Two isostructural carboranes: 3-phenyl-1,2-dicarba-closo-dodecaborane(12) and 1-phenyl-1,7-dicarba-closo-dodecaborane(12).

Grintselev-Knyazev, G V; Lyssenko, K A; Antipin, M Y; Knyazev, S P; Kirin, V N; Chernyshev, E A

Grintselev-Knyazev, G V; Lyssenko, K A; Antipin, M Y; Knyazev, S P; Kirin, V N; Chernyshev, E A.

Grintselev-Knyazev GV; X-Ray Structural Centre, Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov Street, B-334, Moscow 117813, Russian Federation. gena@xrlab.ineos.ac.ru

Acta Crystallogr C ; 57(Pt 7): 827-9, 2001 Jul.

Article en En | MEDLINE | ID: mdl-11443255

RESUMEN

Two phenyl-substituted carboranes, 3-phenyl-1,2-dicarba-closo-dodecaborane(12), C8H16B10, (I), and 1-phenyl-1,7-dicarba-closo-dodecaborane(12), C8H16B10, (II), were found to be isostructural. Comparison of the bond angles at the ipso-C atoms of the phenyl substituent for (I) and (II) [117.71 (3) and 118.45 (10) degrees, respectively] indicates that electron donation of the carborane cage for B- and C-substituted carboranes is different.

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Banco de datos: MEDLINE Idioma: En Año: 2001 Tipo del documento: Article

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Banco de datos: MEDLINE Idioma: En Año: 2001 Tipo del documento: Article