on rapid testing data obtained clinically.


Assuntos
Córnea , Procedimentos Cirúrgicos Refrativos , Animais , Coelhos , Córnea/cirurgia , Fenômenos Biomecânicos
4.
J Synchrotron Radiat ; 30(Pt 4): 739-745, 2023 Jul 01.
Artigo em Inglês | MEDLINE | ID: mdl-37166982

RESUMO

An understanding of deformation behavior and texture development is crucial for the formability improvement of Mg alloys. X-ray line profile analysis using the convolutional multiple whole profile (CMWP) fitting method allows the experimental determination of dislocation densities separately for different Burgers vectors up to a high deformation degree. A wider use of this technique still requires exploration and testing of various materials. In this regard, the reliability of the CMWP fitting method for Mg-Zn-Y alloys, in terms of the dislocation activity during tensile deformation, was verified in the present study by the combined analysis of electron backscatter diffraction (EBSD) investigation and visco-plastic self-consistent (VPSC) simulation. The predominant activity of non-basal 〈a〉 dislocation slip was revealed by CMWP analysis, and Schmid factor analysis from the EBSD results supported the higher potential of non-basal dislocation slip in comparison with basal 〈a〉 dislocation slip. Moreover, the relative slip activities obtained by the VPSC simulation also show a similar trend to those obtained from the CMWP evaluation.


Assuntos
Ligas , Síncrotrons , Reprodutibilidade dos Testes , Zinco
5.
Exp Eye Res ; 227: 109363, 2023 02.
Artigo em Inglês | MEDLINE | ID: mdl-36584907

RESUMO

Corneal cross-linking (CXL) has been proved efficiency for treating progressive keratoconus and other corneal ectasia diseases by stabilizing corneal geometry and biomechanics. However, the necessity of repeated CXL treatment in patients is unknown. This study aimed to investigate corneal biomechanical stiffness and change in corneal histopathological characteristics after repeated accelerated CXL (A-CXL) in cat eyes. A-CXL was performed with 0.1% riboflavin applied for 10 min, followed by ultraviolet A irradiation at 30 mW/cm2 for 3 min at 365 nm in 15 domestic cats. Corneas (n = 30) were divided into three groups: one-time accelerated corneal cross-linking (A-CXL*1 group), repeated accelerated corneal cross-linking (A-CXL*2 group), and an untreated control group. In A-CXL*2 group, A-CXL was repeated at 1-month intervals. In vivo ocular examinations were performed pre- and postoperatively. Biomechanical analysis was performed using a biotester biaxial testing system. We used the Mooney-Rivlin strain-energy function to describe corneal material properties. No infection in any case after A-CXL was observed. Biomechanical tests showed that the stress-strain curves of the two A-CXL groups were significantly different from those of the control group (P < 0.01), whereas stress-strain curve of the A-CXL*2 group was similar to that of the A-CXL*1 group (P > 0.05). Delayed epithelial healing and haze were observed 1 month after surgery. Stromal demarcation line depth measured with anterior spectral-domain optical coherence tomography was 187.6 ± 20.4 and 197.1 ± 11.5 µm for the A-CXL*1 and A-CXL*2 groups, respectively (P > 0.05). These results show that A-CXL can increase corneal biomechanics in cat eyes. The biomechanical enhancement of cat corneas treated with repeated A-CXL at 1-month intervals was similar to that of performing a one-time A-CXL. Repeated cross-linking procedures at short intervals may increase the risk of adverse reactions, and more caution should be taken in clinical applications.


