Bimetallic-MOF Derived Carbon with Single Pt Anchored C4 Atomic Group Constructing Super Fuel Cell with Ultrahigh Power Density And Self-Change Ability.
Adv Mater
; 36(1): e2308989, 2024 Jan.
Article
en En
| MEDLINE
| ID: mdl-37966064
ABSTRACT
Pursuing high power density with low platinum catalysts loading is a huge challenge for developing high-performance fuel cells (FCs). Herein, a new super fuel cell (SFC) is proposed with ultrahigh output power via specific electric double-layer capacitance (EDLC) + oxygen reduction reaction (ORR) parallel discharge, which is achieved using the newly prepared catalyst, single-atomic platinum on bimetallic metal-organic framework (MOF)-derived hollow porous carbon nanorods (PtSA /HPCNR). The PtSA-1.74 /HPCNR-based SFC has a 3.4-time higher transient specific power density and 13.3-time longer discharge time with unique in situ self-charge and energy storage ability than 20% Pt/C-based FCs. X-ray absorption fine structure, aberration-corrected high-angle annular dark-field scanning transmission electron microscope, and density functional theory calculations demonstrate that the synergistic effect of Pt single-atoms anchored on carbon defects significantly boosts its electron transfer, ORR catalytic activity, durability, and rate performance, realizing rapid " ORR+EDLC" parallel discharge mechanism to overcome the sluggish ORR process of traditional FCs. The promising SFC leads to a new pathway to boost the power density of FCs with extra-low Pt loading.
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2024
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