Synthesis of pyridine-capped diketopyrrolopyrrole and its use as a building block of low band-gap polymers for efficient polymer solar cells.
Chem Commun (Camb)
; 49(76): 8495-7, 2013 Oct 04.
Article
en En
| MEDLINE
| ID: mdl-23939290
ABSTRACT
A new building block for low band-gap polymers, diketopyrrolopyrrole (DPP) flanked by pyridine (PyDPP), has been synthesized via a simple synthetic route. PyDPP was polymerized with bithiophene (BT) to afford a low band-gap copolymer (PBTPyDPP) which was used as an electron donor of the active layer in polymer solar cells. The solar cell device based on PBTPyDPP exhibited a promising PCE of 4.9% with a high VOC over 0.9 V, which is one of the highest values among DPP-based polymer solar cells.
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2013
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Article