Assuntos
Ceratocone , Fármacos Fotossensibilizantes , Animais , Gatos , Fármacos Fotossensibilizantes/uso terapêutico , Crosslinking Corneano , Substância Própria/patologia , Colágeno/uso terapêutico , Reagentes de Ligações Cruzadas/uso terapêutico , Córnea/patologia , Riboflavina/farmacologia , Riboflavina/uso terapêutico , Raios Ultravioleta , Ceratocone/tratamento farmacológico , Ceratocone/patologia , Topografia da Córnea
6.
Nano Lett ; 22(24): 9883-9890, 2022 12 28.
Artigo em Inglês | MEDLINE | ID: mdl-36472408

RESUMO

The growth of flexible semiconductor thin films and membranes is highly desirable for the fabrication of next-generation wearable devices. In this work, we have developed a one-step, surface tension-driven method for facile and scalable growth of silver sulfide (Ag2S) membranes with a nanomesh structure. The nanomesh membrane can in principle reach infinite size but only limited by the reactor size, while the thickness is self-limited to ca. 50 nm. In particular, the membrane can be continuously regenerated at the water surface after being transferred for mechanical and electronic tests. The free-standing membrane demonstrates exceptional flexibility and strength, resulting from the nanomesh structure and the intrinsic plasticity of the Ag2S ligaments, as revealed by robust manipulation, nanoindentation tests and a pseudo-in situ tensile test under scanning electron microscope. Bendable electronic resistance-switching devices are fabricated based on the nanomesh membrane.


Assuntos
Semicondutores , Compostos de Prata , Eletrônica
7.
Surg Endosc ; 36(12): 8797-8806, 2022 12.
Artigo em Inglês | MEDLINE | ID: mdl-35578046

RESUMO

BACKGROUND: Recently, in the field of abdominal wall repair surgery, some minimally invasive procedures introduced the use of staplers to provide a retromuscular prosthetic repair. However, to the knowledge of the authors, there are little data in the literature about the outcomes of stapled sutures adoption for midline reconstruction. This study aims to investigate the biomechanics of stapled sutures, simple (stapled), or oversewn (hybrid), in comparison with handsewn suture. From the results obtained, we tried to draw indications for their use in a clinical context. METHODS: Human cadaver fascia lata specimens, sutured (handsewn, stapled, or hybrid) or not, underwent tensile tests. The data on strength (maximal stress), ultimate strain (deformability), Young's modulus (rigidity), and dissipated specific energy (ability to absorb mechanical energy up to the breaking point) were recorded for each type of specimens and analyzed. RESULTS: Stapled and hybrid suture showed a significantly higher strength (handsewn 0.83 MPa, stapled 2.10 MPa, hybrid 2.68 MPa) and a trend toward a lower ultimate strain as compared to manual sutures (handsewn 344%, stapled 249%, hybrid 280%). Stapled and hybrid sutures had fourfold higher Young's modulus as compared to handsewn sutures (handsewn 1.779 MPa, stapled 7.374 MPa, hybrid 6.964 MPa). Handsewn and hybrid sutures showed significantly higher dissipated specific energy (handsewn 0.99 mJ-mm3, stapled 0.73 mJ-mm3, hybrid 1.35 mJ-mm3). CONCLUSION: Stapled sutures can resist high loads, but are less deformable and rigid than handsewn suture. This suggests a safer employment in case of small defects or diastasis (< W1 in accord to EHS classification), where the presumed tissutal displacement is minimal. Oversewing a stapled suture improves its efficiency, becoming crucial in case of larger defects (> W1 in accord to EHS classification) where the expected tissutal displacement is maximal. Hybrid sutures seem to be a good compromise.


Assuntos
Proctocolectomia Restauradora , Grampeamento Cirúrgico , Humanos , Técnicas de Sutura , Suturas , Proctocolectomia Restauradora/métodos , Anastomose Cirúrgica/métodos
8.
J Esthet Restor Dent ; 34(7): 1068-1076, 2022 10.
Artigo em Inglês | MEDLINE | ID: mdl-35578442

