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trans-Cyclooctenes as Halolactonization Catalysts.
Einaru, Shunsuke; Shitamichi, Kenta; Nagano, Tagui; Matsumoto, Akira; Asano, Keisuke; Matsubara, Seijiro.
  • Einaru S; Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyotodaigaku-katsura, Nishikyo, Kyoto, 615-8510, Japan.
  • Shitamichi K; Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyotodaigaku-katsura, Nishikyo, Kyoto, 615-8510, Japan.
  • Nagano T; Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyotodaigaku-katsura, Nishikyo, Kyoto, 615-8510, Japan.
  • Matsumoto A; Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyotodaigaku-katsura, Nishikyo, Kyoto, 615-8510, Japan.
  • Asano K; Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyotodaigaku-katsura, Nishikyo, Kyoto, 615-8510, Japan.
  • Matsubara S; Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyotodaigaku-katsura, Nishikyo, Kyoto, 615-8510, Japan.
Angew Chem Int Ed Engl ; 57(42): 13863-13867, 2018 Oct 15.
Article en En | MEDLINE | ID: mdl-30160817
ABSTRACT
The strained olefins in trans-cyclooctenes serve as efficient catalysts for halolactonizations, including bromolactonizations and iodolactonizations. The trans-cyclooctene framework is essential for excellent catalytic performance, and the substituents also play important roles in determining efficiency. These results are the first demonstration of catalysis by a trans-cyclooctene.
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Año: 2018 Tipo del documento: Article
Texto completo
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Año: 2018 Tipo del documento: Article