A tetradentate ligand for the enantioselective Ti(IV)-promoted oxidation of sulfides to sulfoxides: origin of enantioselectivity.
J Am Chem Soc
; 134(42): 17354-7, 2012 Oct 24.
Article
en En
| MEDLINE
| ID: mdl-23046346
ABSTRACT
A detailed stereomechanistic analysis has led to the design of a new tetradentate ligand for the enantioselective Ti(IV)-catalyzed oxidation of unsymmetrical sulfides to sulfoxides with high selectivity. The pathway of this oxidation and the closely related and long-known Kagan-Modena oxidation have been clarified to identify the likely origin of the enantioselectivity.
Texto completo:
1
Banco de datos:
MEDLINE
Asunto principal:
Sulfuros
/
Sulfóxidos
/
Titanio
Idioma:
En
Año:
2012
Tipo del documento:
Article