RESUMO

OBJECTIVE: This study aimed to evaluate the effects of different universal adhesives and surface treatments on the repair bond strength between resin composites. MATERIALS AND METHODS: A total of 220 composite samples were divided into three groups according to the adhesive resin to be applied: 1) Scotchbond Universal, 2) G-Premio Bond, and 3) Peak Universal Bond. They were then divided into seven subgroups according to surface treatments (n = 10): A) air abrasion, B) air abrasion+silane, C) hydrofluoric acid, D) hydrofluoric acid+silane, E) air abrasion+hydrofluoric acid+silane, F) silane, and G) no surface treatment (negative control). After surface treatment, a repair composite was applied. Samples aged in the thermocycle were subjected to micro-tensile bond strength testing. Cohesive strength values of 10 non-aged composite blocks were used as a positive control. Kruskal-Wallis and one-way ANOVA tests were used for statistical evaluation. Fractured surfaces were evaluated using a scanning electron microscope. RESULTS: In Scotchbond Universal and G-Premio Bond, the mean micro-tensile bond strength value of the no surface treatment subgroup was significantly lower than that of the positive control. All subgroups of Peak Universal Bond showed similar values to the positive control. CONCLUSION: While Scotchbond Universal and G-Premio Bond required mechanical roughening before adhesive application, Peak Universal Bond did not require any surface treatment. CLINICAL SIGNIFICANCE: Different universal adhesives may show different repair bonding strengths with different surface treatments. Since achieving a standard in this regard can be associated with many independent factors, clinicians should determine how to apply the adhesive they use most effectively with the most appropriate surface treatment based on their own clinical experience.


Assuntos
Abrasão Dental por Ar , Colagem Dentária , Resinas Compostas/química , Cimentos Dentários , Ácido Fluorídrico , Teste de Materiais , Metacrilatos , Cimentos de Resina/química , Silanos/química , Propriedades de Superfície , Resistência à Tração
9.
J Fish Biol ; 100(1): 242-252, 2022 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-34739135

RESUMO

In recent days, many researchers are focusing on emerging a new class of bio-inspired architectured materials. The primary strategy of these architecture designs is directly dependent on the types of available literature based on higher-ordered species such as nacre and fish scales. In this study, the authors have investigated the microstructural features and mechanical properties of five different ray-finned fish scales from Lutjanidae family collected in Iran. It was found that habitat depth and habits may result in significant changes in scale's surface morphology and mechanical properties. Interestingly, the variations in cross-sectional microstructural features such as fibre orientation and layer thickness ratios in scales did not show noticeable differences. It has also been proved that the mechanical performance of fish scales is influenced by the shape, array pattern and compactness of strips on posterior edges in a scale. Moreover, the radii count at anterior positions is higher in fishes living in wide-ranging depth; it supports in achieving higher scale stiffness and flexibility during movement. Consideration of these factors may help in optimising the performance of newly designed architectured materials subjected to mechanical loadings.


Assuntos
Ecossistema , Peixes , Animais , Estudos Transversais , Irã (Geográfico)
10.
Proc Biol Sci ; 288(1954): 20211125, 2021 07 14.
Artigo em Inglês | MEDLINE | ID: mdl-34229492

RESUMO

Coevolution of male and female genitalia is widespread in animals. Nevertheless, few studies have examined the mechanics of genital interactions during mating. We characterized the mechanical properties of the elongated female genitalia, the spermathecal duct, of the small cassidine beetle, Cassida rubiginosa. The data were compared with the mechanical properties of the elongated male genitalia, the flagellum. We analysed the material distributions of the spermathecal duct using a microscopy technique, established a tensile test setup under a light microscope and conducted tensile tests. Diameter and tensile stiffness gradients were present along the spermathecal duct, but its Young's modulus and material distribution were more or less homogeneous. The results confirmed the hypothesis based on numerical simulations that the spermathecal duct is more rigid than the flagellum. In the study species, the penile penetration force is simply applied to the base of the hyper-elongated flagellum and conveyed along the flagellum to its tip. Considering this simple penetration mechanism, the relatively low flexibility of the spermathecal duct, compared to the flagellum, is likely to be essential for effective penetration of the flagellum.


