Tris(1H-imidazole-κN)(7-oxabicyclo-[2.2.1]heptane-2,3-dicarboxyl-ato-κO,O,O)cobalt(II) 3.35-hydrate.
Acta Crystallogr Sect E Struct Rep Online
; 65(Pt 8): m854, 2009 Jul 01.
Article
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| MEDLINE
| ID: mdl-21583323
ABSTRACT
In the crystal structure of the title compound, [Co(C(8)H(8)O(5))(C(3)H(4)N(2))(3)]·3.35H(2)O, the central Co(II) ion is in a slightly distorted octa-hedral environment, coordinated by the bridg-ing O atom from the bicyclo-[2.2.1]heptane ligand, by two carboxyl-ate O atoms from two different carboxyl-ate groups and by three N atoms from imidazole ligands. Uncoordinated water mol-ecules, some of them disordered, are present in the crystal structure. In the crystal structure, mol-ecules are linked by O-Hâ¯O, N-Hâ¯O and O-Hâ¯N hydrogen-bonding inter-actions.
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2009
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Article