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1-(Benzotriazol-1-yl)-2-bromoethanone.
Asiri, Abdullah M; Abo-Dya, Nader E; Arshad, Muhammad Nadeem; Shafiq, Muhammad.
  • Asiri AM; Chemistry Department, Faculty of Science, King Abdulaziz University, PO Box 80203, Jeddah 21589, Saudi Arabia ; Center of Excellence for Advanced Materials Research (CEAMR), Faculty of Science, King Abdulaziz University, PO Box 80203, Jeddah 21589, Saudi Arabia.
Acta Crystallogr Sect E Struct Rep Online ; 68(Pt 11): o3179, 2012 Nov 01.
Article en En | MEDLINE | ID: mdl-23284492
ABSTRACT
In the title compound C(8)H(6)BrN(3)O, the benzotriazole ring is essentially planar (r.m.s. deviation = 0.0034 Å) and the bromo-acetyl unit is twisted at a dihedral angle of 15.24 (16)° with respect to it. In the crystal, pairs of C-H⋯O hydrogen bondings result in the formation of inversion dimers, forming R(2) (2)(12) rings, which are connected by further C-H⋯O inter-actions into chains extending along the b-axis direction.