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Enhancing the reactivity of 1,2,3-triazoles in "click" macrocycles by face-to-face dibenzylammonium ion binding.
Liu, Yi; Zhang, Xiyun; Klivansky, Liana M; Koshkakaryan, Gayane.
  • Liu Y; The Molecular Foundry, Lawrence Berkeley National Laboratory, One Cyclotron Road, MS 67R6110, Berkeley, CA 94720, USA.
Chem Commun (Camb) ; (45): 4773-5, 2007 Dec 07.
Article en En | MEDLINE | ID: mdl-18004437
ABSTRACT
A face-to-face binding motif between dibenzylammonium ions and macrocycles containing 1,2,3-triazoles was established, which operates cooperatively to enhance the reactivity of 1,2,3-triazoles in an Arbuzov-type dealkylation reaction.
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Banco de datos: MEDLINE Idioma: En Año: 2007 Tipo del documento: Article
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Banco de datos: MEDLINE Idioma: En Año: 2007 Tipo del documento: Article