Remote Photoregulated Ring Gliding in a [2]Rotaxane via a Molecular Effector.
Org Lett
; 19(1): 154-157, 2017 01 06.
Article
en En
| MEDLINE
| ID: mdl-27935723
ABSTRACT
A molecular barbiturate messenger, which is reversibly released/captured by a photoswitchable artificial molecular receptor, is shown to act as an effector to control ring gliding on a distant hydrogen-bonding [2]rotaxane. Thus, light-driven chemical communication governing the operation of a remote molecular machine is demonstrated using an information-rich neutral molecule.
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2017
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Article