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Synthesis and Properties of Energy-Rich Methanofullerenes Containing Norbornadiene and Quadricyclane Moieties.
Tuktarov, Airat R; Akhmetov, Arslan R; Khuzin, Artur A; Dzhemilev, Usein M.
  • Tuktarov AR; Laboratory of Catalytic Synthesis , Institute of Petrochemistry and Catalysis of RAS (IPC RAS) , Prospect Octyabrya, 141 , 450075 Ufa , Russian Federation.
  • Akhmetov AR; Laboratory of Catalytic Synthesis , Institute of Petrochemistry and Catalysis of RAS (IPC RAS) , Prospect Octyabrya, 141 , 450075 Ufa , Russian Federation.
  • Khuzin AA; Laboratory of Catalytic Synthesis , Institute of Petrochemistry and Catalysis of RAS (IPC RAS) , Prospect Octyabrya, 141 , 450075 Ufa , Russian Federation.
  • Dzhemilev UM; Laboratory of Catalytic Synthesis , Institute of Petrochemistry and Catalysis of RAS (IPC RAS) , Prospect Octyabrya, 141 , 450075 Ufa , Russian Federation.
J Org Chem ; 83(7): 4160-4166, 2018 04 06.
Article en En | MEDLINE | ID: mdl-29533625
ABSTRACT
The energy-rich methanofullerenes were synthesized for the first time by the reaction of fullerene C60 with mono- and bisquadricyclane esters of malonic acid. The C-C bond cleavage in the quadricyclane moieties of new hybrid molecules takes place in the presence of catalytic amounts of Cu, Pd, and Pt salts or complexes or SiO2 and is accompanied by heat evolution.
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Año: 2018 Tipo del documento: Article
Texto completo
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Año: 2018 Tipo del documento: Article