Structural requirements for palladium catalyst transfer on a carbon-carbon double bond.
J Am Chem Soc
; 137(17): 5682-5, 2015 May 06.
Article
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| MEDLINE
| ID: mdl-25900778
ABSTRACT
Intramolecular transfer of (t)Bu3PPd(0) on a carbon-carbon double bond (CâC) was investigated by using Suzuki-Miyaura coupling reaction of dibromostilbenes with aryl boronic acid or boronic acid esters in the presence of various additives containing CâC as a model. Substituent groups at the ortho position of CâC of stilbenes are critical for selective intramolecular catalyst transfer and may serve to suppress formation of the bimolecular CâC-Pd-CâC complex that leads to intermolecular transfer of (t)Bu3PPd(0).
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