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The Ag-promoted α-C-H arylation of alcohols.
Wang, Shoufeng; Xing, Shuya; Zhang, Yingying; Fan, Yafei; Zhao, Huaiqing; Wang, Jianfeng; Zhang, Shuxiang; Wang, Wengui.
  • Wang S; School of Chemistry and Chemical Engineering, University of Jinan 336 West Road of Nan Xinzhuang Jinan 250022 China chm_wangwf@ujn.edu.cn chm_wangwg@ujn.edu.cn.
  • Xing S; Shandong Provincial Key Laboratory of Fluorine Chemistry and Chemical Materials 336 West Road of Nan Xinzhuang Jinan 250022 China.
  • Zhang Y; School of Chemistry and Chemical Engineering, University of Jinan 336 West Road of Nan Xinzhuang Jinan 250022 China chm_wangwf@ujn.edu.cn chm_wangwg@ujn.edu.cn.
  • Fan Y; School of Chemistry and Chemical Engineering, University of Jinan 336 West Road of Nan Xinzhuang Jinan 250022 China chm_wangwf@ujn.edu.cn chm_wangwg@ujn.edu.cn.
  • Zhao H; School of Chemistry and Chemical Engineering, University of Jinan 336 West Road of Nan Xinzhuang Jinan 250022 China chm_wangwf@ujn.edu.cn chm_wangwg@ujn.edu.cn.
  • Wang J; Shandong Provincial Key Laboratory of Fluorine Chemistry and Chemical Materials 336 West Road of Nan Xinzhuang Jinan 250022 China.
  • Zhang S; School of Chemistry and Chemical Engineering, University of Jinan 336 West Road of Nan Xinzhuang Jinan 250022 China chm_wangwf@ujn.edu.cn chm_wangwg@ujn.edu.cn.
  • Wang W; Key Laboratory of Interfacial Reaction & Sensing Analysis in Universities of Shandong 336 West Road of Nan Xinzhuang Jinan 250022 China.
RSC Adv ; 9(71): 41847-41850, 2019 Dec 13.
Article en En | MEDLINE | ID: mdl-35541603
We herein report the functionalization of α-C-H in alcohols through cross-dehydrogenative coupling reactions. Selectfluor was used as a mild oxidant. In situ-generated HF participated in the reaction and no external strong acid was necessary. A variety of heteroaryl-substituted alcohols were achieved with good yields and with good functional group tolerance.
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Año: 2019 Tipo del documento: Article
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Texto completo: 1 Banco de datos: MEDLINE Idioma: En Año: 2019 Tipo del documento: Article