Titanium Nanopillar Arrays Functioning as Electron Transporting Layers for Efficient, Anti-Aging Perovskite Solar Cells.

ABSTRACT

Electron transporting layers (ETLs), required to be optically transparent in perovskite solar cells (PSCs) having regular structures, possess a determinant effect on electron extraction and collection. Metal oxides (e.g., TiO2 ) have overwhelmingly served as ETLs, but usually have low electron mobility (µe  < 10-2  cm2 V-1 s-1 ) not favorable for photovoltaic conversion. Here, metal oxides are replaced with metals (e.g., Ti with µe  ≈ 294 cm2 V-1 s-1 ) that are sculptured via glancing angle deposition to be a close-packed nanopillar array (NaPA), which vertically protrudes on a transparent electrode to obtain sufficient optical transmission for light harvesting in perovskite. Ti NaPAs, whose rough surfaces are passivated with 5 nm thick TiO2 (i.e., Ti NaPAs@TiO2 ) to suppress exciton recombination, lead to the champion power conversion efficiency (PCE) of 18.89% that is superior to that of MAPbI3 PSCs without Ti NaPAs@TiO2 or containing TiO2 NaPAs@TiO2 , owing to high surface wettability, high µe , and relatively low work function of Ti. Furthermore, Ti NaPAs@TiO2 effectively prevents the decomposition of MAPbI3 to achieve long-term shelf stability whereby 50-day aging only causes 15% PCE degradation. This work paves the way toward widening the material spectrum, from semiconductors to metals, to generate a diverse range of ETLs for producing efficient optoelectronic devices with long-term shelf stability.