A solid-state NMR study of C(70): a model molecule for amorphous carbons.
Solid State Nucl Magn Reson
; 42: 81-6, 2012 Apr.
Article
en En
| MEDLINE
| ID: mdl-22316606
ABSTRACT
We show that natural abundance, solid-state MAS-NMR (13)C INADEQUATE spectra can be recorded for crystallized C(70), using the through-bond J-coupling for the magnetization transfer. The effect of strong J-coupling can be lessened at high magnetic fields, allowing the observation of cross-peaks between close resonances. DFT calculations of the chemical shifts show an excellent agreement with the experimental values. A correlation is observed between the average CCC bond angles and the (13)C chemical shift, offering a way to understand the dispersion of (13)C chemical shifts in nanoporous activated carbons in terms of local deviations from planarity.
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Banco de datos:
MEDLINE
Asunto principal:
Carbono
/
Espectroscopía de Resonancia Magnética
Idioma:
En
Año:
2012
Tipo del documento:
Article