An eight-coordinate vanadium thiolate complex with charge delocalization between V(V)-thiolate and V(IV)-thiyl radical forms.
J Am Chem Soc
; 133(15): 5708-11, 2011 Apr 20.
Article
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| MEDLINE
| ID: mdl-21438583
ABSTRACT
A six-coordinate oxovanadium(V) thiolate complex and an eight-coordinate non-oxovanadium thiolate complex, [PPh(4)][VO(PS3'')(OCH(3))] (1) and [NEt(4)][V(PS3'')(2)] (2) (PS3'' = P(C(6)H(3)-3-Me(3)Si-2-S)(3)(3-)), respectively, have been isolated and structurally characterized. The former belongs to a limited collection of oxovanadium(V) thiolate complexes. The latter has an unusual coordination number of eight. More importantly, its consensus electronic structure derived from its spectroscopic data should be considered as the resonance forms of V(V)-thiolate and V(IV)-thiyl radical species. This implies that V(IV)-thiyl radical can maintain a stable presence in biological systems.
Texto completo:
1
Banco de datos:
MEDLINE
Asunto principal:
Compuestos de Sulfhidrilo
/
Vanadatos
/
Compuestos de Vanadio
Idioma:
En
Año:
2011
Tipo del documento:
Article