Responsive nature of 1,2,4,5-tetrakis(2-pyridylthiomethyl)benzene toward group 12 metal nitrates: activity of coordinated nitrate in metal complexes.
Inorg Chem
; 53(12): 5887-9, 2014 Jun 16.
Article
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| MEDLINE
| ID: mdl-24884196
ABSTRACT
This study provides a detailed analysis on the responsive behavior of 1,2,4,5-tetrakis(2-pyridylthiomethyl)benzene (L) toward group 12 metal nitrates in both aqueous and nonaqueous media. The ligand L proved to be an environmentally responsive species, and structural investigations of its complexes with respective M(NO3)2 (M = Zn, Cd, and Hg) allowed one to remark on the inherent activity of the nitrate ion, resulting in a distinctively higher coordination number and dimensionality to the metal cations.
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2014
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