Eicosanuclear cluster [Cu(13)W(7)] of copper-octacyanotungstate bimetallic assembly: synthesis, structure, and magnetic properties.

Wang, Jun; Zhang, Zai-Chao; Wang, Hui-Sheng; Kang, Ling-Chen; Zhou, Hong-Bo; Song, You; You, Xiao-Zeng

Wang, Jun; Zhang, Zai-Chao; Wang, Hui-Sheng; Kang, Ling-Chen; Zhou, Hong-Bo; Song, You; You, Xiao-Zeng.

Wang J; State Key Lab of Coordination Chemistry and School of Chemistry and Chemical Engineering, Nanjing University, Hankou Road 22, Nanjing 210093, People's Republic of China.

Inorg Chem ; 49(7): 3101-3, 2010 Apr 05.

Article en En | MEDLINE | ID: mdl-20218652

RESUMEN

Octacyanotungstate(V) reacts with Cu(NO(3))(2).2H(2)O and 1,4,7-trimethyl-1,4,7-triazacyclononane in methanol, resulting in an eicosanuclear cluster [Cu(13)W(7)], which shows a diamondoid shape with a Tolkowsky cut and bears intracluster ferromagnetic coupling.

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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Año: 2010 Tipo del documento: Article

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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Año: 2010 Tipo del documento: Article