Au doped metal organic frameworks as di-functional photocatalysts for clearing organics in wastewater.

ABSTRACT

Along with the development of productive forces, the use of organic compounds including diversified dyes and multiple drugs has become more and more commonly, resulting in the accelerating water contamination. Herein in this paper, Au doped PCN 224 are designed as bi-functional wastewater treatment agents to absorb and decompose organics molecules efficiently under light irradiation. After inserted with Au, the PCN 224 nanoparticles, which is kind of porous, stable and photosensitive metal-organic framework, show enhanced photodegradeability. Because the Au inserted could inhibit the re-combination of electrons and holes by absorbing photo-electrons; decrease the nanoparticles' band gap, and finally produce much more free radicals. In the meanwhile, due to the lower binding energy between S and Au, the Au modified PCN 224 perform better in absorbing organic compounds consisted of S contained heterocyclic ring (such as methylene blue). This work provides new insights into the precious design of materials in clearing organic compounds.