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Rapid Ring-Opening Metathesis Polymerization of Monomers Obtained from Biomass-Derived Furfuryl Amines and Maleic Anhydride.
Blanpain, Anna; Clark, James H; Farmer, Thomas J; Guo, Yuanlong; Ingram, Ian D V; Kendrick, John E; Lawrenson, Stefan B; North, Michael; Rodgers, George; Whitwood, Adrian C.
  • Blanpain A; Department of Chemistry, University of York, Heslington, YO10 5DD, UK.
  • Clark JH; Department of Chemistry, University of York, Heslington, YO10 5DD, UK.
  • Farmer TJ; Department of Chemistry, University of York, Heslington, YO10 5DD, UK.
  • Guo Y; Department of Chemistry, University of York, Heslington, YO10 5DD, UK.
  • Ingram IDV; Department of Chemistry, University of York, Heslington, YO10 5DD, UK.
  • Kendrick JE; Department of Chemistry, University of York, Heslington, YO10 5DD, UK.
  • Lawrenson SB; Department of Chemistry, University of York, Heslington, YO10 5DD, UK.
  • North M; Department of Chemistry, University of York, Heslington, YO10 5DD, UK.
  • Rodgers G; Department of Chemistry, University of York, Heslington, YO10 5DD, UK.
  • Whitwood AC; Department of Chemistry, University of York, Heslington, YO10 5DD, UK.
ChemSusChem ; 12(11): 2393-2401, 2019 Jun 07.
Article en En | MEDLINE | ID: mdl-30950226
ABSTRACT
Well-controlled and extremely rapid ring-opening metathesis polymerization of unusual oxanorbornene lactam esters by Grubbs third-generation catalyst is used to prepare a range of bio-based homo- and copolymers. Bio-derived oxanorbornene lactam monomers were prepared at room temperature from maleic anhydride and secondary furfuryl amines by using a 100 % atom economical, tandem Diels-Alder lactamization reaction, followed by esterification. Several of the resulting homo- and copolymers show good control over polymer molecular weight and have narrow molecular weight distributions.
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Año: 2019 Tipo del documento: Article

Texto completo: 1 Banco de datos: MEDLINE Idioma: En Año: 2019 Tipo del documento: Article