Sub-Doppler Frequency Metrology in HD for Tests of Fundamental Physics.

Weak transitions in the (2,0) overtone band of the hydrogen deuteride molecule at λ=1.38 µm were measured in saturated absorption using the technique of noise-immune cavity-enhanced optical heterodyne molecular spectroscopy. Narrow Doppler-free lines were interrogated with a spectroscopy laser locked to a frequency comb laser referenced to an atomic clock to yield transition frequencies [R(1)=217105181895(20) kHz; R(2)=219042856621(28) kHz; R(3)=220704304951(28) kHz] at three orders of magnitude improved accuracy. These benchmark values provide a test of QED in the smallest neutral molecule, and they open up an avenue to resolve the proton radius puzzle, as well as constrain putative fifth forces and extra dimensions.