Assuntos
Besouros , Animais , Feminino , Genitália Feminina , Genitália Masculina , Masculino , Pênis , Reprodução
11.
Skin Res Technol ; 27(5): 948-958, 2021 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-33822382

RESUMO

BACKGROUND: Suction cups are widely used in applications such as in measurement of mechanical properties of skin in vivo, in drug delivery devices or in acupuncture treatment. Understanding mechanical response of skin under hypobaric pressure is of great importance for users of suction cups. The aim of this work is to predict the hypobaric pressure induced 3D stretching of the skin. METHODS: Experimental skin tensile tests were carried out for mechanical property characterization. Both linear elasticity and hyperelasticity parameters were determined and implemented in Finite Element modelling. Skin suction tests were performed in both experiments and FEM simulations for model validation. 3D skin stretching is then visualized in detail in FEM simulations. RESULTS: The simulations showed that the skin was compressed consistently along the thickness direction, leading to reduced thickness. At the center of the dome, the radial and angular strain decreases from the top surface to the bottom surface, although always in tension. Hyperelasticity modelling showed superiority over linear elasticity modelling while predicting the strain distribution because the stretch ratio reaches values exceeding the initial linear elastic stage of the stress-strain curve for skin. CONCLUSION: Hyperelasticity modelling is an effective approach to predict the 3D strain distribution, which paves a way to accurately design safe commercial products that interface with the skin.


Assuntos
Pele , Fenômenos Biomecânicos , Elasticidade , Análise de Elementos Finitos , Pressão , Estresse Mecânico
12.
J Biomech Eng ; 143(1)2021 01 01.
Artigo em Inglês | MEDLINE | ID: mdl-33006367

RESUMO

Tensile testing is an essential experiment to assess the mechanical integrity of musculoskeletal soft tissues, yet standard test methods have not been developed to ensure the quality and reproducibility of these experiments. The ASTM International standards organization has created tensile test standards for common industry materials that specify geometric dimensions of test specimens (coupons) that promote valid failures within the gage section (midsubstance), away from the grips. This study examined whether ASTM test standards for plastics, elastomers, and fiber-reinforced composites are suitable for tensile testing of bovine meniscus along the circumferential fiber direction. We found that dumbbell (DB) shaped coupons based on ASTM standards for elastomers and plastics had an 80% and 60% rate of midsubstance failures, respectively. The rate of midsubstance failures dropped to 20% when using straight (ST) coupons based on ASTM standards for fiber-reinforced composites. The mechanical properties of dumbbell shaped coupons were also significantly greater than straight coupons. Finite element models of the test coupons revealed stress distributions that supported our experimental findings. In addition, we found that a commercial deli-slicer was able to slice meniscus to uniform layer thicknesses that were within ASTM dimensional tolerances. This study provides methods, recommendations, and insights that can advance the standardization of tensile testing in meniscus and other soft fibrous tissues.


Assuntos
Teste de Materiais , Resistência à Tração , Estresse Mecânico
13.
Mar Drugs ; 19(12)2021 Nov 29.
Artigo em Inglês | MEDLINE | ID: mdl-34940678

RESUMO

The growing applications of tissue engineering technologies warrant the search and development of biocompatible materials with an appropriate strength and elastic moduli. Here, we have extensively studied a collagenous membrane (GSCM) separated from the mantle of the Giant squid Dosidicus Gigas in order to test its potential applicability in regenerative medicine. To establish the composition and structure of the studied material, we analyzed the GSCM by a variety of techniques, including amino acid analysis, SDS-PAGE, and FTIR. It has been shown that collagen is a main component of the GSCM. The morphology study by different microscopic techniques from nano- to microscale revealed a peculiar packing of collagen fibers forming laminae oriented at 60-90 degrees in respect to each other, which, in turn, formed layers with the thickness of several microns (a basketweave motif). The macro- and micromechanical studies showed high values of the Young's modulus and tensile strength. No significant cytotoxicity of the studied material was found by the cytotoxicity assay. Thus, the GSCM consists of a reinforced collagen network, has high mechanical characteristics, and is non-toxic, which makes it a good candidate for the creation of a scaffold material for tissue engineering.


