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New chemistry of transition metal oxyhydrides.
Kobayashi, Yoji; Hernandez, Olivier; Tassel, Cédric; Kageyama, Hiroshi.
  • Kobayashi Y; Department of Energy & Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Kyoto, Japan.
  • Hernandez O; Solid State Chemistry and Materials Group, Institute of Chemical Sciences at Rennes, UMR 6226 CNRS-University of Rennes 1, Rennes, France.
  • Tassel C; Department of Energy & Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Kyoto, Japan.
  • Kageyama H; Department of Energy & Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Kyoto, Japan.
Sci Technol Adv Mater ; 18(1): 905-918, 2017.
Article en En | MEDLINE | ID: mdl-29383042
ABSTRACT
In this review we describe recent advances in transition metal oxyhydride chemistry obtained by topochemical routes, such as low temperature reduction with metal hydrides, or high-pressure solid-state reactions. Besides the crystal chemistry, magnetic and transport properties of the bulk powder and epitaxial thin film samples, the remarkable lability of the hydride anion is particularly highlighted as a new strategy to discover unprecedented mixed anion materials.
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