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Isolation of 1,4-Diarsinine-1,4-diide and 1,4-Diarsinine Derivatives.
Rottschäfer, Dennis; Glodde, Timo; Neumann, Beate; Stammler, Hans-Georg; Andrada, Diego M; Ghadwal, Rajendra S.
  • Rottschäfer D; Molecular Inorganic Chemistry and Catalysis, Inorganic and Structural Chemistry, Center for Molecular Materials, Faculty of Chemistry, Universität Bielefeld, Universitätsstrasse 25, 33615, Bielefeld, Germany.
  • Glodde T; Molecular Inorganic Chemistry and Catalysis, Inorganic and Structural Chemistry, Center for Molecular Materials, Faculty of Chemistry, Universität Bielefeld, Universitätsstrasse 25, 33615, Bielefeld, Germany.
  • Neumann B; Molecular Inorganic Chemistry and Catalysis, Inorganic and Structural Chemistry, Center for Molecular Materials, Faculty of Chemistry, Universität Bielefeld, Universitätsstrasse 25, 33615, Bielefeld, Germany.
  • Stammler HG; Molecular Inorganic Chemistry and Catalysis, Inorganic and Structural Chemistry, Center for Molecular Materials, Faculty of Chemistry, Universität Bielefeld, Universitätsstrasse 25, 33615, Bielefeld, Germany.
  • Andrada DM; Inorganic and Computational Chemistry Group, Allgemeine und Anorganische Chemie, Universität des Saarlandes, Campus C4.1, 66123, Saarbrücken, Germany.
  • Ghadwal RS; Molecular Inorganic Chemistry and Catalysis, Inorganic and Structural Chemistry, Center for Molecular Materials, Faculty of Chemistry, Universität Bielefeld, Universitätsstrasse 25, 33615, Bielefeld, Germany.
Angew Chem Int Ed Engl ; 60(29): 15849-15853, 2021 Jul 12.
Article en En | MEDLINE | ID: mdl-34015179
1,4-Diarsinine-1,4-diide compound [(ADCPh )As]2 (5) (ADCPh ={C(DippN)}2 CPh, Dipp=2,6-iPr2 C6 H3 ) with a planar C4 As2 ring fused between two 1,3-imidazole scaffolds has been isolated as a red crystalline solid. Compound 5, formally comprising an 8π-electron C4 As2 ring, is antiaromatic and undergoes 2e-oxidation with AgOTf to form the 6π-electron aromatic system [(ADCPh )As]2 (OTf)2 (6).
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Año: 2021 Tipo del documento: Article
Texto completo
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Año: 2021 Tipo del documento: Article