Benzyl (E)-3-(2-methyl-benzyl-idene)dithio-carbazate.
Acta Crystallogr Sect E Struct Rep Online
; 67(Pt 9): o2497, 2011 Sep 01.
Article
en En
| MEDLINE
| ID: mdl-22059047
ABSTRACT
The title compound, C(16)H(16)N(2)S(2), was obtained from the condensation reaction of benzyl dithio-carbazate and 2-methyl-benzaldehyde. The asymmetric unit contains two independent mol-ecules. In both mol-ecules, the methyl-phenyl ring and the dithio-carbazate fragment are located on opposite sides of the C=N bond, showing an E conformation. In each mol-ecule, the dithio-carbazate fragment is approximately planar, the r.m.s deviations being 0.018 and 0.025â
Å. The mean plane of dithio-carbazate group is oriented at dihedral angles of 7.9â
(3) and 68.24â
(12)°, respectively, to the methyl-phenyl and phenyl rings in one mol-ecule, while the corresponding angles in the other mol-ecule are 10.9â
(3) and 69.76â
(16)°. Inter-molecular N-Hâ¯S hydrogen bonding occurs in the crystal structure to generate inversion dimers for both molecules.
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2011
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Article