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On-surface synthesis of planar acenes via regioselective aryl-aryl coupling.
Feng, Lin; Wang, Tao; Jia, Hongxing; Huang, Jianmin; Han, Dong; Zhang, Wenzhao; Ding, Honghe; Xu, Qian; Du, Pingwu; Zhu, Junfa.
  • Feng L; National Synchrotron Radiation Laboratory, Department of Chemical Physics and Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes, University of Science and Technology of China, Hefei, 230029, China. jfzhu@ustc.edu.cn.
  • Wang T; National Synchrotron Radiation Laboratory, Department of Chemical Physics and Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes, University of Science and Technology of China, Hefei, 230029, China. jfzhu@ustc.edu.cn.
  • Jia H; Hefei National Laboratory of Physical Science at the Microscale, CAS Key Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), University of Science and Technology of China, 96 Jinzha
  • Huang J; National Synchrotron Radiation Laboratory, Department of Chemical Physics and Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes, University of Science and Technology of China, Hefei, 230029, China. jfzhu@ustc.edu.cn.
  • Han D; National Synchrotron Radiation Laboratory, Department of Chemical Physics and Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes, University of Science and Technology of China, Hefei, 230029, China. jfzhu@ustc.edu.cn.
  • Zhang W; National Synchrotron Radiation Laboratory, Department of Chemical Physics and Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes, University of Science and Technology of China, Hefei, 230029, China. jfzhu@ustc.edu.cn.
  • Ding H; National Synchrotron Radiation Laboratory, Department of Chemical Physics and Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes, University of Science and Technology of China, Hefei, 230029, China. jfzhu@ustc.edu.cn.
  • Xu Q; National Synchrotron Radiation Laboratory, Department of Chemical Physics and Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes, University of Science and Technology of China, Hefei, 230029, China. jfzhu@ustc.edu.cn.
  • Du P; Hefei National Laboratory of Physical Science at the Microscale, CAS Key Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), University of Science and Technology of China, 96 Jinzha
  • Zhu J; National Synchrotron Radiation Laboratory, Department of Chemical Physics and Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes, University of Science and Technology of China, Hefei, 230029, China. jfzhu@ustc.edu.cn.
Chem Commun (Camb) ; 56(36): 4890-4893, 2020 May 05.
Article en En | MEDLINE | ID: mdl-32236253
The reaction of 2,2'-dibromo-biphenyl on a Ag(111) surface leads to the formation of planar acenes with a high-regioselectivity rather than nonplanar saddle-shaped tetraphenylene as the typical product in solution chemistry. The regioselective aryl-aryl coupling reaction is attributed to the hydrogen repulsion between the reactants on the confined two-dimensional surface.
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Año: 2020 Tipo del documento: Article
Texto completo
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Año: 2020 Tipo del documento: Article