DNDMH-mediated direct nitration of aryl alkenes.
Chem Commun (Camb)
; 60(23): 3202-3204, 2024 Mar 14.
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| MEDLINE
| ID: mdl-38415740
ABSTRACT
N-nitro type reagents have been demonstrated as mild nitration tools in recent years. This work presents an exploration of direct nitration of aryl alkenes mediated by DNDMH, a novel N-nitro type reagent developed in our previous study. It exhibits herein a new property of DNDMH as an effective direct nitration reagent for aryl alkenes, through probably the delivery of nitro radicals with the aid of TEMPO and Cu(OAc)2.
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2024
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