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A Mononuclear Nonheme Iron(V)-Imido Complex.
Hong, Seungwoo; Sutherlin, Kyle D; Vardhaman, Anil Kumar; Yan, James J; Park, Sora; Lee, Yong-Min; Jang, Soojeong; Lu, Xiaoyan; Ohta, Takehiro; Ogura, Takashi; Solomon, Edward I; Nam, Wonwoo.
  • Hong S; Department of Chemistry and Nano Science, Ewha Womans University , Seoul 03760, Korea.
  • Sutherlin KD; Department of Chemistry, Sookmyung Women's University , Seoul 04310, Korea.
  • Vardhaman AK; Department of Chemistry, Stanford University , Stanford, California 94305, United States.
  • Yan JJ; Department of Chemistry and Nano Science, Ewha Womans University , Seoul 03760, Korea.
  • Park S; Department of Chemistry, Stanford University , Stanford, California 94305, United States.
  • Lee YM; Department of Chemistry and Nano Science, Ewha Womans University , Seoul 03760, Korea.
  • Jang S; Department of Chemistry and Nano Science, Ewha Womans University , Seoul 03760, Korea.
  • Lu X; Department of Chemistry and Nano Science, Ewha Womans University , Seoul 03760, Korea.
  • Ohta T; Department of Chemistry and Nano Science, Ewha Womans University , Seoul 03760, Korea.
  • Ogura T; Picobiology Institute, Graduate School of Life Science, University of Hyogo , RSC-UH LP Center, Hyogo 679-5148, Japan.
  • Solomon EI; Picobiology Institute, Graduate School of Life Science, University of Hyogo , RSC-UH LP Center, Hyogo 679-5148, Japan.
  • Nam W; Department of Chemistry, Stanford University , Stanford, California 94305, United States.
J Am Chem Soc ; 139(26): 8800-8803, 2017 07 05.
Article en En | MEDLINE | ID: mdl-28628312
ABSTRACT
Mononuclear nonheme iron(V)-oxo complexes have been reported previously. Herein, we report the first example of a mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [(TAML)FeV(NTs)]- (1). The spectroscopic characterization of 1 revealed an S = 1/2 Fe(V) oxidation state, an Fe-N bond length of 1.65(4) Å, and an Fe-N vibration at 817 cm-1. The reactivity of 1 was demonstrated in C-H bond functionalization and nitrene transfer reactions.
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Texto completo: 1 Banco de datos: MEDLINE Asunto principal: Complejos de Coordinación / Imidas / Hierro Idioma: En Año: 2017 Tipo del documento: Article
Texto completo
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Texto completo: 1 Banco de datos: MEDLINE Asunto principal: Complejos de Coordinación / Imidas / Hierro Idioma: En Año: 2017 Tipo del documento: Article