Piezoelectricity-enhanced photoelectrochemistry synthesis of H2O2 on an Au nanoparticles modified p-type Sb-doped ZnO nanotubes array.
Chem Commun (Camb)
; 59(1): 114-117, 2022 Dec 22.
Article
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| MEDLINE
| ID: mdl-36477700
ABSTRACT
A p-type Sb-doped ZnO nanorods (p-ZnOSb,NR) array was hydrothermally prepared on indium tin oxide (ITO) and then etched into a p-type Sb-doped ZnO nanotubes (p-ZnOSb,NT) array by hot alkali solution. Further photodeposition of Au nanoparticles (AuNP) yielded a novel AuNP/p-ZnOSb,NT/ITO photocathode. The green synthesis of H2O2 by piezoelectricity-enhanced photoelectrochemistry and oxygen reduction reaction was studied for the first time, giving a H2O2 yield of 15.2 µmol cm-2 h-1, a photocurrent density of -1.05 mA cm-2 and a Faraday efficiency of 79.0% on this photocathode.
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