Assuntos
Materiais Biocompatíveis/química , Colágeno/química , Decapodiformes , Alicerces Teciduais/química , Animais , Organismos Aquáticos , Resistência à Tração , Engenharia Tecidual
14.
BMC Musculoskelet Disord ; 22(1): 1047, 2021 Dec 20.
Artigo em Inglês | MEDLINE | ID: mdl-34930185

RESUMO

BACKGROUND: Bone and Site Hold Tendon Inside (BASHTI) technique is an organic implant-less technique for anterior cruciate ligament (ACL) reconstruction with some clinical advantages, such as speeding up the healing process, over implantable techniques. The study aims to compare the mechanical properties of BASHTI technique with the conventional interference screw technique. METHODS: To investigate the mechanical properties, 20 in-vitro experimental tests were conducted. Synthetic dummy bone, along with fresh digital bovine tendons, as a graft, were used for experiments. Three loading steps were applied to all specimens, including a preconditioning, a main cyclic, and a pull-out loading. RESULTS: The mechanical characters of an interference screw technique using an 8 mm tendon diameter, including fixation strength, average cyclic stiffness (ACS), and average pull-out stiffness (APS) were found to be 439 ± 132 N, 10.3 ± 5.3 kN/mm, and 109 ± 40 N/mm, respectively. In the case of an interference screw using a 9 mm tendon, the fixation strength, ACS, and APS were obtained 549 ± 87 N, 10.3 ± 4.7 kN/mm, and 91 ± 13 N/mm, respectively. In parallel, the fixation strength, APS, and ACS of BASHTI technique using an 8 mm tendon were 360 ± 123 N, 3.3 ± 0.6 kN/mm, and 79 ± 27 N/mm, respectively, while, for 9 mm tendon 278 ± 103 N, 2.4 ± 1.2 kN/mm, and 111 ± 40 N/mm, were reported for fixation strength, APS, and ACS respectively when BASHTI technique was used. CONCLUSION: About 50% of interference screw samples showed superior mechanical properties compared to BASHTI technique, but in another half of the samples, the differences were not significant (N.S.). However, due to organic advantages of BASHTI technique and lower cost, it could be used as a substitute for interference screw technique, especially where fast recovery is expected.


Assuntos
Reconstrução do Ligamento Cruzado Anterior , Animais , Parafusos Ósseos , Bovinos , Humanos
15.
J Res Natl Inst Stand Technol ; 126: 126050, 2021.
Artigo em Inglês | MEDLINE | ID: mdl-38469435

RESUMO

Uniaxial tensile tests are routinely conducted to obtain stress-strain data for forming applications. It is important to understand the deformation behavior of test specimens at plastic strains, temperatures, and strain rates typically encountered in metal forming processes. In this study, the Johnson-Cook (J-C) flow stress model was used to describe the constitutive behavior of ASTM International (ASTM) A 1008 steel specimens during uniaxial tensile tests at three different average strain rates (10-5 s-¹, 10-³ s-¹, and 10-¹ s-¹). The digital image correlation (DIC) technique was used for displacement and strain measurement, and two-dimensional (2D) infrared (IR) imaging was employed for temperature measurement. Separate optimization studies involving relevant finite element (FE) modeling with appropriate measured data yielded optimum values of convective heat transfer coefficients, J-C parameters, and inelastic heat fraction variables. FE modeling employing these optimum parameter values was then used to study the mechanical behavior. While FE predictions matched measured strain localization and thermal field very well in the intermediate- and low-rate experiments, the high-rate test showed narrower strain localization and a sharper temperature peak in the experiment. Possible use of a higher steel thermal conductivity value and/or exclusion of material inhomogeneities may have resulted in discrepancies between computed and measured temperature and strain fields. The study shows that an optimized set of parameters obtained with a controlled test could be reasonably applied for other tests conducted at very different strain rates.

