Simultaneous desulfurization and denitrification from flue gas by Ferrate(VI).
Environ Sci Technol
; 45(9): 4060-5, 2011 May 01.
Article
en En
| MEDLINE
| ID: mdl-21466216
ABSTRACT
An innovative semidry process has been developed to simultaneously remove NO and SO2 from flue gas. According to the conditions of the flue gas circulating fluidized bed (CFB) system, ferrate(VI) absorbent was prepared and added to humidified water, and the effects of the various influencing factors, such as ferrate(VI) concentration, humidified water pH, inlet flue gas temperature, residence time, molar ratio of Ca/(S+N), and concentrations of SO2 and NO on removal efficiencies of SO2 and NO were studied experimentally. Removal efficiencies of 96.1% for SO2 and 67.2% for NO were obtained, respectively, under the optimal experimental conditions, in which the concentration of ferrate(VI) was 0.03 M, the humidified water pH was 9.32, the inlet flue gas temperature was 130 °C, the residence time was 2.2 s, and the molar ratio of Ca/(S+N) was 1.2. In addition, the reaction mechanism of simultaneous desulfurization and denitrification using ferrate(VI) was proposed.
Texto completo:
1
Banco de datos:
MEDLINE
Asunto principal:
Dióxido de Azufre
/
Restauración y Remediación Ambiental
/
Gases
/
Hierro
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Óxidos de Nitrógeno
Idioma:
En
Año:
2011
Tipo del documento:
Article