Your browser doesn't support javascript.
loading
Heterometallic d8 -d10 Coupling of Rh(I) and M(0) (M=Pd, Pt) in a Sandwich Framework of π-Conjugated Ligands.
Inoue, Iori; Yamamoto, Koji; Sakaki, Shigeyoshi; Murahashi, Tetsuro.
  • Inoue I; Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo, 1528552, Japan.
  • Yamamoto K; Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo, 1528552, Japan.
  • Sakaki S; Elements Strategy Initiative for Catalysts and Batteries, Kyoto University, Kyoto, 6158510, Japan.
  • Murahashi T; Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo, 1528552, Japan.
Chemistry ; 27(41): 10558-10562, 2021 Jul 21.
Article en En | MEDLINE | ID: mdl-34003537
ABSTRACT
A heterometallic M-M' bond formation is a key to construct atomically precise bimetallic clusters and materials. However, it is sometimes not straightforward to construct a heterometallic M-M' bond through conventional methods including redox condensation. Here, we found that a sandwich framework of π-conjugated unsaturated hydrocarbon ligands provides a unique coordination environment that facilitates unusual coupling of d8 RhI and d10 M0 (M=Pd, Pt). The molecular orbital analysis showed that the electron-accepting ability of the sandwich framework through back-donation allows the formation of a dσ-type Rh-Pd bond in a (d-d)18 electron system.
Palabras clave
Texto completo
Imprimir
XML
PubMed Links
Search on Google

Texto completo: 1 Banco de datos: MEDLINE Idioma: En Año: 2021 Tipo del documento: Article
Texto completo
Imprimir
XML
PubMed Links
Search on Google

Texto completo: 1 Banco de datos: MEDLINE Idioma: En Año: 2021 Tipo del documento: Article