16.
Sensors (Basel) ; 21(24)2021 Dec 09.
Artigo em Inglês | MEDLINE | ID: mdl-34960329

RESUMO

This manuscript deals with the detection of internal cracks and defects in aeronautical fibreglass structures. In technical practice, it is problematic to accurately determine the service life or MTBF (Mean Time Between Failure) of composite materials by the methods used in metallic materials. The problem is mainly the inhomogeneous and anisotropic structure of composites, possibly due to the differences in the macrostructure during production, production processes, etc. Diagnostic methods for detecting internal cracks and damage are slightly different, and in practice, it is more difficult to detect defects using non-destructive testing (NDT). The article deals with the use of Radio frequency identification (RFID) technology integrated in the fibreglass laminates of aircraft structures to detect internal defects based on deformation behaviour of passive RFID tag antenna. The experiments proved the potential of using RFID technology in fibreglass composite laminates when using tensile tests applied on specimens with different structural properties. Therefore, the implementation of passive RFID tags into fibreglass composite structures presents the possibilities of detecting internal cracks and structural health monitoring. The result and conclusion of the basic research is determination of the application conditions for our proposed technology in practice. Moreover, the basic research provides recommendations for the applied research in terms of the use in real composite airframe structures.


Assuntos
Dispositivo de Identificação por Radiofrequência , Pesquisa
17.
Sensors (Basel) ; 21(12)2021 Jun 17.
Artigo em Inglês | MEDLINE | ID: mdl-34204422

RESUMO

In recent decades, researchers have paid more attention to the indirect tensile test than to the direct tensile test (DTT) of rocks, mainly due to difficulties in the alignment and the stress concentration at the end of an intact cylindrical specimen. In this paper, a new flattened cylinder specimen and a clamp device were designed to obtain the true tensile strength of the rock in DTT. Stress distributions of the specimen with different lengths (l) and cutting thicknesses (t) were analyzed, and damage processes of the specimen were monitored by the Digital Image Correlation (DIC), the fractured sections were also scanned. Different mechanical parameters were also obtained by the DTT of the flattened cylinder specimens and the intact cylinder specimens, as well as the Brazilian disc. Research results show that the tensile strength obtained by DTT is smaller than the Brazilian disc and is slightly greater than the intact cylindrical specimen. The flattened cylinder specimen with 0.20 ≤ 2t/D < 0.68 and 0.10 ≤ l/D ≤ 0.20 is recommended to measure the true tensile strength of rock material in DTT. This new shape of the specimen is promising to be extended in the uniaxial or triaxial direct tension test.

18.
Molecules ; 26(3)2021 Jan 22.
Artigo em Inglês | MEDLINE | ID: mdl-33499359

RESUMO

Carbonized elastomer-based composites (CECs) possess a number of attractive features in terms of thermomechanical and electromechanical performance, durability in aggressive media and facile net-shape formability, but their relatively low ductility and strength limit their suitability for structural engineering applications. Prospective applications such as structural elements of micro-electro-mechanical systems MEMS can be envisaged since smaller principal dimensions reduce the susceptibility of components to residual stress accumulation during carbonization and to brittle fracture in general. We report the results of in situ in-SEM study of microdeformation and fracture behavior of CECs based on nitrile butadiene rubber (NBR) elastomeric matrices filled with carbon and silicon carbide. Nanostructured carbon composite materials were manufactured via compounding of elastomeric substance with carbon and SiC fillers using mixing rolling mill, vulcanization, and low-temperature carbonization. Double-edge notched tensile (DENT) specimens of vulcanized and carbonized elastomeric composites were subjected to in situ tensile testing in the chamber of the scanning electron microscope (SEM) Tescan Vega 3 using a Deben microtest 1 kN tensile stage. The series of acquired SEM images were analyzed by means of digital image correlation (DIC) using Ncorr open-source software to map the spatial distribution of strain. These maps were correlated with finite element modeling (FEM) simulations to refine the values of elastic moduli. Moreover, the elastic moduli were derived from unloading curve nanoindentation hardness measurements carried out using a NanoScan-4D tester and interpreted using the Oliver-Pharr method. Carbonization causes a significant increase of elastic moduli from 0.86 ± 0.07 GPa to 14.12 ± 1.20 GPa for the composite with graphite and carbon black fillers. Nanoindentation measurements yield somewhat lower values, namely, 0.25 ± 0.02 GPa and 9.83 ± 1.10 GPa before and after carbonization, respectively. The analysis of fractography images suggests that crack initiation, growth and propagation may occur both at the notch stress concentrator or relatively far from the notch. Possible causes of such response are discussed, namely, (1) residual stresses introduced by processing; (2) shape and size of fillers; and (3) the emanation and accumulation of gases in composites during carbonization.


