Nickel-catalyzed one-pot tandem 1,4-1,2-addition of P(O)H compounds to 1,10-phenanthrolines.
J Org Chem
; 80(2): 1192-9, 2015 Jan 16.
Article
en En
| MEDLINE
| ID: mdl-25485888
ABSTRACT
A novel and efficient nickel-catalyzed tandem 1,4-1,2-addition of P(O)H compounds to 1,10-phenanthrolines forming various 2,4-diphosphono-1,2,3,4-tetrahydro-1,10-phenanthrolines has been developed. This reaction breaks up the aromatic stabilization and directly introduces two phosphorus moieties in one single step. This finding is the first example of transition-metal-catalyzed double hydrophosphonylation of 1,10-phenanthrolines.
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1
Banco de datos:
MEDLINE
Asunto principal:
Compuestos Organofosforados
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Fenantrolinas
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Níquel
Idioma:
En
Año:
2015
Tipo del documento:
Article