Designed Tetranuclear Iron-oxo Clusters with Redox Activity for High-Performance Lithium Storage.
Angew Chem Int Ed Engl
; 62(30): e202306193, 2023 Jul 24.
Article
en En
| MEDLINE
| ID: mdl-37269225
ABSTRACT
Polyoxometalates (POMs) are considered as promising catalysts with unique redox activity at the molecular level for energy storage. However, eco-friendly iron-oxo clusters with special metal coordination structures have rarely been reported for Li-ion storage. Herein, three novel redox-active tetranuclear iron-oxo clusters have been synthesized using the solvothermal method with different ratios of Fe3+ and SO4 2- . Further, they can serve as anode materials for Li-ion batteries. Among them, cluster H6 [Fe4 O2 (H2 O)2 (SO4 )7 ]â
H2 O, the stable structure extended by SO4 2- with a unique 1D pore, displays a specific discharge capacity of 1784â
mAh g-1 at 0.2â
C and good cycle performance (at 0.2â
C and 4â
C). This is the first instance of inorganic iron-oxo clusters being used for Li-ion storage. Our findings present a new molecular model system with a well-defined structure and offer new design concepts for the practical application of studying the multi-electron redox activity of iron-oxo clusters.
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1
Banco de datos:
MEDLINE
Tipo de estudio:
Prognostic_studies
Idioma:
En
Año:
2023
Tipo del documento:
Article