Assuntos
Elastômeros/química , Nanocompostos/química , Carbono/química , Compostos Inorgânicos de Carbono/química , Simulação por Computador , Módulo de Elasticidade , Análise de Elementos Finitos , Dureza , Teste de Materiais , Microscopia Eletrônica de Varredura , Nanocompostos/ultraestrutura , Compostos de Silício/química , Estresse Mecânico , Resistência à Tração
19.
Environ Chem Lett ; 19(2): 1737-1763, 2021.
Artigo em Inglês | MEDLINE | ID: mdl-33424525

RESUMO

Issues of fossil fuel and plastic pollution are shifting public demand toward biopolymer-based textiles. For instance, silk, which has been traditionally used during at least 5 milleniums in China, is re-emerging in research and industry with the development of high-tech spinning methods. Various arthropods, e.g. insects and arachnids, produce silky proteinic fiber of unique properties such as resistance, elasticity, stickiness and toughness, that show huge potential for biomaterial applications. Compared to synthetic analogs, silk presents advantages of low density, degradability and versatility. Electrospinning allows the creation of nonwoven mats whose pore size and structure show unprecedented characteristics at the nanometric scale, versus classical weaving methods or modern techniques such as melt blowing. Electrospinning has recently allowed to produce silk scaffolds, with applications in regenerative medicine, drug delivery, depollution and filtration. Here we review silk production by the spinning apparatus of the silkworm Bombyx mori and the spiders Aranea diadematus and Nephila Clavipes. We present the biotechnological procedures to get silk proteins, and the preparation of a spinning dope for electrospinning. We discuss silk's mechanical properties in mats obtained from pure polymer dope and multi-composites. This review highlights the similarity between two very different yarn spinning techniques: biological and electrospinning processes.

20.
Int J Legal Med ; 134(4): 1501-1510, 2020 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-31820099

RESUMO

The purpose of this work has been to determine differences in biomechanical properties of porcine skin from organic and non-organic farming as porcine skin is widely used as a model for human skin. A test apparatus was used, using gravity to stretch and finally tear a dumbbell-shaped specimen of prepared abdominal skin with a testing surface area of 25 × 4 mm. A total of 32 specimens were taken from seven individual pigs, three from organic and four from non-organic farming, in different orientations with respect to the Langer's lines. The tests were performed at a dynamic speed of around 1.66 m/s (corresponding to a nominal strain rate of 67 s-1). Engineering strain at rupture was higher in pig skin from non-organic farming with values up to 321% as opposed to 90% in organic pig skin. The maximum tensile stress found in non-organic pig skin was lower than in pig skin from organic farming with maximum values of 34 MPa as opposed to 58 MPa. The reason for the difference in biomechanical properties is unclear; the effect of sunlight is discussed as well as other factors like age and exercise. It seems that the biomechanical properties of porcine skin from organic farming are more similar to those of human skin.


Assuntos
Fenômenos Fisiológicos da Pele , Sus scrofa , Resistência à Tração , Animais , Fenômenos Biomecânicos , Alemanha , Humanos , Modelos Animais , Agricultura Orgânica
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