Eco-friendly synthesis of sulphur-doped graphenes with applicability in caffeic acid electrochemical assay.

ABSTRACT

A new electrode based on glassy carbon modified with a sulphur-doped graphene material was successfully developed and applied for caffeic acid (CA) voltammetric detection and quantification. The structural features of sulphur-doped graphene (exfGR-S) characterized by different physicochemical and analytical techniques are presented. Cyclic voltammetry (CV) technique was employed to evaluate the electrochemical behavior of both bare glassy carbon (GCE) and modified GCE/exfGr-S electrodes towards CA oxidation. The study revealed that the modified electrode exhibits superior electrochemical performances compared to the bare electrode, with a broad CA detecting range (from 0.1 to 100.0 µM), a low detection limit 3.03 × 10-8 M), excellent anti-interference capabilities, as well as good stability and repeatability. The developed electrochemical sensor appears to be a promising candidate for real sample quality control analysis since it successfully displayed its ability to directly detect CA in commercially available coffee product without any pretreatment.