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Dichlorido(2,9-diprop-oxy-1,10-phenanthroline-κN,N')cadmium(II).
Niu, Cao-Yuan; Zheng, Xian-Fu; Dang, Yu-Li.
  • Niu CY; College of Sciences, Henan Agricultural University, Zhengzhou 450002, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online ; 65(Pt 10): m1245, 2009 Sep 26.
Article en En | MEDLINE | ID: mdl-21577762
ABSTRACT
In the title complex, [CdCl(2)(C(18)H(20)N(2)O(2))], the Cd(II) ion is coordinated by two N atoms from a bis-chelating 2,9-diprop-oxy-1,10-phenanthroline ligand and two Cl atoms in a distorted tetra-hedral environment. The two Cd-Cl bond distances are significantly different from each other and the N-Cd-N bond angle is acute. In the crystal structure, there are π-π stacking inter-actions between symmetry-related phenanthroline ring systems, with a centroid-centroid distance of 3.585 (3) Å.